• 제목/요약/키워드: Chemical/Mechanical degradation

검색결과 214건 처리시간 0.022초

보론 나이트라이드와 탄소나노튜브로 충전된 실리콘 고무의 열전도도 향상 (Improvement of Thermal Conductivity of Poly(dimethyl siloxane) Composites Filled with Boron Nitride and Carbon Nanotubes)

  • 하진욱;홍진호;김민재;최진규;박동화;심상은
    • 폴리머
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    • 제37권6호
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    • pp.722-729
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    • 2013
  • Poly(dimethyl siloxane)(PDMS, 실리콘 고무)의 열전도도 향상을 위하여 보론 나이트라이드과 탄소나노튜브를 열전도성 충전제로 사용하였다. 보론 나이트라이드의 함량은 0에서 100 phr로 증가시켰으며, 탄소나노튜브의 함량은 보론 나이트라이드의 함량을 100 phr로 고정시킨 상태에서 0에서 4 phr로 증가시켰다. 실리콘 고무 복합재료의 열전도도는 보론 나이트라이드 함량의 증가에 따라 증가하였으나, 탄소나노튜브를 추가로 첨가하더라도 열전도도 향상에 대한 효과는 미미하였다. 100 phr 함량의 보론 나이트라이드 함량에 탄소나노튜브를 충전 시 복합재료의 열분해가 가속화되는 예상치 못한 결과를 얻었다. 이를 해석하기 위하여 Horowitz-Metzger 방법을 이용하여 열분해 활성화 에너지를 계산하였다. 또한 보론 나이트라이드/탄소나노튜브가 충전된 실리콘 고무 복합재료의 경화거동, 전기저항 및 기계적 물성을 연구하였다.

효소에 의한 방축가공 양모직물의 물성 변화에 관한 연구 (A Study on the Mechanical Properties of Shrink-Resistant Wool Fabric Treated with Enzyme)

  • 박미라;김환철;박병기
    • 한국염색가공학회지
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    • 제13권3호
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    • pp.155-164
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    • 2001
  • Textile wet-processing industry usually five rise to environmental pollution problems caused by using chemical substance. The objective of this study is to apply enzymes for wool and reduce the environmental problems. Three commercial protein degradation enzymes and a cellulose degradation enzyme as a reference were treated to prevent the shrinkage of wool fabric on laundering. Shrink resistant effects used change with the kinds of enzyme, the amount of enzyme, assistant chemicals, and the pre-treatment condition of wool fabric. When pre-treated with corona before enzyme treatment under ultrasonic condition, the weight loss was increased and strength was decreased and elongation was increased. Both corona pre-treatment and the addition of $Na_2SO_4$ also decreased shrinkage of wool fabrics on laundering. The existence of assistant chemicals increased alkali solubility of wool fabrics.

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FRP 복합체의 자외선 저항성에 관한 실험적 연구 (Experimental Study on Ultra-Violet Resistance of FRP composites used in Strengthening RC members)

  • 송태협;최기선;유영찬;김긍환
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2006년도 춘계 학술발표회 논문집(II)
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    • pp.333-336
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    • 2006
  • In general, polymer materials undergo degradation when exposed to ultraviolet radiation, which can cause dissociation of chemical bonds. FRP composites which are used in strengthening existing structure are usually adhered on the concrete surface, its mechanical properties as well as appearance such as color, surface conditions are affected by sunlight and expecially ultraviolet light. In this study, variations of tensile strength after exposure for certain period of time through accelerated exposure by Xe arc methods specified in KS F 2274 are measured in order to examine strength degradation characteristics of FRP composite. As a result of ultraviolet light test for FRP composite after accelerated exposure for 0, 500, 1000, 1500 hour, discoloration of FRP composite occurs according to the passage of time. But, few strength degradations of FRP composite are observed due to exposure of ultraviolet ray with an small variation of tensile strength.

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철도차량용 견인전동기의 수명예측 및 절연신뢰성 평가 방법에 관한 연구 (A Study on the Evaluation of Reliability and Expected Life for the Insulation System of Traction Motors in Urban Transit E.M.U)

  • 왕종배;김상걸;이헌돈;오현석;김기준
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1999년도 하계학술대회 논문집 A
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    • pp.449-451
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    • 1999
  • When the traction motor for urban transit E.M.U is driven with VVVF controlled inverter, the insulation degradation factors on the 200 Class insulation system of VPI process are analyzed with considering dielectric, mechanical properties, thermal stability, chemical resistivity and compatibility. A new test method of complex accelerating degradation is proposed to evaluate the insulation reliability and the long-term life including harmonic loss and transient surge stress due to PWM inverter drive.

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송배전용 Al-Cu 접속금구의 신뢰도 향상에 관한 연구(II) 압축형 및 폭발용접형 접속금구의 내식성 비교 (Study on the Improvement of the Reliability of Al-Cu Connections in Power Distribution Systems(II))

  • 하윤철;배정효;하태현;이현구;김대경
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2003년도 추계학술대회 논문집 전력기술부문
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    • pp.370-372
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    • 2003
  • As there expands the usage of Al-Cu connections to interface aluminum and copper in power distribution systems, efforts to mitigate the mechanical, electrical or electro-chemical degradation are widely spreading. The explosive bending technology, in particular, has been thought as a countermeasure for the degradation. In this paper, electrochemical analysis and optical microscopic observation are carried out in order to compare the corrosion resistivities of the commercial compression type bimetallic sleeve and the explosion type bimetallic sleeve. The results show that the explosive bonding technology can prevent the interfacial corrosion caused by the formation of crevices and pits as well as from galvanic potential difference.

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고온시의 경화된 시멘트 페이스트의 공극률 예측모델 (A Prediction Model on Porosity of Hardened Cement Paste under High Temperatures)

  • 이재승;정성진;정영한;김흥열;김형준
    • 한국화재소방학회논문지
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    • 제23권3호
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    • pp.103-109
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    • 2009
  • 콘크리트의 온도에 의한 재료적 특성에 대한 저감은 두 가지 메커니즘에 기인한다. 첫 번째 메커니즘은 온도범위에 따른 구성성분의 상변화이다. 초기 구성성분들은 온도 증가로 인해 다른 성분들로 상변화를 일으킨다. 두 번째 메커니즘은 온도에 의한 각 구성성분의 역학적 특성 변화이다. 따라서 고온에 노출된 콘크리트의 재료적 특성에 관한 모델 역시 이 두 가지 메커니즘을 함께 고려하여 제시되어야 한다. 본 연구는 위에서 언급한 두 가지 메커니즘을 고려한 고온에 노출된 콘크리트의 재료적 특성 모델을 제안하기 위한 기반연구로서, 온도범위에 따른 상변화를 고려한 경화된 시멘트 페이스트의 공극률에 대한 이론적 모델을 제시한다.

Residual properties of high-strength fiber reinforced concrete after exposure to high temperatures

  • Tang, Chao-Wei
    • Computers and Concrete
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    • 제24권1호
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    • pp.63-71
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    • 2019
  • Thermal energy from high temperatures can cause concrete damage, including mechanical and chemical degradation. In view of this, the residual mechanical properties of high-strength fiber reinforced concrete with a design strength of 75 MPa exposed to $400-800^{\circ}C$ were investigated in this study. The test results show that the average residual compressive strength of high-strength fiber reinforced concrete after being exposed to $400-800^{\circ}C$ was 88%, 69%, and 23% of roomtemperature strength, respectively. In addition, the benefit of steel fibers on the residual compressive strength of concrete was limited, but polypropylene fibers can help to maintain the residual compressive strength and flexural strength of concrete after exposure to $400-600^{\circ}C$. Further, the load-deflection curve of specimen containing steel fibers exposed to $400-800^{\circ}C$ had a better fracture toughness.

A Study on the Evaluation of Mterial Degradaion for 2.25Cr-1Mo Steel using Ultrasonic Attenuation Characterization

  • Kim, Chung-Soek;Park, Ik-Keun;Park, Un-Su;Kim, Hyun-Mook;Kwun, Sook-In;Byeon, Jai-Won
    • 한국공작기계학회:학술대회논문집
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    • 한국공작기계학회 2001년도 추계학술대회(한국공작기계학회)
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    • pp.319-323
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    • 2001
  • In significant number of energy-related facilities for like thermal power plant or petro-chemical industry, CrMo steels are widely used energy conversion industries. However, these materials undergo precipitation of carbides or intermetallic compounds into grain boundary and change of internal microstructure such as coarsening of precipitation, decrease of solute elements and impurity segregation under more severe service conditions, which results in deterioration of inherent superior material characteristics. In this study, it was verified experimentally the feasibility of the aging degradation evaluation for degraded 2.25Cr-lMo steel specimens prepared by isothermal aging heat treatment at 63$0^{\circ}C$ by high frequency longitudinal ultrasonic and surface SH wave investigating the change of attenuation coefficient analyzed by spectral analysis. Attenuation coefficient had a tendency to increase as degradation proceeded.

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Aging Mechanisms of Lithium-ion Batteries

  • Jangwhan Seok;Wontae Lee;Hyunbeom Lee;Sangbin Park;Chanyou Chung;Sunhyun Hwang;Won-Sub Yoon
    • Journal of Electrochemical Science and Technology
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    • 제15권1호
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    • pp.51-66
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    • 2024
  • Modern society is making numerous efforts to reduce reliance on carbon-based energy systems. A notable solution in this transition is the adoption of lithium-ion batteries (LIBs) as potent energy sources, owing to their high energy and power densities. Driven by growing environmental challenges, the application scope of LIBs has expanded from their initial prevalence in portable electronic devices to include electric vehicles (EVs) and energy storage systems (ESSs). Accordingly, LIBs must exhibit long-lasting cyclability and high energy storage capacities to facilitate prolonged device usage, thereby offering a potential alternative to conventional sources like fossil fuels. Enhancing the durability of LIBs hinges on a comprehensive understanding of the reasons behind their performance decline. Therefore, comprehending the degradation mechanism, which includes detrimental chemical and mechanical phenomena in the components of LIBs, is an essential step in resolving cycle life issues. The LIB systems presently being commercialized and developed predominantly employ graphite anode and layered oxide cathode materials. A significant portion of the degradation process in LIB systems takes place during the electrochemical reactions involving these electrodes. In this review, we explore and organize the aging mechanisms of LIBs, especially those with graphite anodes and layered oxide cathodes.

화학적 환경에 노출된 콘크리트 보강용 FRP 보강근의 장기 효과 (Long-Term Effect of Chemical Environments on FRP Reinforcing Bar for Concrete Reinforcement)

  • 박찬기;원종필;유정길
    • 콘크리트학회논문집
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    • 제15권6호
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    • pp.811-819
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    • 2003
  • 철근의 부식은 철근콘크리트 구조물의 주요파괴 원인이다. 철근의 부식에 대한 문제점을 해결할 가능성이 있는 재료 중 FRP 보강근은 그 가능성이 높다. 그렇지만 FRP 보강근은 보강철근과 다른 파괴 매카니즘으로 의하여 현저하게 성능이 저하될 가능성을 가지고 있다. 이와 같은 환경에는 알칼리, 산, 염해 및 물과 수분 등이 있다. 따라서 본 연구에서는 FRP 보강근의 화학적 환경하에서의 내구성능을 평가하고자 하였으며 사용된 FRP 보강근은 2가지 종류의 CFRP 보강근 및 GFRP 보강근, 한가지 종류의 AFRP 보강근으로 알칼리용액, 산용액, 염해환경 및 중성용액에 노출시켰다. FRP 보강근의 역학적 특성 및 내구특성은 인장, 압축 및 전단시험을 통하여 평가하였으며 시험결과 FRP 보강근은 매우 혹독한 화학적 환경에서 우수한 내구성을 가지고 있음을 알 수 있었다.