• 화약ㆍ발파
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• 제29권2호
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• pp.13-31
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• 2011

국내외의 광산 및 대규모 현장에서는 노천발파 시, Air Deck 발파공법을 사용하여 발파효율성을 높이려 하고 있으나 이는 공 내부 상태에 따라 장전밀도가 달라짐으로 인해 대괴가 발생하는 등 문제점이 있다. 특히 석회석 광산의 경우 침식 용해 작용에 의해 공벽이 확공되거나 손상된 경우가 많아 Air Deck 공법 적용 시 의도하지 않은 집중장약이 발생하는 경우가 있다. 따라서 본 연구에서는 석회석 광산의 대규모 노천발파를 대상으로 사전에 공 내부를 내시경 검사한 후 공 내부에서 장약집중을 야기할 수 있는 구간을 Air Tube를 이용한 데크차지 공법으로 분상장약(Deck Charge)하여 Air Deck 발파공법의 효과가 온전히 나타나도록 유도하였고 이를 일반장약 공법과 비교하였다. 비교대상은 전체적인 발파효과, 파쇄도, 장약량 절감율 및 시공속도(장약에서 발파까지의 총 작업속도)였으며, 그 결과 시공속도를 제외한 나머지 비교대상에 있어 일반장약에 의한 발파공법 보다 Air Deck를 이용한 이중분상 발파공법이 더 효율적으로 나타났다.

• 공업화학
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• 제9권4호
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• pp.463-468
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• 1998

알루미늄의 부식에 있어서 HCI 용액내에 황산을 첨가하는 경우 황산이온의 화학적 흡착에 의한 부식억제 효과가 나타나며, CV (cyclic voltammetry) 실험결과 황산이온은 핏트내부에 보호성 산화피막을 생성함으로서 에치핏트가 핏트내부와 알루미늄 표면에 함께 생성되어 핏트의 밀도가 증가하였다. 알루미늄 교류에칭시에 핏트분포는 황산이온의 농도와 환원전류량에 의하여 크게 영향을 받으며, 환원전류인가시 $0.8mC/cm^2$ 이하의 전하량에서 핏트내부에 생성된 산화피막은 황산이온 농도의 증가에 따라 핏트발생에 대한 저항성이 중가하였으나, $0.8mC/cm^2$ 이상에서는 산화피막내에 국부적인 구조변화가 발생하며 황산이온 농도에 관계없이 산화피막의 파괴가 빠르게 진행되었다.

• 한국원자력학회:학술대회논문집
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• 한국원자력학회 2004년도 추계학술발표회 발표논문집
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• pp.911-912
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• 2004

1. Cathodic hydrogen charging considerably reduced the tensile ductility of ODS steels and a 9Cr-2W RMS. The hydrogen embrittlement of ODS steels was strongly affected by specimen sampling orientation, showing significant embrittlement in the T-direction. This comes from the microstructural anisotropy caused by elongated grains of ODS steels in L-direction. 2. The ODS steels contained a higher concentration of hydrogen than 9Cr-2W RMS at the same cathodic charging condition, and the critical hydrogen concentration required to transition from ductile to brittle fracture was in the range of $10{\sim}12$ wppm, which approximately 10 times larger than that of a 9Cr-2W martensitic steel. 3. The ODS steels showed a typical ductile to brittle transition behavior and it strongly depended on the specimen sampling direction, namely L- and T-direction. In T-direction, the SP-DBTT was about 170 L, irrespective of the ODS materials, and L-direction showed a lower SP-DBTT than that of T-direction.

• 대한화학회지
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• 제15권6호
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• pp.347-352
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• 1971

The variations of the positive and negative electrode potentials, and of internal pressure were measured during the charge of the sealed type Ni-Cd cell. Both polarization characteristics of a paste type Cd-electrode as a gas diffusion electrode in 30% KOH solution and the effects of active carbon electrode as an oxygen consuming auxiliary electrode of the Ni-Cd cell on the charging characteristics of the cell were studied. Peak voltage at the end of charge of the cell is ascribed to the peak at the negative electrode potential, which is due to the concentration polarization by the lack of $Cd^{++}$ ion and oxygen concentration. And the recovery of the negative electrode potential is resulted from depolarization by the increasing diffusion limiting current density with the increasing oxygen pressure. The active carbon electrode was effective as an oxygen consuming auxiliary electrode. The internal pressure of the cell could be maintained below 200mmHg even at one hour rate charge and overcharge by the use of active carbon electrode as an auxiliary electrode.

• Journal of Electrical Engineering and Technology
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• 제8권5호
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• pp.1175-1181
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• 2013

The aim of this paper is to design and evaluate a high concentration, high penetration unipolar corona ionizer. The electrostatic characteristics in terms of voltage-current relationships of the present ionizer in the discharge zones for positive and negative coronas were discussed. Using ion current measurement, the concentration and penetration of ions were evaluated at corona voltages across the needle electrodes between 1 and 4 kV, flow rates between 1 and 5 L/min, and an operating pressure of 1 atm. In the discharge zone of the ionizer, the highest ion concentrations were found to be about $1.71{\times}10^{14}$ and $5.09{\times}10^{14}\;ions/m^3$ for positive and negative coronas, respectively. At the outlet of the ionizer, it was found that the highest ion concentration was about $1.95{\times}10^{13}$ and $1.91{\times}10^{13}\;ions/m^3$ for positive and negative coronas, respectively. The highest ion penetration for positive and negative coronas through the ionizer was found to be about 98 % and 33 %, respectively. The $N_it$ product for positive and negative coronas was also found to $1.28{\times}10^{13}$ and $7.43{\times}10^{13}\;ions/m^3s$, respectively. From the findings, this ionizer proved to be particularly useful as an aerosol charger for positive and negative charge before the detector in an electrical aerosol detector.

• 대한기계학회논문집A
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• 제26권6호
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• pp.1107-1113
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• 2002

This study presents the hydrogen emblittlement in the metal, which decreases the ductility and then induces the brittle fracture. The contribution deals with the effect of strain rate and notch geometry on hydrogen emblittlement of 1.25Cr-0.5Mo and 2.25Cr-1Mo steels, which are in use at high pressure vessel. Smooth and notched specimens were examined to obtain the elongation and tensile strength. For charging the hydrogen in the metal, the cathodic electrolytic method was used. In this process, current density is maintained constant. The amount of hydrogen penetrated in the specimen was detected by the hydrogen determenator(LECO RH404) with the various charging time. The distribution of hydrogen concentration penetrated in the specimen was obtained by finite element analysis. The amount of hydrogen is high in smooth specimen and tends to concentrate in the vicinity of surface. The elongation and tensile strength decreased with the passage of charging time in 1.25Cr-0.5Mo and 2.25Cr-1Mo steels. The elongation increased and tensile strength decreased as strain rate increased. As a result of this study, it is supposed that 1.25Cr-0.5Mo steel is more sensitive than 2.25Cr-lMo steel in hydrogen embrittlement. Hydrogen embrittlement susceptibility of notched specimen after hydrogen charging is more remarkable than that of smooth specimen.

• Nuclear Engineering and Technology
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• 제52권9호
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• pp.2041-2046
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• 2020

The present article investigates the influence of hydrogen concentration on the creep performance of cold-worked stress-relieved unirradiated Zircaloy-4 cladding tube using nanoindentation technique. The as-received Zircaloy-4 tube is hydrided to the concentrations of 600 ppm and 900 ppm using gaseous hydrogen charging method. Constant load indentation creep tests are performed for a dwell period of 600 s in the temperature range of 300℃-500 ℃ at 1000 μN, 2000 μN, and 3000 μN. The impact of hydrogen is evaluated in terms of steady state power law creep exponent and activation energy. The power law creep exponent decreases with increase in hydrogen concentration, however, it remains fairly constant with increase in temperature up to 500 ℃. Moreover, activation energy too decreases significantly with increase in hydrogen concentration. The mean stress exponent and activation energy are found to be 3.58 and 28.67 kJ/mol, respectively, for as-received sample.

• 한국전기전자재료학회논문지
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• 제18권10호
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• pp.929-935
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• 2005

In this paper, synthetic conditions of titania nanparticle was investigated to enhance its uniformity of the particle size as a child particle on organic mother particle of liquid powder type electronic paper. The physical properties are very important to improve the uniformity of electrical charging properties Concentration of titania raw material ($C_9H_{19}NO_4Ti$) in the ethanol solvent, pH, and concentration of the solution in the D.I. water were selected as parameters. As a result, ultrafine and well crystallized titania nanoparticle with good uniformity could be synthesized as the concentration of the $C_9H_{19}NO_4Ti$ in the ethanol solvent, pH of the solution, and the amount of the D.I. water were increased. Using the optimized conditions, the titania nanparoticle with uniformly ultrafime size of 10 nm could be synthesized.

• 한국에너지공학회:학술대회논문집
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• 한국에너지공학회 2003년도 춘계 학술발표회 논문집
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• pp.191-209
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• 2003

Voices of Customers; 1. Long time operating power 2. Quick Charging 3. High power and energy density 4. Safety 5. Small and light power Technical Requirements for Delivering DMFC to Consumer's Hands; 1. MEA having tripled power density. 2. Membrane of maintaining the same protonic conductivity and near 0% cross-over when 10M or higher concentration of methanol fueling (Omitted)

• 한국세라믹학회지
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• 제42권7호
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• pp.503-508
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• 2005

A simple and effective method for the synthesis of LiMn$_{2}$O$_{4}$ powder as a cathode material for lithium secondary battery is reported. Micrometer size LiMn$_{2}$O$_{4}$ was prepared by combustion synthesis technique employing initial mixture of l.l LiNO$_{3}$ -1.3Mn-0.7MnO$_{2}$-1NaCl composition. Parametric study of the combustion process including molar ratio of Mn/MnO$_{2}$ and NaCl concentration were carried out under air atmosphere. The combustion products obtained were additionally heat treated at the temperature 900$^{\circ}C$ and the washed by distilled water. The results of charging-discharging characteristics revealed that LiMn$_{2}$O$_{4}$ cell synthesized in the presence of NaCl had a high capacity and much better reversibility than one formed without NaCl An approximate chemical mechanism for LiMn$_{2}$O$_{4}$ formation is proposed.