• 제목/요약/키워드: Charge decay

검색결과 91건 처리시간 0.02초

전기방사를 통해 제조된 정전기 보유 필터의 표면전위 및 대전량에 따른 성능특성 분석 (Characteristic Analysis of Electret Filters made by Electrospinning)

  • 김길태;안영철;이재근
    • 설비공학논문집
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    • 제20권12호
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    • pp.820-824
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    • 2008
  • Electret filter media are used in general ventilation filters, disposable respirators, vehicle cabin filters, vacuum cleaners and room air cleaners. There are basic mechanisms of interception, inertial impaction, diffusion, gravitational settling, electrostatic attraction by which an aerosol particle can be deposited onto a fiber in a filter. The ability of fine particle removal strongly depends on the electrostatic forces between particles and polarized fibers. Thus, the stability of the fiber polarization is a major factor in the reliability of electret filters. In this study, the electret filter is made by electrospinning process using Polystyrene which is dissolved by 5 : 5 of Tetrahydrofuran (THF) and Dimethylformamide (DMF). Also the electrical properties and the filtration performances of electrospun filter media are Quantitatively investigated. Electrical properties of electrospun filters have been studied on surface charge potential and surface charge density. Also the filtration performance of the electret filters are evaluated on collection efficiency. The surface charge potential and the surface charge density of electrospun PS filters are increased with increasing applied voltage and saturated at 30 kV of applied voltage. Also collection efficiency of electro spun filters is increased with increasing surface charge potential and surface charge density. But the surface charge potential is decreased by natural decay and it causes deterioration of particle collection efficiency.

바닥발파에서 암질지수(RQD)와 발파진동상수 K, n의 관계 (Relationship between Rock Quality Designation and Blasting Vibration Constant "K" & Decay Constant "n" by Bottom Blasting Pattern)

  • 천병식;오민열
    • 한국지반공학회지:지반
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    • 제11권3호
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    • pp.55-68
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    • 1995
  • 본 연구는 수직구의 바닥굴착을 위한 바닥발파시 삼승근환산식과 자승근환산식의 발파진동상수 및 감쇠지수와 암질지수(RQD)와의 관계를 시험발파계측을 통하여 정리분석한 것이다. 각종 발파시 발파진동의 크기는 장약량, 발파원과 발파진동 측정지점과의 거리, 지반의 특성에 따라 크게 좌우되며 본 논문에서는 지반의 특성이 발파진동에 미치는 영향을 규명하기 위하여 암반의 절리특성을 대표하는 RQD와 발파진동 크기와의 관계를 연구한 것이다. 시험결과 RQD의 증가에 따라 발파진동상수 K와 감치지수 n의 절대치는 상대적으로 증가하는 것으로 나타났으며 본 연구결과에 의하여 향후 암질지수에 따른 바닥발파의 발파진동속도를 예측할 수 있다.

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Electron Paramagnetic Resonance Study on the Photoproduced Cation Radical of N-Methylphenothiazine in the Gel Matrices

  • Lee, Don-Keun;Zhang, Dong-Ri;Kang, Youn-Soo
    • 한국자기공명학회논문지
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    • 제6권2호
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    • pp.103-112
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    • 2002
  • The photoproduced cation radical of N-methylphenothiazine $(PC_1)$ doped into phenyltriehtoxysilane (PhiTEOS), vinyltriethoxysilane (VTEOS) and methyltriethoxysilane (METOS) was studied with electron spin resonance (ESR) and electron nuclear double resonance (ENDOR). The photoinduced charge separation efficiency was determined by integration of ESR spectra which correspond to the amount of photoproduced cation radical in the matrices. This was correlatively studied with the polarity and pore size of the gel matrices. The relative polarity of the matrices was determined by measuring ${\lambda}_{max}$ values of $PC_1$ in the different matrices. The relative pore size among the matrices was determined by measuring relative proton matrix ENDOR line widths of the photoproduced cation of $PC_1$. The decay kinetic constants of the cation radical of $PC_1$ in the different matrices with relatively studied with fitting the biexponential decay curves after exposure at the ambient condition. This is correlatively interpreted with the polarity and pore size of the matrices.

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스멕타이트 점토의 팽창도, 층전하, 양이온 교환능에 대한 열수반응의 영향 (Effect of a Hydrothermal Reaction on the Expandibility, Layer Charge, and CEC of Smectite Clay)

  • 이재완;조원진
    • 방사성폐기물학회지
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    • 제8권3호
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    • pp.173-179
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    • 2010
  • 고준위폐기물처분장에서 완충재는 오랜 기간 동안 방사성핵종의 붕괴열과 여러가지 화학조건의 지하수에 노출되며, 이러한 열수조건은 완충재물질의 차수 및 핵종저지 방벽성능에 심각한 영향을 줄 수 있다. 본 연구에서는 국산 스멕타이트를 대상으로 열수실험을 수행하고, 열수반응에 의한 스멕타이트 점토의 팽창도, 층전하, 양이온교환능의 변화를 조사하였다. 열수실험 결과, 온도와 용액 중 칼륨농도를 증가시켰을 때, 스멕타이트의 팽창도는 감소하였고, 층전하는 더 큰 음전하를 가졌으며, 양이온교환능도 감소하였다.

전압인가식 제전기의 특성에 관한 연구 (A Study on Characteristics of a Volatage-Applied Electrostatic Reducer)

  • 이동훈;정용철
    • 한국안전학회지
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    • 제10권2호
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    • pp.77-83
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    • 1995
  • An electrostatic reducer of a multi-pole high DC voltage applied type and a high frequency square wave voltage applied type have been studied to eliminate effectively and safely electrostatic charge on a dummy charged material. As a fundamental experiments, measurement were made on the decay time as a function of distance between electrostatic reducer and charged body, skewed angle of electrostatic reducer installed and wind speed of generated ions(+ or -) by electrostatic reducer with high DC voltage and high frequency square wave voltage. Based oil the results above, a appropriate installation and method were produced as a trial for factory.

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The $Al_2O_3$ Passivation Mechanism for c-Si Surface Deposited by ALD Using $O_3$ Oxidant

  • 조영준;장효식
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제45회 하계 정기학술대회 초록집
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    • pp.320.1-320.1
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    • 2013
  • We have investigated the effect of surface passivation for crystalline silicon solar cell using ozone-based atomic layer deposited (ALD) $Al_2O_3$. We examined passivation properties such as uniformity, carrier lifetime, thickness, negative fixed charge density at AlOx/Si interface, and reflectance. The influences of process temperature and heat treatment were investigated using microwave photoconductance decay (PCD). Ozone-based ALD $Al_2O_3$ film shows the best carrier lifetime at lower deposition temperature than $H_2O$-based ALD.

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A Numerical Study on the Triboelectrostatic Separation of PVC Materials From Mixed Plastics for Waste Plastic Recycling

  • Ha, Man-Yeong;Jeon, Chung-Hwan;Park, Doo-Seong;Park, Hae-Jin
    • Journal of Mechanical Science and Technology
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    • 제17권10호
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    • pp.1485-1495
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    • 2003
  • We investigate the triboelectrostatic separation of polyvinylchloride (PVC) from mixed plastics in the laboratory scale triboelectrostatic separation system. The flow and electric fields in the precipitator are obtained from the numerical solution of finite volume method. Using these flow and electric fields, we solved the particle motion equation considering the inertia, drag, gravity and electrostatic forces acted on the particles. The particle trajectories are obtained using a Lagrangian method as a function of different important variables such as Reynolds number, Stokes number, electrostatic force, electric charge and electric field distribution, inclined angle of plane electrodes, particle rebounding, particle charge decay rate after impact on the electrode surface, etc., in order to determine the optimal design conditions. The present predicted results for the cumulative yield represent well the experimental ones.

레이저 프린터용 이층형 유기감광막의 전자사진특성 (The electrophotographic characteristics of the duble-layered orgaic photoreceptors for the laser printer)

  • 박종관;박구범;이덕출
    • 전자공학회논문지D
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    • 제35D권4호
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    • pp.53-60
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    • 1998
  • The purpose of this paper is to meausre the electrophotographic characteristics of double-layered organic photoreceptor and to evaluate an application for the laser beam printer drum. The characte carrier generation layer(CGL) of double-layered photoreceptor was fabricated with .tau.-H$_{2}$Pc which has high photosensitivity in the near-infrareed region(thickness is about 0.3.mu.m), and Oxadiazole derivative was chosen as a charge carrier transport layer(CTL) because of its high hole mobility. To observe the electrophotographic characteristics of the photoreceptor, we measured the charge acceptance, dark-decay ratio, residual potential after light irradiation. From the result of this study, proper thickness of CTL was about 10.mu.m. Also it's realized that electrophotographic characteristics of the photoreceptor were depend on the thickness of the CTL and the initial surface potential.

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EFFECT OF NITROGEN POSITION ON EXCITED STATE PROPERTIES OF 1-(9- ANTHRYL )-2-(n-QUINOLINYL)ETHENES

  • Shin, Eun-Ju
    • Journal of Photoscience
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    • 제6권2호
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    • pp.61-65
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    • 1999
  • The fluorescence properties and photoisomerization behavior of 1-(9-anthryl)-2-(n-quinolinyl)ethene (n-AQE, n=2-4) have been investigated in various solvents. t-3-AQE is strongly fluorescent, but does not accomplish photoisomerization, similar to parent hydrocarbon compound, t-1-(9-anthryl)-2-phenylethene (t-9-APE) or t-1-(9-anthryl)-2-(1-naphthyl)ethene (t-1-ANE). Fluorescence and photoisomerization oft-2-AQE and t-4-AQE are strongly affected by solvent polarity. Dependence of fluorescence quantum yield on the solvent polarity is moderate for t-2-AQE and large for t-4-AQE. In nonpolar solvent (in n-hexane), they exhibit relatively strong fluorescence, but do not isomerize to cis isomer on irradiation, even if inefficient isomerization is observed for t-4-AQE. However, as solvent polarity increases, their fluorescences become weak with efficient photoisomerization to corresponding cis isomer. Intramolecular charge-transfer excited state is presumed to contribute to photoisomerization. The S$_1$ decay parameters were found to be solvent-dependent due to the charge-transfer character of lowest S$_1$ state. In polar solvents, the activation barrier to twisting is reduced enhancing the isomerization of r-2-AQE and t-4-AQE in the singlet manifold.

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Micellar Effects on Intramolecular Charge Transfer Emission from Biphenylcarboxylic Acids

  • Yoon, Min-Joong;Cho, Dae-Won;Kang, Seong-Gwan;Lee, Min-Yung
    • Bulletin of the Korean Chemical Society
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    • 제14권6호
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    • pp.704-708
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    • 1993
  • The intramolecular charge transfer (ICT) phenomena of the photoexcited 2-biphenylcarboxylic acid (2BPCA) and 4-biphenylcarboxylic acid (4BPCA) have been investigated in some surfactant micellar solutions. The ICT emission of 4BPCA and 2BPCA in aqueous solution at sufficiently low pH (1-3) has been observed to be markedly quenched and blue-shifted upon addition of a cationic surfactant, cetyltrimethylammonium chloride (CTAC) in contrast to little change in anionic sodium dodecyl sulfate (SDS) and neutral Brij 35. An anionic emission band has been observed to be enhanced at expense of the ICT emission as a function of the concentration of CTAC. These results with the micellar effects on the fluorescence decay kinetics of 4BPCA suggest that formation of the ICT state of the excited acids is inhibited by CTAC-induced proton transfer as well as the decrease in the polarity and/or hydrogen-bonding ability of the micellar microenvironment entrapping the acids.