• Title/Summary/Keyword: Chemical Durability

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Evaluation of Physico-Mechanical Properties and Durability of Larix kaempferi Wood Heat-Treated by Hot Air (고온 열기 처리에 의한 낙엽송재의 물리·역학적 성능 및 내부후성능 변화 고찰)

  • Park, Yonggun;Han, Yeonjung;Park, Jun-Ho;Chang, Yoon-Seong;Yang, Sang-Yun;Chung, Hyunwoo;Kim, Kyungjung;Yeo, Hwanmyeong
    • Journal of the Korean Wood Science and Technology
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    • v.43 no.3
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    • pp.334-343
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    • 2015
  • This study was carried out to evaluate quantitatively some properties (density, equilibrium moisture content, shrinkage, water vapor adsorption, water absorptivity, compressive strength, bending strength, hardness and decay resistance) of Larix kaempferi lumber which was heat-treated by hot air and has been used commercially in Korea. Equilibrium moisture content of the heat-treated wood was decreased with increase of hydrophobicity. Dimensional stability of the wood was improved with decrease of shrinkage, water vapor adsorption and free water absorptivity. Also, with the thermo-chemical changes of wood component and lower equilibrium moisture content, decay resistance and compressive strength of heat-treated wood were increased. But, bending strength and hardness of wood were decreased.

Development of the Integrated Fuel Cell Monitoring System (통합 연료전지모니터링 시스템 개발)

  • KIM, HYUNJUN;YEOM, SANGCHUL;AHN, BYUNGKI;KIM, SAEHOON;KUM, YEONGBEOM
    • Transactions of the Korean hydrogen and new energy society
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    • v.26 no.3
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    • pp.241-246
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    • 2015
  • The interest of New Renewable Energy is increasing globally because of the increment of the uncertainty for the energy's supply and demand, and the increment of the frequency in weather anomaly and its damages. One of the New Renewable Energies, Hydrogen receives attention as the future energy that can deal with global environment regulation. Fuel Cell Electric Vehicle (FCEV) is an environment-friendly vehicle that uses Hydrogen as fuel. The electric power for FCEV is generated by chemical reaction with Oxygen from the air and Hydrogen. Hyundai Motor Company (HMC) has developed a proprietary fuel cell system since 2005. In 2012, HMC is the first car maker that mass-produces the ix35 FCEV to the worldwide such as North America, Europe, etc. In order to develop and improve the FCEV technology, data acquisition and analysis of the driving vehicle information is essential. Therefore, the monitoring system is developed, which is consist of datalogger, Automatic Vehicle Location (AVL) server and main server. Especially, WCDMA technology is integrated into the system which enables the data analysis without any restriction of time and region. The main function of the system is the analysis of the driving pattern and the component durability, and the safety monitoring. As a result, ix35 FCEV has successfully developed by using the developed monitoring system. The system is going to take an advantage of development in the future FCEV technology.

Experimental Study on the Gel time of Acryl Gel According to a Catalyzer quantity (촉매제의 양에 따른 아크릴 겔의 겔화시간에 관한 실험적 연구)

  • Han, Sang-Il;Lee, Dae-Geun;Choi, Duck-Jin;Yoon, Kung-Suk;You, Chang-You;Kim, Jin-Man
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.449-452
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    • 2008
  • Reinforced concrete structure with supplementary relation is a distinguished material. But in this structure, crack is generated by many factors and caused decadence of durability, safety, function, and so on. Hence structure is in need of repair. Preexistence injection of chemical grouting for using repair of crack not enough performance. In this study, Setting time test of Acryl Gel was carried out According to a Catalyzer quantity. The result of test showed that gel time of Acryl Gel decreased with the increased of catalyzer quantity. The result of this study could be used as the basic data for the repair of crack using Acryl Gel.

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Radioactive Wastes Vitrification Using Induction Cold Crucible Melter: Characteristics of Vitrified Form (유도 가열식 저온용융로를 이용한 방사성페기물 유리화: 유리 고화체 특성)

  • 김천우;박은정;최종락;지평국;최관식;맹성준;박종길;신상운;송명재
    • Journal of the Korean Ceramic Society
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    • v.39 no.6
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    • pp.576-581
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    • 2002
  • In order to simultaneously vitrify the ton Exchange Resin(IER) and Dry Active Waste(DAW) generated from the Nuclear Power Plants, a vitrification pilot test was conducted using an induction cold crucible melter. The PCT result evaluating the chemical durability of the vitrified from showed that the final glass was more durable than the benchmark glass. Liquidus temperature for the final vitrified form was 1048 K(775$\^{C}$) fur heat treatment experiments. The value of the compressive strength for the vitrified form was ninety times higher than the regulation limit, 34 kg/㎠. The glasses on bottom, middle and top of the CCM were homogeneous with no secondary phase. The precipitation of the magnetic metal phase was able to be avoided by simultaneously fEeding of DAW with IER containing strongly reducing organics. Volume reduction factor of 74 was achieved through the vitrification Pilot test for mixed waste.

Performance of Ru-based Preferential Oxidation Catalyst and Natural Gas Fuel Processing System for 1 kW Class PEMFCs System (Ru계 촉매의 CO 선택적 산화 반응 및 1 kW급 천연가스 연료처리 시스템의 성능 연구)

  • Seo, Yu-Taek;Seo, Dong-Joo;Seo, Young-Seog;Roh, Hyun-Seog;Jeong, Jin-Hyeok;Yoon, Wang-Lai
    • Transactions of the Korean hydrogen and new energy society
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    • v.17 no.3
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    • pp.293-300
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    • 2006
  • KIER has been developing a Ru-based preferential oxidation catalysts and a novel fuel processing system to provide hydrogen rich gas to residential PEMFCs system. The catalytic activity of Ru-based catalysts was investigated at different Ru loading amount and different support structure. The obtained result indicated that 2 wt% loaded Ru-based catalyst supported on ${\alpha}-Al_2O_3$ showed high activity in low temperature range and suppressed the methanation reaction. The developed prototype fuel processor showed thermal efficiency of 78% as a HHV basis with methane conversion of 92%. CO concentration below 10 ppm in the produced gas is achieved with separate preferential oxidation unit under the condition of $[O_2]/[CO]=2.0$. The partial load operation have been carried out to test the performance of fuel processor from 40% to 80% load, showing stable methane conversion and CO concentration below 10 ppm. The durability test for the daily start-stop and 8 h operation procedure is under investigation and shows no deterioration of its performance after 50 start-stop cycles. In addition to the system design and development.

Effects of Substituting B2O3 for P2O5 on the Structure and Properties of SnO-P2O5 Glass Systems (SnO-P2O5계 유리에서 P2O5를 B2O3로 치환시 구조와 물성에 미치는 영향)

  • Kim, Dong-Hwan;Hwang, Cha-Won;Kim, Nam-Jin;Im, Sang-Hyeok;Gwoo, Dong-Gun;Kim, Tae-Hee;Cha, Jae-Min;Ryu, Bong-Ki
    • Journal of the Korean Ceramic Society
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    • v.48 no.1
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    • pp.63-68
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    • 2011
  • The investigation is directed to lead free (Pb-free) frits that can be used for organic light emitting diode, plasma display screen devices and other sealing materials. $P_2O_5$-SnO system glasses have been prepared for Pb-free low temperature glass frit. Structure and properties of the glasses with the composition SnO-$xB_2O_3-(60-x)P_2O_5$ (x=0, 5, 10, 15, 20, 25, 30, 35, 40 mol%) were characterized by infrared spectra (IR), X-ray diffraction(XRD), Density, Molar volume, Thermo mechanical analysis(TMA) and weight loss after immersion test. Glass transition temperature($T_g$), dilatometric softening temperature($T_d$) and chemical durability increased, and coefficient of thermal expansion($\alpha$) decrease with the substitution of $B_2O_3$ for $P_2O_5$ in the range of 0~25 mol%.

Bicomponent Finishing of Cotton Fabrics(I) -Loess and Chitosan- (면의 복합가공(I) -황토와 키토산-)

  • Bae, Ki-Hyun;Kwon, Jung-Sook;Lee, Shin-Hee
    • Fashion & Textile Research Journal
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    • v.10 no.4
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    • pp.552-559
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    • 2008
  • Recent days, various inner wears, sheets and interior goods are manufactured using materials dyed with loess emphasizing its improved blood circulation, metabolism, anti-bacterial, deodorizing properties, and far-infrared ray emissions. The purpose of this study is to investigate the effect of chitosan treatment on the dyeing of cotton fabric using loess as colorants. Particle size of loess, the morphology and dyeability(K/S) of chitosan crosslinked cotton fabrics, and washing durability of loess dyed cotton fabric were investigated. In this study, cotton fabrics were treated with a crosslinking agent, epichlorohydrin, in the presence of chitosan to improve the dyeing properties of cotton fabrics with natural dye by the chemical linking of chitosan to the cellulose structure. This process was applied by means of the conventional mercerizing process. The results obtained were as follows; Mean average diameter of loess was $1.13{\mu}m$. According to various conditions, the optimum dyeing conditions for cotton fabrics pretreated by 1% chitosan treatment was where 10%(owb) of loess was applied at $90^{\circ}C$ for 120minutes, while for cotton fabrics without chitosan treatment was where 15%(owb) of loess was applied at $90^{\circ}C$ for 150minutes. Overall, K/S value of loess dyed cotton fabric pretreated with 1% chitosan was higher than that of cotton fabrics without chitosan treatment. The Color fastness, washing fastness and light fastness of loess were excellent as 4-5grade.

Enhancement of the Characteristics of Cement Matrix by the Accelerated Carbonation Reaction of Portlandite with Supercritical Carbon Dioxide

  • Kim, In-Tae;Kim, Hwan-Young;Park, Geun-Il;Yoo, Jae-Hyung;Kim, Joon-Hyung;Seo, Yong-Chil
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.586-591
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    • 2001
  • This research investigated the feasibility of the accelerated carbonation of cement waste forms with carbon dioxide in a supercritical state. Hydraulic cement has been used as a main solidification matrix for the immobilization of radioactive and/or hazardous wastes. As a result of the hydration reaction for major compounds of portland cement, portlandite (Ca(OH)$_2$) is present in the hydrated cement waste form. The chemical durability of a cement form is expected to increase by converting portlandite to the less soluble calcite (CaCO$_3$). For a faster reaction of portlandite with carbon dioxide, SCCD (supercritical carbon dioxide) rather than gaseous $CO_2$, in ambient pressure is used. The cement forms fabricated with an addition of slated lime or Na-bentonite were cured under ambient conditions for 28days and then treated with SCCD in an autoclave maintained at 34$^{\circ}C$ and 80atm. After SCCD treatment, the physicochemical properties of cement matrices were analyzed to evaluate the effectiveness of accelerated carbonation reaction. Conversion of parts of portlandite to calcite by the carbonation reaction with SCCD was verified by XRD (X-ray diffraction) analysis and the composition of portlandite and calcite was estimated using thermogravimetric (TG) data. After SCCD treatment, tile cement density slightly increased by about 1.5% regardless of the SCCD treatment time. The leaching behavior of cement, tested in accordance with an ISO leach test method at 7$0^{\circ}C$ for over 300 days, showed a proportional relationship to the square root of the leaching time, so the major leaching mechanism of cement matrix was diffusion controlled. The cumulative fraction leached (CFL) of calcium decreased by more than 50% after SCCD treatment. It might be concluded that the enhancement of the characteristics of a cement matrix by an accelerated carbonation reaction with SCCD is possible to some extent.

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Characteristics of Asphalt Concrete using Waste Foundry Sand (주물고사 첨가 아스팔트 콘크리트의 특성에 관한 연구)

  • Kim, Kwang-Woo;Ko, Dong-Hyuk;Choi, Dong-Chon;Kim, Sung-Won;Kim, Joong-Yul
    • International Journal of Highway Engineering
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    • v.3 no.4 s.10
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    • pp.105-116
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    • 2001
  • This study was performed to evaluate the characteristics of waste foundry sand (WFS) and the asphalt mixture made of a foundry waste sand. To estimate the applicability of WFS, chemical and physical properties were measured by XRF(X-ray fluorescent), and SEM(Scanning electronic microfilm). To improve the stripping resistance of WFS asphalt mixture, anti-stripping agents (a hydrated lime and a liquid anti-stripping agent) were used. To improve tensile properties and durability of WFS asphalt concrete mixture, LDPE(low-density polyethylene) was used as an asphalt modifier Marshall mix design, indirect tensile strength, tensile strength ratio(TSR) after freezing and thawing, moisture susceptibility and wheel tracking tests were carried out to evaluate performance of WFS asphalt concrete. Comparing with conventional asphalt concrete, WFS asphalt concretes showed similar or the better qualify in mechanical properties, and satisfied all specification limits. Therefore, it Is concluded that waste foundry sand can be recycled as an asphalt pavement material.

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Controlled Release of Oxyfluorfen from the Variously Complexed Formulations - II. Selection of Promising Formulations (수종(數種) 결합제형(結合劑型)으로부터 Oxyfluorfen의 방출제어(放出制御) 연구(硏究) - II. 유용(有用)한 방출제어형(放出制御型의) 선발(選拔))

  • Guh, J.O.;Im, W.H.;Lim, K.P.;Cho, C.S.;Chung, I.W.
    • Korean Journal of Weed Science
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    • v.10 no.3
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    • pp.207-213
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    • 1990
  • Thirty formulations of oxyfluorfen(2-chloro-2,2,2-trifluoro-p-toyl 3-ethoxy-4-nitrophenyl ether were manufactured by adsorption and substitation. Of them 16 formulations n-ere selected because they showed rekatuvely high activity and long durability in the bioassay with (Brassica campestris V.L.) Then, the formulations selected and 4 commercial formulations were tested using Monochoria in pots. As the result, the formulations of polyer 11, elvan 7/40, coal-slag 7/40, zeolite(A), and bentonite(A) were selected because they showed almost complete inhibition of Monochoria even up the 73 days after treatment.

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