• Journal of Mechanical Science and Technology
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• v.16 no.12
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• pp.1652-1663
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• 2002

It is desirable to perform nondestructive evaluation to assess material properties and part homogeneity because manufacturing of carbon/carbon (C/C) composites requires complicated and costly processes. In this work several ultrasonic techniques were applied to carbon/carbon composites for the evaluation of spatial variations in material properties that are attributable to the manufacturing process. In a large carbon/carbon composite manufactured by chemical vapor infiltration (CVI) method, the spatial variation of ultrasonic velocity was measured and found to be consistent with the densification behavior in CVI process in order to increase the density of C/C composites. Ultrasonic velocity and attenuation depend on a density variation of materials. Low frequency through-transmission scans based on both amplitude and time-of-flight of the ultrasonic pulse were used for mapping out the material property inhomogeneity These results were compared with that obtained by dry-coupling ultrasonics. Pulse-echo C-scans was used to image near-surface material property anomalies such as the placement of spacers between disks during CVI. Also, optical micrograph had been examined on the surface of C/C composites using a destructive way.

• Journal of the Semiconductor & Display Technology
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• v.14 no.2
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• pp.61-65
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• 2015

SiC composite materials are usually used to very high temperature condition such as thermal protection system materials at space vehicles, combustion chambers or engine nozzles because they have high specific strength and good thermal properties at high temperature. One of the most widely used fabrication methods of SiC composites is the chemical vapor infiltration (CVI) process. During the process, chemical gases including Si are introduced into porous preform which is made by carbon fibers for infiltration. Since the processes take a very long time, it is important to reduce the process time in designing the reactors and processes. In this study, both the gas flow and heat transfer in the reactors during the processes are analyzed using a computational fluid dynamics method in order to design reactors and processes for uniform, high quality SiC composites. Effects of flow rate and heater temperature as process parameters to the infiltration process were examined.

• Composites Research
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• v.30 no.2
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• pp.108-115
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• 2017

Among several fabrication processes of $SiC_f/SiC$ composites, the chemical vapor infiltration (CVI) process has attractive advantages in manufacturing complex net-or near-net-shape components at relatively low temperatures, easily controlling the microstructure of the matrix and obtaining the highest SiC purity level. However, it has disadvantages in that the ratio of residual pores in matrix is higher than other processes and processing time is relatively long. To reduce the residual porosity, the whisker-growing-assisted CVI process, which is composed of whisker growth and matrix filling steps has been developed. The whiskers grown before matrix filling may serve to divide the large natural pores between the fibers or bundles so that the matrix can be effectively filled into the finely divided pores. In this paper, the fundamentals of the CVI process for preparation of $SiC_f/SiC$ composites and some experimental results prepared by CVI and whisker-growing-assisted CVI processes are briefly introduced.

• Journal of the Korean Ceramic Society
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• v.41 no.7
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• pp.518-527
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• 2004

In this study, SiC whiskers were grown in porous alumina substrate in order to enhance the filtering efficiency, performance, and durability by controlling pore morphology. This experiment was performed by Chemical Vapor Infiltration (CVI) in order to obtain the whiskers on the inside of pores as well as on the surface of porous the A1$_2$O$_3$ substrate. The deposition behavior was changed remarkably with the deposition position, temperature, and input gas ratio. First, the mean diameter of whisker was decreased as the position of observation moved into the inside of substrate due to the reactant gas depletion effect'. Second, the deposition temperature caused the changes of the deposition type such as debris, whiskers and films and the change in morphology affect the various properties. When SiC films were deposited. the gas permeability and the specific surface area decreased. However, the whisker showed the opposite result. The whiskers increase not only the specific surface area and minimizing pressure drop but also mechanical strength. Therefore it is expected that the porous alumina body which deposited the SiC whisker is the promising material for the filter trapping the particles.

• Journal of the Korea Institute of Military Science and Technology
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• v.3 no.2
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• pp.244-249
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• 2000

Thermal gradient chemical vapor infiltration (TG-CVI) process, which is one of the CVI techniques to densify a porous fiber preform, requires for a heater to have uniform surface temperature distribution. Thus, it is essential to design the shape of the heater and to predict the temperature distribution when the heater has a profile which is not a simple cylinder. In this study, an analytical method has been used to design the inner profile of a conical heater showing uniform temperature distribution, if its outer shape is specified. Temperature distribution on the heater surface has been calculated with the finite difference method and compared with the experimental results. When a heater had a combined profile with a large cone and a small cylinder, temperature was higher in the cylindrical part. To reduce the temperature difference between these areas, a hole-machining method has been proposed including other possible ones. A shape design and optimization program has been made to improve the temperature uniformity of the TG-CVI heater better than that designed with the analytical method.

• Journal of the Korean Ceramic Society
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• v.45 no.2
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• pp.132-137
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• 2008

The main purpose of this study is enhancing the filtering efficiency, performance and durability of filter by growing SiC whiskers on cordierite honeycomb substrate. The experiment was performed by Chemical Vapor Infiltration (CVI) in order to control pore morphology of substrate. Increasing the mechanical strength of porous substrate is one of important issues. The formation of "networking structure" in the pore of porous substrate increased mechanical strength. The high pressure gas injection to the specimen showed that a little of whiskers were separated from substrate but additional film coating enhanced the stability of whisker at high pressure gas injection. Particle trap test was performed. More nano-particle was trapped by whisker growth at the pore of substrate. Therefore it is expected that the porous cordierite which deposited the SiC whisker will be the promising material for the application as filter trapping the nano-particles.

• Composites Research
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• v.34 no.4
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• pp.249-256
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• 2021

In this paper, the densification of a carbon/carbon composite during a chemical vapor infiltration (CVI) process is studied using a chemo-mechanical model. The multi-physics numerical model, developed in the previous research, couples computational fluid dynamics and major chemical reactions in the reactor. The model is especially utilized to study the effect of flow behavior around the preform on the densification. Four different types of "flow-guide" structures are placed to alter the gas flow around the preform. It is shown that the flow pattern and speed around the preform can be controlled by the guide structures. The process simulations demonstrate that the average density and/or density distribution of the preform can be improved by controlling the gas flow around the perform. In this study, a full industrial-scale reactor and process parameter were used.

• Carbon letters
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• v.8 no.1
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• pp.25-29
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• 2007

The carbon brake discs were manufactured by densification the carbon fiber preform using PG-CVI technology with Propene as a carbon precursor gas and Nitrogen as a carrier gas. The densities of carbon brake discs were tested at different densification time. The results indicate that the densification rate is more rapid before 100 hrs than after 200 hrs. The CTscanning image and the SEM technology were used to observe the inner subtle structure. CT-images show the density distribution in the carbon brake disc clearly. The carbon brake disk made by PG-CVI is not very uniform. There is a density gradient in the bulk. The high-density part in the carbon brake is really located in the friction surface, especially in the part of inner circle. This density distribution is most suitable for the stator disc.

• Journal of the Korean Ceramic Society
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• v.30 no.7
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• pp.549-556
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• 1993

Interfacial shear strength plays an important role in determining the mechanical properties of a fiber-reinforced ceramic composites. In this study, the effect ofinterlayer thickness on mechanical properties of Nicalon-fiber-reinforced SiC composites fabricated via polymer solution infiltration/chemical vapor infiltration (PSI/CVI) was studied. It was found that the flexural strength and fracture toughness of the composites were increased with the interlayer thickness and showed maximum value at the interlayer thickness of 0.66${\mu}{\textrm}{m}$. Typical flexural strength and fracture toughness of Nicalon-fiber-reinforced SiC composites with interlayer thickness of 0.66${\mu}{\textrm}{m}$ were 391.7$\pm$34.6MPa and 15.1$\pm$1.8MPa.m1/2, respectively.

• Applied Chemistry for Engineering
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• v.10 no.6
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• pp.843-847
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• 1999

In this research, C/SiC composites, i.e. activated carbon coated with SiC obtained from dichlorodimethylsilane(DDS) and hydrogen, have been made by chemical vapor infiltration(CVI) in a fluidized bed reactor. Activated carbons of sizes of 4~12, 12~20, and 20~40 mesh were used. After deposition the surface area, the amount and the shape of deposit of each sample were observed at different concentrations of reactant DDS, sizes of activated carbon, reaction pressures and reaction times. The experimental results showed that uniform deposition in the pores of sample was obtained at a lower concentration of DDS and a lower pressure. Additionally, from the observation that the pore diameter and the surface area have minimum values at a certain time of deposition, it was known that deposition occurred inside of the pore at first and then on the outside of particle. Small particles of SiC were deposited uniformly on the surface of activated carbon at lower DDS concentrations and lower reaction pressures. The results were confirmed by SEM, TGA, the pore size distribution analyzer and BET.