• Asian Journal of Turfgrass Science
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• v.23 no.2
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• pp.271-278
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• 2009

This study was conducted to investigate the effect of the mixture ratio of the inorganic soil amendments on the soil physicochemical properties. In this experiment, three kinds of soil amendments which had similar pH, EC and particle size, the A, B and C, were tested. The mixture ratio of soil amendment were 0%, 3%, 5%, 7% and 10% (V/V) incorporated with sand which met to the USGA(United State of Golf Association) particle standard. To analyze the effects of amendment on chemical soil properties, pH, EC(electrical conductivity) and CEC(cation exchangeable capacity) were measured. The porosity, bulk density and hydraulic conductivity also measured to analyze the changes of physical properties. In the chemical properties, pH was significantly related to the mixture ratios of amendments, A and C(P<0.05), CEC and EC also related to the ratios of C(P<0.01). When the results were applied to the USGA standard of the soil physical properties, the optimum mixture ratios of each amendment were 3% in A and B, and 7~10% in C. To analyze the corelation of mixture ratio versus to physical character, volume of porosity was significantly related to the ratio of B (P<0.05), and showed similar corelation in porosity and hydraulic conductivity with ratio of C(P<0.05). These results indicate that types and mixture ratio of inorganic soil amendments should affect on soil physio-chemical properties of root zone on USGA sand green.

• The Korean Journal of Pesticide Science
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• v.20 no.4
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• pp.312-318
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• 2016

This study investigated the reduction of residual pesticide in soil by using eight kinds of soil amendments such as shell, quick lime, dolomite, silicic acid, leaf mold, oil cake, bed soil and husk. A total of ten pesticides most frequently detected in agricultural soil were selected (azoxystrobin etc.) and soil amendments were treated in soils at a 2% application rate and incubated for 7 days. Pesticides were analyzed by HPLC-MS/MS with QuEChERS-based sample preparation procedure and pH was measured on 1, 3 and 7 days. This study showed that, soil amemdments were effective in reducing pesticides after 7days of incubation. Over 90% of azoxystrobin, cadusafos, chlorpyrifos, fluquinconazole, imidacloprid, isoprothiolane and procymidone were decomposed from soils amended with 2% quick lime, whereas the concentration of boscalid, dimethomorph and triycyclazole were not decreased. The soil pH increased to 12.8-12.9 in soil amended with quick lime, but other soil conditioners did not change the soil pH. Quick lime was particularly effective in reducing residual pesticides.

• Korean Journal of Soil Science and Fertilizer
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• v.51 no.2
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• pp.101-110
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• 2018

There is an increasing concern over arsenic (As) contamination in rice since Codex Committee on Contaminants in Food (CCCF) discuss on maximum levels for As in rice in 2010. This study was conducted to reduce As concentration in rice by soil amendment treatments in paddy field soils contaminated by As. The selected four amendments were poultry manure, agri-lime, steel slag, and gypsum with the addition of 3% or 5% (w/w) on a dry basis. The As reduction effect could not be verified, as a result of the pot test by adding poultry manure to the paddy soil around the mine located in Yesan. Among the agri-lime treated rice cultivated pots, the As concentration increased up to 32.1%. On the other hand, the content of As in the sample pots treated with steel slag and gypsum decreased by 65.4% and 63.4%, respectively. On the basis of the results of these pot experiments, the field test was carried out in the As polluted rice field around the mine located in Yesan, and when the four amendments were treated, the As content in the brown rice reduced in all the amendment treatments compared with the control plot. The As reduction in brown rice of the amendment was confirmed to be higher efficiency by the order of gypsum > steel slag > poultry manure > agri-lime. As a result of pot experiments using paddy soil around the mine located in Seosan, As stabilization efficiency in rice and As reduction effect could not be determined by comparison to the control. From the rice cultivated from agri-lime treated pot, As concentration increased by 15.8% in rice. On the other hand, the As content of the pots treated with steel slag and gypsum decreased by 39.1% and 60.2%, respectively. In conclusion, distinguished As reducing effectiveness could be expected by soil amendment treatments for rice cultivation.

• Korean Journal of Soil Science and Fertilizer
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• v.45 no.6
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• pp.973-982
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• 2012

Crop safety in heavy metal contaminated agricultural field has been a critical issue in Korea and various remediation methods are proposed for minimizing heavy metal transfer from soil to crops. The main objective of this research was to evaluate remediation efficiency of two chemical amendments, lime and steel slag, and to decide extractant for assessing bioavailability of heavy metals. In order to select optimum extractant for evaluating bioavailability of heavy metals, four different single extractants, HCl, DTPA, $CaCl_2$, $NH_4NO_3$, and sequential extraction method were examined. Both chemical amendments showed high immobilization effect for Cd (66%, $33.62mg\;kg^{-1}$) and Pb (74%, $27.65mg\;kg^{-1}$) in soil by HCl extractant. In terms of heavy metal concentration in rice grains, concentrations for Cd (77%, $0.023mg\;kg^{-1}$) and Pb (82%, $0.039mg\;kg^{-1}$) decreased, with addition of chemical amendments. HCl, DTPA, and sequential extractant showed the higher correlation between heavy metal concentration in soil and crops than others. These results indicated that they could be used for assessing bioavailability of heavy metals.

• Korean Journal of Soil Science and Fertilizer
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• v.45 no.6
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• pp.961-967
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• 2012

There have been many studies about efficiency of amendments for heavy metal stabilization through chemical assessment. The objective of this study was to evaluate the efficiency of several soil amendments (lime, agric-lime, dolomite, steel slag, fly ash and acid mine drainage sludge) on heavy metals stabilization through not only chemical but also biological assessments (phytotoxicity test) in abandoned mining area soil. In order to achieve the goal, we conducted preliminary screening experiment targeting 12 types of crop plants such as radish, young radish, chinese cabbage, winter grown cabbage, cabbage, bok choy, chicory, crown daisy, carrot, chives, spinach, and spring onion. The results of inhibition rates of early plant growth in metal-contaminated soil against non-contaminated soil and the correlations between inhibitions items showed that the bok choy was appropriate specie with respect to confirm the effect of several amendments. Several amendment treatments on contaminated soil brought about the changes in the root and shoot elongation of bok choy after 1 week. Agric-lime, dolomite and steel slag treatments showed the great efficiency of reducing on mobility of heavy metals using chemical assessment. But in contrary, these treatments resulted in the reduction of root and shoot elongation and only AMD sludge increased that of elongation, significantly. When considering both chemical and biological assessments, AMD sludge could be recommended the compatible amendment for target contaminated soil. In conclusion, biological assessment was also important aspect of decision of successful soil remediation.

• Korean Journal of Soil Science and Fertilizer
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• v.44 no.6
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• pp.1052-1062
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• 2011

Residual of heavy metals originated from abandoned metal mines in agricultural field can cause adverse effect on ecosystem and eventually on human health. For this reason, remediation of heavy metal contaminated agriculture field is a critical issue. In this study, five different amendments, agriculture lime, dolomite, steel slag, zeolite, and compost, were evaluated for stabilization efficiency of heavy metals in agricultural field. Applied mixing ratio of amendments was varied (2% or 6%) depending on properties of amendments. Result showed that soil pH was increased compared to control (6.1-6.7) after mixing with amendments and ordered as dolomite (7.2~8.3) > steel slag (6.7~8.1) > agriculture lime (6.6~7.4) > zeolite (6.2~6.9) > compost (6.1~7.1). Among other amendments, agriculture lime, steel slag, and dolomite showed the highest stabilization efficiency of heavy metals in soil. For Cd, stabilization efficiency was 49~72%, 51~83%, and 0~36% for agriculture lime, steel slag, and dolomite respectively. In case of Pb, 43~64, 37~73%, and 51~73% of stabilization efficiency was observed for agriculture lime, steel slag, and dolomite respectively. However, minimal effect of heavy metal stabilization was observed for zeolite and compost. Based on result of this study, amendments that can increase the soil pH were the most efficient to stabilize heavy metal residuals and can be adapted for remediation purpose in agricultural field.

• Korean Journal of Environmental Agriculture
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• v.17 no.2
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• pp.164-169
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• 1998

In order to evaluate the utility of the bituminous coal fly ash, gypsum, oyster shell as soil amendments, acid sandy loam soil with low boron content were amended in the upper 15cm with amendments, and then chinese cabbage was cultivated in fall. Amendments treated were, in metric tons per hectare, i ) none(Check) ; ii) 80 fly ash(FA) ; iii) 4shell(SH) ; iv) 56 fly ash+24gypsum (FG) ; v) 40 fiy ash + 24 gypsum +0.8 shell(FGS). On the whole, amendments imoroved soil chemical properties and contents of N, P, K, Ca, and B in leaves. Among treatmens, FA prominently neutralized soil pH and increased available $P_2O_5$ ,B but decreased Fe contents in soils. FGS also affected the increment of exchangeable Ca, Mg, and available B. Yield response in fresh weight of chinese cabbage was in order of 85% for FGS>77% for FG>66% FA>5% for SH plants. Reducing sugar and vitamin-C contents of leaves depending on treatments showed the same tendencies as that in yields, whereas crude fiber opposite to theme. In particular, FA, FG, and FGS plants showed normal growth without boron deficiency symotoms which appeared in Check and SH plants.Taken together, FGS was an effective combination enable to maximize the utility of fly ash, gypsum, and shell as soil amemdments, especially in cabbage yield and quality.

• Journal of the Korean Chemical Society
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• v.19 no.4
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• pp.258-268
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• 1975

The physical and chemical characteristics of solid organic wastes from paper and pulp industries, tanneries, and food processing industries were studied with regard to fertilizer value as well as humus sources as a rational method of waste utilization. The pulp and paper mill wastes containing low mineral nutrients but high lignin may be utilized for soil amendments through humus preparation. Chemical treatment sludges of tannery wast water contained appreciable fertilizer nutrients andiliming materials, but utilization as fertilizers or soil amendments depends on the pollution effect of high chromium content, which has not been well understood. Food processing wastes may be utilized as organic fertilizers or micronutrient sources for plant. Some wastes containing high water-soluble sugars or lower C/N ratio than 20 may be utilized as additives for rapid humus preparation.

• Korean Journal of Soil Science and Fertilizer
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• v.21 no.1
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• pp.3-10
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• 1988

A laboratory study was carried out to investigate the effects of application level of soil amendments, mixing method of soil amendments, and compost treatment on desalinization by examining the changes in hydraulic conductivity and chemical properties of effluent of the soil during desalinization. 1. The treatment of soil amendments brought about the increase in hydraulic conductivity. 2. The higher the application level of a soil amendment, the higher the hydraulic conductivity and the shorter the time elapsed to complete the desalinization. 3. Complete mixing of calcium compounds was more effective for desalinization than surface mixing. 4. The compost treatment induced the rise in pH and therefore brought about the remarkable drop in hydraulic conductivity. 5. During the desalinization, the changes in physical and chemical properties of the soil were influenced by the kind and application level of soil amendments, mixing method of soil amendment, and compost treatment.

• Advances in environmental research
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• v.6 no.1
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• pp.15-23
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• 2017

Powdered marble wastes (PMW) generated by Utique marble cutting industries (North of Tunisia) with abundant amounts were used in this study as low-cost materials to investigate the stabilization of heavy metals (Pb, Zn, Fe) in sludge generated from a local Zn-Electroplating factory. Powdered marble wastes were evaluated by means of chemical fractions of heavy metals in sludge and concentrations of heavy metals in leachate from columns to determine their ability to stabilize heavy metals in contaminated sludge. Results indicated that chemical fractions of heavy metals in sludge were affected by application of the PMW mineral materials and pH, however, the effects varied with heavy metals. Application of the powdered marble wastes mineral materials reduced exchangeable metals in the sequence of Pb (60.5%)>Fe (40.5%)>Zn (30.1%). X-ray diffraction and hydro-geochemical transport code PHREEQC analysis were successfully carried out to get a better understanding of the mechanisms of reactive mineral phases involved in reduced exchangeable heavy metals in sludge after PMW material amendments. Therefore, metal immobilization using powdered marble wastes materials is an effective stabilization technique for industrial metallic hydroxide sludge.