• Title/Summary/Keyword: Chemical Admixture

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Physical and Chemical Properties of Nano-slag Mixed Mortar

  • Her, Jae-Won;Lim, Nam-Gi
    • Journal of the Korea Institute of Building Construction
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    • v.10 no.6
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    • pp.145-154
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    • 2010
  • As buildings have become higher and larger, the use of high performance concrete has increased. With this increase, interest in and use of ultra fine powder admixture is also on the rise. The silica fume and BSF are the admixtures currently being used in Korea. However, silica fume is exclusively import dependent because it is not produced in Korea. In the case of BFS, it greatly improves concrete fluidity and long-term strength. But a problem exists in securing early strength. Furthermore, air-cooled slag is being discarded, buried in landfills, or used as road bed materials because of its low activation energy. Therefore, we investigated in this study the usability of nano-slag (both rapidly-chilled and air-cooled) as an alternative material to the silica fume. We conducted a physic-chemical analysis for the nano-slag powder and performed a mortar test to propose quality standards. The analysis and testing were done to find out the industrial usefulness of the BFS that has been grinded to the nano-level.

The Effect of Limestone Powder Admixture Chemical Properties on Workability and Compressive Strength of Composite Cement (석회석 미분말 혼합재의 화학특성이 혼합시멘트 유동성과 강도에 미치는 영향)

  • Suh, Dong Kyun;You, Byeong Know;Choi, Jae Won;Kim, Kyeong Suk;Woo, Ji Wan
    • Cement Symposium
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    • s.49
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    • pp.29-30
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    • 2022
  • Since the climate problem getting severe, carbon neutrality is rising global issue. The limestone powder addition that can substitute clinker in cement is look forward to get positive effect as filler. This study focus on the effect of limestone powder chemical characteristic on mortar workability and compressive strength. Consequently, regardless of type of limestone and subsitution amount, the compressive strength was lower then OPC. But the workability of limestone composite cement showed higher then OPC. Considering latter strength development, using unit water decreasing effect of limestone composite cement is planned further.

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The Effect of Cement Admixtures on Solidification of Tannery Sludge based Cement Method (피혁슬러지 고형화시 시멘트 혼화제의 영향)

  • 주소영;박상찬;전태성;손종렬;김태영
    • Journal of environmental and Sanitary engineering
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    • v.18 no.4
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    • pp.36-44
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    • 2003
  • The cement-based system among S/S(Solidification/Stabilization) is widely used to treat hazardous wastes. In this study, tannery sludge was solidified to evaluate the stabilization effects of using admixtures in the cement-based S/S. Fly ash as substitute also used to increase the strength of the S/S of hazardous waste. The compressive strength measurement and leaching experiment of chromium metal of solidified mortar were carried out to compare and evaluate the physical and chemical characteristics of solidified hazardous waste sludge. From the result of this study, there was increased of compressive strength by using AEW-3(early-hardening AE water reducing agent), and leaching concentration of chromium became low enough to satisfy the regulatory criteria. The successful solidification for the organic contaminant and heavy metal in hazardous waste should enable to treat by cement-based system using early-hardening AE water reducing admixture and fly ash as substituted cement.

A Study on the Strength Properties of Mortar Under Various Types and Contents of Accelerators for Freezing Resistance (내한촉진제의 종류 및 혼입양 변화에 따른 모르터의 강도특성에 관한 연구)

  • Lee, Sang-Soo;Won, Cheol;Park, Sang-Joon;Kim, Dong-Seok
    • Journal of the Korea Institute of Building Construction
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    • v.2 no.2
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    • pp.151-156
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    • 2002
  • When fresh concrete is exposed to low temperature, the concrete may suffer frost damage due to freezing at early ages and strength development may be delayed. One of the solution methods for resolve these problems is to reduce freezing temperature of concrete by the use of chemical admixture called Accelerators for freezing resistance. In this study, we investigate the effect on strength development of cement mortar using accelerators for freezing resistance with the variance curing condition. As the result of this study, the mortar using accelerators for freezing resistance show that continuously strength development in curing condition of -5$^{\circ}C$. And compressive strength under the variance temperature condition was higher than constant temperature condition in same maturity.

The Effect on Strength Development of Cement Mortar using Accelerators for Freezing Resistance with the Curing Condition (양생조건이 내한촉진제를 사용한 시멘트 모르타르의 강도증진에 미치는 영향에 관한 연구)

  • Won, Cheol;Kim, Dong-Seok;Park, Sang-Joon;Lee, Sang-Soo;Kim, Young-Jin
    • Proceedings of the Korea Concrete Institute Conference
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    • 2001.11a
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    • pp.533-536
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    • 2001
  • When fresh concrete is exposed to low temperature, the concrete may suffer frost damage due to freezing at early ages and strength development may be delayed. One of the solution methods for resolving these problems is to reduce freezing temperature of concrete by the use of chemical admixture called Accelerators for freezing resistance. In this study, we investigate the effect on strength development of cement mortar using accelerators for freezing resistance with the variance curing condition. As the result of this study, the mortar using accelerators for freezing resistance show that continuously strength development in curing condition of -5$^{\circ}C$. And compressive strength under the variance temperature condition was higher than fixed temperature condition in same maturity.

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Modeling of Setting Behavior in Fresh Concrete considering Microstructure Formation

  • Cho, Ho-Jin;Song, Ha-Won;Byun, Keun-Joo
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.05a
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    • pp.490-493
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    • 2004
  • In the analysis of early-age concrete behavior, the fresh concrete is considered as a structural element immediately after mixing. But for the activation of real structural behavior in the fresh concrete, the so-called setting time is necessary a few hours after the beginning of hydration reaction. In this paper, analysis on the setting behavior is carried out by proposing an analytical model based on the percolation theory as well as the expanding cluster model by defining the setting as a microstructure formation in fresh concrete. An experimental investigation is also carried out to show the influences of curing temperature, mineral admixtures and chemical admixture on setting behavior of fresh concrete. Finally, the analytical results using proposed model are compared with the experimental results for the sake of verification.

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Fundamental Properties of Mortar Utilizing Waste Concrete Power (폐콘크리트 분말을 활용한 모르타르의 기초물성에 관한 연구)

  • Choi, Yun-Wang;Moon, Dae-Joong;Kim, Sung-Su;Kim, Ki-Hyung;Moon, Han-Young
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.05a
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    • pp.620-623
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    • 2004
  • Waste concrete powder(WCP) has been estimated with a great value-added material as by-product of waste concrete manufactured to fine and coarse aggregate for concrete, because it is able to utilized for cement clinker and concrete admixture. In the experimental results for this study, chemical composition of WCP was similar to that of cement, and specific gravity of WCPs were 2.46 and 2.48 due to internal micro-void of WCP. Final setting of paste with WCP was delayed, and flow value of mortar with WCP was tendency to reduced in comparison with that of paste and mortar with only ordinary portland cement as replacement ratio of WCP increased. Furthermore, sorptivity of mortar with WCP was increased as replacement ratio of WCP increased. Compressive strength of mortar with $15\%$ WCP was developed about 27MPa at 28days.

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Surface Protection Technique for Durability Improvement of Concrete Structure (내구성 증진을 위한 콘크리트 구조물의 표면보강 방법)

  • Jin, Nan-Ji;Yeon, Kyu-Seok;Joo, Myung-Ki;Baek, Jong-Man;Lee, Youn-Su
    • Proceedings of the Korean Society of Agricultural Engineers Conference
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    • 2002.10a
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    • pp.169-172
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    • 2002
  • In this study, the effects of the number of coat and immersion period on strength properties, waterproofness and chemical resistance of painted and immersed cement mortars using two admixture were examined. Test results showed that the flexural and the compressive strengths of the coated and immersed cement mortars increase with increasing number of coat and immersion period. The water absorption of the coated and immersed cement mortars tended to decrease with increasing number of coated and immersion period. In the case of the change of weight and the immersion period for the solutions, a decreasing tendency was shown as the immersion period increases regardless of solution, with a little variation.

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Optimum Mix Design of Concrete (콘크리트 용도별 최적배합을 위한 연구)

  • 이병덕;양우석;안태성
    • Proceedings of the Korea Concrete Institute Conference
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    • 1999.04a
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    • pp.209-214
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    • 1999
  • Strength provisions in Korea Concrete Institute code are more conservative that those in ACI code by increasing load factors and decreasing capacity reduction factors. Cement content of mix design in construction field is usually higher than the modified for standard deviation because of rigorous inspection. Higher cement content increases not only strengths but also heat of hydration, shrinkage and brittleness which are not beneficial. To reduce and optimize the cement content in current mix design of Korean Highway Corporation, properties of fresh and hardened concrete for 16 different mix proportions have been investigated. It is found that the chemical admixture and cement of current mix proportions for highway construction are somewhat higher than the optimum amount. Therefore, the optimum mix design for 16 different purposes has been proposed.

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The Physical Properties of Cement Containing Melamine-type Superplasticizer obtained Various Synthetic Conditions (다양한 합성조건에서 얻어진 멜라민계 고유동화제가 함유된 시멘트의 물리적 특성)

  • Yoon, Sung-Won;Shin, Kyoung-Ho
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.11a
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    • pp.415-418
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    • 2005
  • Nowadays the three major commercially available of organic chemical admixtures are modified lignosulfonates(LS), sulfonated naphthalene-formaldehyde resins (SNF) and sulfonated melamine-formaldehye (SMF). In this study, various sulfonated melamine-formaldehyde (SMF) superplasticizers were synthesized via four synthetic steps. Hydroxymethylation (Step 1), Sulfonation (Step 2), Polymerization (Step 3) and Neutralization and Stabilization (Step 4). In this synthesis of SMF, reaction conditions such as the mole ratio of melamine to formaldehyde and the amount of acid catalyst were changed. After application of SMF superplasticizer to cement paste and mortar, the physical properties including workability, slump loss, compressive strength were compared.

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