• Journal of the Korean Electrochemical Society
• /
• v.13 no.1
• /
• pp.19-33
• /
• 2010

The surface film, which is formed on graphite negative electrodes during the initial charging, is a key component in lithium secondary batteries. The battery reactions are strongly affected by the nature of the surface film. It is thus very important to understand the physicochemical properties of the surface film. On the other hand, the surface film formation is a very complicated interfacial phenomenon occurring at the graphite/electrolyte interface. In studies on electrode surfaces in lithium secondary batteries, in-situ experimental techniques are very important because the surface film is highly reactive and unstable in the air. In this respect electrochemical atomic force microscopy (ECAFM) is a useful tool for direct visualizing electrode/solution interfaces at which various electrochemical reactions occur under potential control. In the present review, mechanism of surface film formation and its correlation with electrolyte are summarized on the basis of in-situ ECAFM studies for understanding of the nature of the surface film on graphite negative electrodes.

• The Journal of Society for e-Business Studies
• /
• v.5 no.1
• /
• pp.135-158
• /
• 2000

In recent years, many retail businesses jumped on the Internet auction bandwagon and paid substantially high fees to learn and develop proper business strategies for this new environment. Unlike what most businesses in the real world presume, this research shows that discriminatory-price ascending-bid auctions in a digital economy might be not very beneficial for the sellers on the Internet, if sellers sell the identical digital products through both a typical posted-price market and an auction. Using an extensive technology infrastructure along with suitable incentives and rules for market agents, we found that a discriminatory-price ascending-bid auction, which is the most popular auction mechanism on the Internet, serves consumers better than it does the sellers or producers in the digital economy. That is, the average prices for digital goods in these auctions are substantially lower than the prices in a posted-price market. This shows that it is not so wise for sellers to jump on the bandwagon of Internet auctions, if there is a market place with posted-price mechanisms which sells comparable items, or if a seller does not have special advantages or strategies in this new market institution. Electronic market mechanisms provide powerful means of understanding and measuring consumer characteristics including willingness-to-pay and other demographics for sellers or producers. Many concern that sellers may extract the entire surplus from the market by using customization on the Internet, thus consumers will be worse off in this digital economy. We found that these sellers who can customize their products and prices fail to capture the whole consumers surplus and cannot exercise a monopoly. One major explanation for this phenomenon is that the competition among the sellers prohibits them from charging prices according to customers demand for each product, where switching from one seller to another is not so difficult for the customers, and reselling products among the buyers are prohibited.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2012.08a
• /
• pp.418-418
• /
• 2012

Synthesis of nanocrystalline diamond powder was investigated via a gas-to-particle scheme using the hot filament chemical vapor deposition. Effect of substrate surface seeding by nano diamond powder, and that of the electrical conductance of the substrate were studied. The substrate temperature, methane content in the precursor gas, filament-substrate distance and filament temperature were $670^{\circ}C$, 5% methane in hydrogen, 10 mm and $2400^{\circ}C$, respectively. The powder formation by gas-to-particle mechanism were greatly enhanced by the substrate seeding by the nano diamond powder. It was attributed to the removal of the electrostatic force between the substrate and the seeded nano diamond particle by the thermal electron shower from the hot filament, via the depolarization of the substrate surface or the attached diamond powder and subsequent levitation into the gas phase to serve as the gas-phase nucleation site. The powder formation was greatly favoured by the conducting substrate relative to the insulating substrate, which proved the actual effect of the electric static force in the powder formation.

• Progress in Superconductivity and Cryogenics
• /
• v.18 no.3
• /
• pp.30-34
• /
• 2016

An integral crank driven Stirling cryocooler is solidly based on concepts of direct IR detector mounting on the cryocooler's cold finger, and the integral construction of the cryocooler and Dewar envelope. Performance factors of the cryocooler depend on operating conditions of the cryocooler such as a cyclic mean pressure of the working fluid, a rotational speed of driving mechanism, a thermal environment, a targeted operation temperature and etc.. At given charging condition of helium gas, the cyclic mean pressure of helium gas in the cryocooler changes with temperatures of the cold end and the environment. In this study, effects of the cyclic mean pressure of helium gas on performances of the Stirling cryocooler were investigated by numerical analyses using the Sage software. The simulation model takes into account thermodynamic losses due to an inefficiency of regenerator, a pressure drop, a shuttle heat transfer and solid conductions. Simulations are performed for the performance variation according to the cyclic mean pressure induced by the temperature of the cold end and the environment. This paper presents P-V works in the compression and expansion space, cooling capacity, contribution of losses in the expansion space.

• The Transactions of the Korean Institute of Electrical Engineers C
• /
• v.50 no.10
• /
• pp.479-488
• /
• 2001

The effects of accelerated Ultraviolet (UV) radiation on High temperature vulcanized (HTV), Room temperature vulcanized (RTV) silicone rubber and two types of ethylene propylene diene terpolymer (EPDM) used for composite insulator were inverstigated by hydrophobicity class (HC), surface voltage decay after corona charging, SEM-EDS, FTIR and XPS. The contact angle in two kinds of silicone rubber was scarcely change, but EPDM occurred to the loss of hydrophobicity followed by surface cracking and chalking. The surface voltage decay on UV-treated silicone rubber and EPDM showed a different decay trend with UV treatment. EDS and XPS analysis indicated that the oxygen content increased with UV treatment time in all samples. For silicone rubber, the oxidized groups of inorganic silica-like structure increased with UV treatment time. The oxidized carbon of C=0, O=C-O in EPDM increased. These oxidized surface for each material had different electrostatic characteristics, so deposited charges were expected to have different impacts on their surface hydrophobicity. The degradation mechanism based on our results was discussed.

• The Transactions of the Korean Institute of Electrical Engineers C
• /
• v.50 no.10
• /
• pp.494-499
• /
• 2001

The effects of accelerated Ultraviolet (UV) radiation on High temperature vulcanized (HTV), Room temperature vulcanized (RTV) silicone rubber and two types of ethylene propylene diene terpolymer (EPDM) used for composite insulator were investigated by hydrophobicity class (HC), surface voltage decay after corona charging, SEM-ES, FTIR and XPS. The contact angle in two kinds of silicone rubber was scarcely change, but EPDM occurred to the loss of hydrophobicity followed by surface cracking and chalking. The surface voltage decay on UV-treated silicone rubber and EPDM showed a different decay trend with UV treatment. EDS and XPS analysis indicated that the oxygen content increased with UV treatment time in all samples. For silicone rubber, the oxidized groups of inorganic silica-like structure increased with UV treatment time. The oxidized carbon of C=O, O=C-O in EPDM increased. These oxidized surface for each material had different electrostatic characteristics, so deposited charges were expected to have different impacts on their surface hydrophobicity. The degradation mechanism based on our results was discussed.

• Transactions of the Korean Society of Automotive Engineers
• /
• v.15 no.2
• /
• pp.151-158
• /
• 2007

Filtration studies, using simulated test nanoparticles or diesel nanoparticles, have been performed about Inconel foam filters for DPF combined with electrostatic precipitation. The simulated test particles were synthesized by laser ablation in the nitrogen atmosphere at the standard condition. The diesel particles were exhausted from the diesel engine driven on the condition of idle or load mode. Filtration efficiency of the metal foam filter is very low because most of particles are penetrated through the large pores of filter. However, the efficiency was considerably improved by applying the electric field to the filter and/or charging the nanoparticles. Nevertheless, the pressure drop of filter hardly increased because the filter-pores were not clogged by deposited particles and kept open.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
• /
• 2008.04a
• /
• pp.81-89
• /
• 2008

This paper is concerned with the development of the piezoelectric energy harvesting(PEH) device for ubiquitous sensor node(USN). The USN needs auxiliary power to lengthen its operational life. In this study, the piezoelectric energy harvesting system consisting of a cantilever with a tip mass and piezoelectric wafer was investigated in detail both theoretically and experimentally. The dynamic model for the addressed system was derived using the assumed mode method. The resulting equations of motion were expressed in matrix form, which had never been developed before. The power output characteristics of the PEH was then calculated and discussed. Various experiments were carried out to investigate the charging characteristics of electrical components. Theoretical and experimental results showed that the PEH was able to charge a battery with ambient vibrations but still needed an effective mechanism which can convert mechanical energy to electrical energy and an optimal electric circuit which dissipates small energy.

• Journal of Mechanical Science and Technology
• /
• v.19 no.9
• /
• pp.1790-1800
• /
• 2005

The examination on the operating mechanism of a pulsating heat pipe (PHP) using visualization revealed that the working fluid in the PHP oscillated to the axial direction by the contraction and expansion of vapor plugs. This contraction and expansion is due to the formation and extinction of bubbles in the evaporating and condensing section, respectively. In this paper, a theoretical model of PHP was presented. The theoretical model was based on the separated flow model with two liquid slugs and three vapor plugs. The results show that the diameter, surface tension and charge ratio of working fluid have significant effects on the performance of the PHP. The following conclusions were obtained. The periodic oscillations of liquid slugs and vapor plugs were obtained under specified parameters. When the hydraulic diameter of the PHP was increased to d=3mm, the frequency of oscillation decreased. By increasing the charging ratio from 40 to 60 by volume ratio, the pressure difference between the evaporating section and condensing section increased, the amplitude of oscillation reduced, and the oscillation frequency decreased. The working fluid with higher surface tension resulted in an increase in the amplitude and frequency of oscillation. Also the average temperature of vapor plugs decreased.

• Transactions of the Korean Society for Noise and Vibration Engineering
• /
• v.18 no.6
• /
• pp.632-641
• /
• 2008

This paper is concerned with the development of the piezoelectric energy harvesting(PEH) device for ubiquitous sensor node(USN). The USN needs auxiliary power to lengthen its operational life. In this study, the piezoelectric energy harvesting system consisting of a cantilever with a tip mass and piezoelectric wafer was investigated in detail both theoretically and experimentally. The dynamic model for the addressed system was derived using the assumed mode method. The resulting equations of motion were expressed in matrix form, which had never been developed before. The power output characteristics of the PEH was then calculated and discussed. Various experiments were carried out to investigate the charging characteristics of electrical components. Theoretical and experimental results showed that the PEH was able to charge a battery with ambient vibrations but still needed an effective mechanism which can convert mechanical energy to electrical energy and an optimal electric circuit which dissipates small energy.