• Korean Chemical Engineering Research
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• v.58 no.3
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• pp.424-429
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• 2020

An Energy Storage System (ESS) is recently drawing an increasing attention as an efficient tool to cope with variation in the energy system. In order to take the best utilization of ESS, the inherent variation of energy supply and demand should be properly addressed. This paper is concerned with computing the stochastic capacity of ESS in the face of such variations by way of Monte Carlo simulation. The issue of uncertainty in energy systems will be given further focus. More works are expected to be followed to address the issues in academia and industry.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.22 no.1
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• pp.82-90
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• 2012

Objectives: This study was performed to provide workplaces with political guidelines that apply international CMRs (Carcinogens, Mutagens, Reproductive toxins) information to Public Notice of TLVs (Threshold Limit Values). We analyzed information supply status about CMRs of international agencies and compared substances for which TLVs are set in KMoEL (Ministry of Employment and Labor in Korea). Methods: We referred to the reliable literature about classification criteria of CMRs corresponding to UN GHS (Globally Harmonized System of classification and Labeling of chemicals) and Public Notice No. 2009-68 'Standard for Classification, Labeling of Chemical Substance and Material Safety Data Sheet' in KMoEL. The classification system of CMRs in professional organizations (IARC, NTP, ACGIH, EU ECHA, KMoEL, etc.) was investigated through the internet and literature. Conclusions: 191 chemical substances among total 650 substances with TLVs are classified as carcinogens. Also, 43 substances classified as mutagens, and 44 as reproductive toxicants. These results suggest that the information of CMRs in Public Notice of TLV will be reorganized to 191 carcinogens, 43 mutagens, and 44 reproductive toxicants.

• Transactions of the Korean Society of Automotive Engineers
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• v.5 no.3
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• pp.15-26
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• 1997

In this study, the theoretical investigation of the electrically heated catalyst(EHC) for vehicle application has been carried out using the thermal equivalence of EHC system and the data of vehicle tests to meet ultra low emission vehicle(ULEV) standard. To improve the efficiency of EHC system, it is necessary to understand relation between the power, the operating time and the conversion efficiency of EHC system. The relation was found with thermal equivalence of EHC system which considers the power supply to EHC, heat loss, chemical exothermic energy generated by oxidation reaction and net energy coming in via the exhaust gas. From this relation, the limits of needful power and operating time to meet the ULEV standard can be suggested, when the conversion efficiency of catalyst was known.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2006.11a
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• pp.143-146
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• 2006

There has been growing concern regarding IAQ(Indoor Air Quality) recently, and IAQ problems from the air-tightness and use of chemical materials addition to the building materials have become increasingly important factors in the built environment. Ventilation is supposed as the solution of healthy indoor quality, and Korea government requests that all new apartment buildings must have a ventilation system as a matter of duty since January, 2006. The purpose of this study is to investigate the indoor concentration change of VOCs include the Formaldehyde according to many different ventilation supply types. Results showed that the reduction effect of target pollutants by the ventilation system was very slight. The cause of these results was attribute to increase the emission rate of building materials by increasing the ventilation rate.

• Journal of Korean Society on Water Environment
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• v.24 no.4
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• pp.458-464
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• 2008

Bulking phenomena and scum formation are common problem in suspended growth system like the activated sludge plants for wastewater treatment. Apart from wastewater composition, operating conditions, such as mechanical stress by insufficient oxygen supply, are often decisive for the occurrence of a bulking or scumming problem. There were the comparative aeration tanks in terms of sludge bulking caused by the difference of mechanical aeration facilities in the wastewater treatment plant of N paper mill company. In this study the cause of bulking was investigated through not only the biological isolation and identification but also a series of operational data consideration. On the basis of the investigation results for bulking cause, the operational criteria on dissolved oxygen concentration was derived to decrease the bulking problem.

• Bulletin of the Korean Chemical Society
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• v.28 no.5
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• pp.800-804
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• 2007

Cyanobacterial toxins, microcystins are very potent hepatotoxins and their occurrence has been reported all over the world. They could threaten human health when toxic Microcystis occurs in water supply reservoirs. In this study, the effects of several environmental factors on production and degradation of toxins produced by cyanobacteria in Lake Soyang have been studied. A new rapid quantification method of microcystins using fluorescence for a detection signal and a lateral-flow-type immunochromatography as a separation system was used. Culture age, temperature, light intensity, pH, N-nutrient concentration, P-nutrient concentration, iron and zinc concentration were the most importantly examined factors. The toxin content was the highest on 17-18 days and at temperatures between 20℃ and 25℃, and at pH between 8.4 and 8.8.

• Bulletin of the Korean Chemical Society
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• v.17 no.3
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• pp.254-257
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• 1996

Nucleophilic substitution reactions of 1- and 2-naphthylethyl arenesulfonates, 2 and 3, with anilines and benzylamines in methanol at 65.0 ℃ are investigated. The rates are slower than those for the corresponding derivatives of 2-phenylethyl arenesulfonates, 1, which can be attributed to a greater degree of positive charge stabilization at Cα in the transition state (TS) by a greater electron supply from a phenyl ring compared to a naphthyl ring. The mechanism for the two naphthylethyl systems are similar to that for the 2-phenylethyl derivatives, except that the transition state is formed at somewhat an earlier position along the reaction coordinate. The secondary kinetic isotope effects involving deuterated nucleophilies indicate that naphthylethyl series are sterically more crowded in the TS than 2-phenylethyl system. The data in this work can not elucidate the possible participation of the aryl-assisted pathway in the reaction.

• Journal of Korean Society of Environmental Engineers
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• v.22 no.11
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• pp.1945-1954
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• 2000

This study provides economical installation capacities for wastewater reclamation and reusing system in 7 areas of South Korea applying to contact aeration process using NPV(net present value) model based on cost-benefit. First. considering only private benefits. economical installation capacities for wastewater reclamation and reusing system applying to contact aeration process in household use were more than $500m^3/day$ in Pusan. $1,000m^3/day$ in Taegu. $2,000m^3/day$ in Kwangju. However. installation capacities in Seoul. Inchen, Taejon, and Ulsan were not optimal for $3,000m^3/day$. Therefore, supply ways of wastewater reclamation and reusing system in household use in the latter areas were more optimal local recirculation system than individual recirculation system. Economical installation capacities for wastewater reclamation and reusing system in business use were more than $100m^3/day$ in Seoul. Pusan. and Kwangju and which were $300m^3/day$ in Taegu, Inchen, Taejon, and Ulsan. Economical installation capacities for wastewater reclamation and reusing system in commercial use were more than $100m^3/day$ in Seoul, Pusan, Taegu, Kwangju, Taejon, and Ulsan, and which were $300m^3/day$ in Inchen. Second, considering only social benefits. economical installation capacity for wastewater reclamation and reusing system applying to contact aeration process was more than $100m^3/day$.

• Journal of Institute of Control, Robotics and Systems
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• v.6 no.12
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• pp.1113-1119
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• 2000

To operate a process plant safely and economically, process monitoring is very important. Process monitoring is the task to identify the state of the system from sensor data. Process monitoring includes data acquisition, regulatory control, data reconciliation, fault detection, etc. This research focuses on the data recon-ciliation using scale-space filtering and fault detection using functional-link associative neural networks. Scale-space filtering is a multi-resolution signal analysis method. Scale-space filtering can extract highest frequency factors(noise) effectively. But scale-space filtering has too large calculation costs and end effect problems. This research reduces the calculation cost of scale-space filtering by applying the minimum limit to the gaussian kernel. And the end-effect that occurs at the end of the signal of the scale-space filtering is overcome by using extrapolation related with the clustering change detection method. Nonlinear principal component analysis methods using neural network have been reviewed and the separately expanded functional-link associative neural network is proposed for chemical process monitoring. The separately expanded functional-link associative neural network has better learning capabilities, generalization abilities and short learning time than the exiting-neural networks. Separately expanded functional-link associative neural network can express a statistical model similar to real process by expanding the input data separately. Combining the proposed methods-modified scale-space filtering and fault detection method using the separately expanded functional-link associative neural network-a process monitoring system is proposed in this research. the usefulness of the proposed method is proven by its application a boiler water supply unit.

• Applied Chemistry for Engineering
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• v.30 no.6
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• pp.687-693
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• 2019

As the hydrogen fuel cell market is expanded starting from hydrogen electric vehicle and power generation field, the demand for fuel cells and hydrogen increases recently. Therefore, research works on fuel cell durability and fuel efficiency are required in order to activate the fuel cell market and commercialization. A dead-ended anode system was used in this study to optimize the fuel cell performance and fuel efficiency. The effect of purge condition according to the applied current and hydrogen supply pressure on the fuel cell performance were evaluated. In addition, the influence of water back diffusion on the different electrolyte membrane thickness was analyzed. The accumulated water was purged with a solenoid valve in the case of 3% voltage decrease in the dead-ended anode system. The experiment was performed with the hydrogen supply pressure of 0.1~0.5 bar and purge duration of 0.1~1 second. A maximum fuel efficiency of 98.9% was achieved under the purge duration of 0.1 s and hydrogen supply pressure of 0.1 bar with a NR 211 (25.4 um) membrane. However, the fuel cell performance decreased in a long-term operation due to some frequent flooding. The fuel efficiency and purge interval increased due to decreased back diffusion rates of the water and nitrogen with a NR 212 (50.8 um) membrane.