• Title/Summary/Keyword: Chemical Accidents

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Development of Brake Disk Materials with Ni-Cr-Mo (Ni-Cr-Mo계 제동디스크 소재 개발)

  • Goo, Byeong-Choon;Lim, Choong-Hwan
    • Journal of the Korean Society for Railway
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    • v.11 no.2
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    • pp.188-194
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    • 2008
  • Brake disks for rolling stock are exposed to thermal fatigue during braking, and thermal cracks occur on surface of disks. Thermal cracks can cause serious accidents, deterioration of braking performance and increase of maintenance cost due to frequent exchange of friction materials. In this study, candidate materials with high-heat resistance were selected by searching the literature. By using cast specimens made of the candidate materials, chemical composition, crystal structure and graphite type were analyzed. In addition, friction coefficient and wear were measured and compared with values for the disk material in service. As a result, it was shown that the NiCrMo has highest tensile strength and lowest friction coefficient and the disk material in service has the most stable friction characteristics.

A Study on the Measures for Activating the Fire Fighting Safety Education of Elementary School Students - Focusing on the Fire Fighting Science Class of Gyeonggi-do Goyang Fire Station - (초등학생 소방안전교육의 활성화 방안에 관한 연구 - 경기도 고양소방서 소방과학교실을 중심으로 -)

  • Hyun, Seong-Ho;Cha, Jeong-Min;Song, Yun-Suk;Park, Kyung-Hyo
    • Fire Science and Engineering
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    • v.23 no.2
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    • pp.67-77
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    • 2009
  • The purpose of this study is to deal with fire fighting safety education primarily among the fields of child safety education. So, first of all, this study considered the theoretical background of fire fighting safety education. And this study analyzed the present state and cases of safety accidents in elementary schools. And by focusing on the fire fighting science class for elementary schools which Gyeonggi-do Goyang fire station is executing now, this study analyzed the educational outline, present state, educational goal, and content of fire fighting science class, and conducted the satisfaction survey through questionnaire over the elementary school students participating in fire fighting science class and the fire fighting officers in charge of fire fighting science class. On basis of this research, by developing the new field of fire fighting education and publicity into the program which can diffuse the fire fighting-related chemical experiment based on the science of chemistry and physics in the future and so provide the pleasure and surprise of experiencing directly not only natural fire fighting education and publicity but also learning and the common sense of fire fighting, this study tried to present the alternatives about the measures for activating the fire fighting safety education in elementary schools.

A Study on the Fire Risk of Black Box Wiring in Motor Vehicle (자동차의 블랙박스 와이어링 화재 위험성에 관한 연구)

  • Kang, Sin-Dong;Kim, Ju-Hee;Choi, Jun-Pyo;Kim, Jae-Ho
    • Journal of the Korean Society of Safety
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    • v.32 no.6
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    • pp.22-28
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    • 2017
  • According to the National Fire Data System (NFDS), more than 5,000 vehicle fires have occurred every year for the last 10 years. Vehicle fires are primarily caused by mechanical (breaking system and engine), electrical (wiring and battery), and chemical (oil and fuel gas leakage) problems. The electrical factor has increased with the installation of driver convenience equipment. For example, today, the black box is widely used to provide video data recording of motor vehicle accidents. The black box consists of a front camera, rear camera, and wires. The black box wires are directly connected to the junction box or fuse box from the start battery that operates to provide normal on power supplying for engine stop. It is extremely dangerous when the wires short circuit due to insulation aging, mechanical and electrical stress, etc. In this study, the black box wiring fire risk have been analyzed and investigated when the steady state and abnormal operations, and under the following conditions: wiring arrangements with a high temperature condition, insulation aging, poor contact, and short circuits. The results showed that black box wiring short circuits had a higher fire risk than the other fire hazard elements. To prevent fire hazards caused by black box wiring, the black boxes must be installed by qualified service personnel. Do not modify the wiring, remove the fuse and secure the wiring using cable ties or insulation tape.

Addition Effect of the Deposition and Buoyancy Terms in Modeling Turbulence Diffusion of Hazardous Air Pollutants (유해 대기오염물질의 난류확산 수치모의에서 침적한과 부력항 추가에 따른 효과)

  • Won, Gyeong-Mee;Lee, Hwa-Woon;Ji, Hyo-Eun;Kim, Cheol-Hee;Song, Chang-Keun
    • Journal of Korean Society for Atmospheric Environment
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    • v.22 no.1
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    • pp.73-84
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    • 2006
  • Hazardous Air Pollutants (HAPs) are characterized by being relatively heavier and denser than that of ambient air due to the various reasons such as higher molecular weight, low temperature and other complicated chemical transformations (Witlox, 1994). In an effort to investigate transport and diffusion from instantaneous emission of heavy gas, Lagrangian Particle Dispersion Model (LPDM) coupled with the RAMS output was employed. Both deposition process and buoyancy term were added on the atmospheric diffusion equations of LPDM, and the locations and concentrations of dense gas particle released from instantaneous single point source (emitting initially for 10 minutes only) were analyzed. The result overall shows that adding deposition process and buoyancy terms on the diffusion equation of LPDM has very small but detectable effect on the vertical and horizontal distribution of Lagrangian particles that especially transported for a fairly long traveling time. Also the slumping of dense gas can be found to be ignored horizontally compared to the advection by the horizontal wind suggesting that it was essential to couple the Lagrangian particle dispersion model coupled with the RAMS model in order to explain the dispersion of HAPs more accurately. However, during the initial time of instantaneous emission, buoyancy term play an important role on the vertical locations of dense particles for near surface atmosphere and around source area, indicating the importance of densities of HAPs in the beginning stage or short duration for the risk assessment of HAPs or management of heavy vapors during the explosive accidents.

Effects of Adulterants in HCl on Artificial Hatching in the Silkworm Eggs (염산의 협잡물이 잠종의 인공부화에 미치는 영향)

  • 김윤식;김락상
    • Journal of Sericultural and Entomological Science
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    • v.17 no.1
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    • pp.35-39
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    • 1975
  • The acid treatment hatching method has been used practically for about 60 years and a number of investigators have studied about the artificial hatching for silkworm e99s, but the basic theory about the acid treatment hatching is not clarified yet. It is no exaggeration to say that the accidents of non hatching is continued ceaselessly in the silkworm egg by hydrochloric acid treatment. It is believed that the accident is due to the adulterants in HCl lather than inattention of acid treatment. Therefore, the authors mixed hydrochloric acid (analytical grade) with or added it to chemical ingredients which are possible to be included in the process of hydrochloric acid production, and treated it to summer and fall silkworm egg. The metalic adulterants such as iron, mercury, lead and arsenic are appeared not to be worried, but damage of SO$_3$ and free chlorine is seemed to lie considerable. Therefore, before acid treatment for hatching hydrochloric acid was warmed to 50$^{\circ}C$ with shaking to evaporate several injurious gases, by whick the damage due to use of hydrochloric acid for acid treatment hatching is prevented considerably. In conclusion, it is recommended to pretest bioassay with every HCl samples before artificial hatching of silkworm egg.

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A Study on the Damage Range of Chemical Leakage in Polysilicon Manufacturing Process (폴리실리콘 제조 공정에서 화학물질 누출 시 피해범위에 관한 연구)

  • Woo, Jongwoon;Shin, Changsub
    • Journal of the Korean Institute of Gas
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    • v.22 no.4
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    • pp.55-62
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    • 2018
  • There is growing interest in solar power generation due to global warming. As a result, demand for polysilicon, which is the core material for solar cells, is increasing day by day. As the market grows, large and small accidents occurred in the production process. In 2013, hydrochloric acid leaked from the polysilicon manufacturing plant in SangJu. In 2014, a fire occurred at a polysilicon manufacturing plant in Yeosu, and in 2015, STC(Silicon Tetrachloride) leaked at a polysilicon manufacturing plant in Gunsan City. Leakage of chemicals in the polysilicon manufacturing process can affect not only the workplace but also the surrounding area. Therefore, in this study, we identified the hazardous materials used in the polysilicon manufacturing process and quantitatively estimate the amount of leakage and extent of damage when the worst case scenario is applied. As a result, the damage distance by explosion was estimated to be 726 m, and the damage distance to toxicity was estimated to be 4,500 m. And, if TCS(Trichlorosilane), STC(Silicon Tetrachloride), DCS(Dichlorosilane) leaks into the air and reacts with water to generate HCl, the damage distance is predicted to 5.7 km.

Risk Analysis of Transporting Hazardous Substances in Harbor Using Modeling Program (항만에서 위험물 운송 중 유해화학물질 누출 위험성에 관한 연구)

  • Yoon, Sukyoung;Yun, Jayeon;Han, Jiyun;Jung, Seungho
    • Journal of Ocean Engineering and Technology
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    • v.32 no.4
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    • pp.272-278
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    • 2018
  • Recently, the use of hazardous chemicals has been continuously increasing. Therefore, the international trade volume is growing and chemical accidents have increased. Nowadays, the safety awareness of the public has increased. As a result, the management and supervision of hazardous chemicals have been strengthened. However, the port policy of Korea has focused on increasing the volume of cargo through facility development. Thus, the port management of hazardous chemicals has been relatively neglected. For national economic growth and society, the port management of hazardous chemicals should be considered to efficiently ensure safety and economic growth. Therefore, this study assumed scenarios where hazardous materials were moved in a dangerous container, not only on appropriate wharfs but also in ports that were close to a big city. The BTX substances were selected among the toxic chemicals with large import and export volumes, and the risk distance and damage effects were predicted using various risk assessment programs. It is expected that this could be used to improve a port safety management system and could be utilized to determine the safety distance in case of an accident.

A Review of the Different Models for Predicting Blast Overpressures Caused by Vapor Cloud Explosions (증기운 폭발에 의해 발생된 폭풍 과압 예측 모델 검토)

  • Park Dal Jae;Lee Young Soon;Lim Young Hoon
    • Journal of the Korean Institute of Gas
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    • v.4 no.4 s.12
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    • pp.50-57
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    • 2000
  • Past accidents have shown that vapor cloud explosions are the predominant cause of the largest losses in the chemical and petrochemical industries due to the generation of significant overpressures. Prediction of such overpressure is of great concern and a knowledge of the likely overpressure is needed for the design of equipment, safety cases and emergency planning. For these reasons, risk assessment for vapor cloud explosion is crucial and this assessment can be carried out using the different models including TNT-Equivalency, TNO Hemispherical, TNO Multi-Energy and CFD models. Accordingly, in this paper, the published VCE prediction models are reviewed to provide a critical comparison of the different models used for the quantification of explosion hazards, in terms of the fundamental assumptions employed, and their predictive accuracy

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Process Hazard Review and Consequence Effect Analysis for the Release of Chlorine Gas from Its Storage Tank (염소저장탱크에서의 가스 누출시 공정위험검토 및 결과영향분석)

  • Ko, Jae-Sun;Kim, Hyo
    • Fire Science and Engineering
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    • v.17 no.3
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    • pp.61-73
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    • 2003
  • Most of the accidents occurred from the chemical plants are related to the catastrophic gas release events when the large amount of toxic materials is leaked from its storage tank or transmitting pipe lines. In this case, the greatest concerns are how the spreading behaviors of leakages are depended on the ambient conditions such as air stability and other environmental factors. Hence, we have focused on the risk assessments and consequential analysis for chlorine as an illustrative example. As appeared in the result, Fire & Explosion Index depicted it a bit dangerous with presenting the comprehensive degrees of hazard 90.7. And as a result of Phast6.0/ALOHA, the trends of each scenario appeared considerably identical although there are some differences in the resulting effects according to the input data for the Gas Model. The consequence analysis is performed numerically based on the dense gas mode. In the future, using more correct input data, material properties, and topographical configuration, the method of this research will be useful for the guideline of the risk assessment when the release of toxicants breaks out.

Effects of Oils and Dispersant on the Red Tide Organism Cochlodinium Polykrikoides (적조생물 Cochlodinium Polykrikoides에 대한 유류 및 유처리제의 영향)

  • Lee, Sam-Geun;Cho, Eun-Seob;Lim, Wol-Ae;Lee, Young-Sik
    • Journal of Environmental Science International
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    • v.16 no.7
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    • pp.799-804
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    • 2007
  • Oil spill caused severe effects on the marine fauna and flora due to direct contact of organisms with the oil and even in regions not directly affected by the spill. This study was conducted to understand the effects of the oil spill accidents and the use of dispersant on the red tide of Cochlodinium polykrikoides. Crude oil produced in Kuwait, bunker-C, kerosene and diesel oil, and a chemical dispersant produced in Korea, were added with a series of 10 ppb to 100 ppm in the f/2-Si medium at $20^{\circ}C$ under a photon flux from cool white fluorescent tubes of $100\;mol\;m^{-2}\;s^{-1}$ in a 14: 10 h L:D cycle for the culture of C. polykrikoides. In low concentrations of ${\leq}$ 1 ppm of examined oils no impact on the growth of C. polykrikoides was recorded, while in high concentration of ${\geq}$ 10 ppm, cell density was significantly decreased with the range of 10 to 80% in comparison with the control. The growth of C. polykrikoides after the addition of the dispersant and the mixtures combined with oils and a dispersant of ${\geq}$ 10 ppm appeared to decrease, whereas the growth of C. polykrikoides exposed to ${\leq}$ 100 ppb showed little serious impact. However, almost all the C. polykrikoides cells were died regardless of a dispersant and combined mixtures within a few days after the addition of high concentrations.