• Title/Summary/Keyword: Charge carrier

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Enhanced electrochemical performance of peony flower-like carbon-coated γ-Ga2O3 nanosheets for lithium-ion battery anodes

  • Injun Jeon;Jin Hyun Hwang;Tae Gyun Kim;Linghong Yin;Hyung Woo Lee;Jong Pil Kim;Hyung Soo Ahn;Chae Ryong Cho
    • Journal of Ceramic Processing Research
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    • v.22 no.2
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    • pp.192-199
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    • 2021
  • Peony flower-like γ-Ga2O3 nanosheets (γ-Ga2O3 NSs) were synthesized and carbon layers were coated on their surfaces using a simple hydrothermal process with subsequent carbonization. The γ-Ga2O3 NSs comprised ultrathin layers, which are tens of nanometers in thickness. The carbon-coated γ-Ga2O3 NS (γ-Ga2O3@C NS) electrode exhibited a specific capacity of 598 mAh g-1 at 200 cycles, at a current density of 0.5 A g-1, higher than that of γ-Ga2O3 NSs (60 mAh g-1). Furthermore, a specific capacity of 100 mAh g-1 at 5 A g-1 was achieved owing to the low charge transfer resistance through the carbon layers. This study suggests that two-dimensional γ-Ga2O3@C NSs with both large specific area and high charge carrier transport are promising active materials for lithium-ion battery anodes with better electrochemical performance.

Transport System of Specific Neutral Amino Acids in Suspension-Cultured Cells (현탁배양 세포내에서 특수 중성 아미노산의 수송)

  • Bong-Heuy CHO
    • Korean Journal of Plant Tissue Culture
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    • v.21 no.4
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    • pp.201-206
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    • 1994
  • The influx of glycine, valine, alanine, and histidine was inhibited by all tested neutral amino acids competitively and the reciprocal inhibitory studies showed the neutral amino acids possess the same transport system as neutral amino acids process to the same catalytic site of one carrier to each other, The molecules of histidine were transported actively as a neutral form through the neutral amino acid transport system but were not transported as a charged form. The Km values of the neutral amino acid transport system have been divided into three different category on basis of the affinity to the carrier, below 0.1mM, etween 0.1ImM-0.5mM and above 0.5mM. The $V_{max}$ was between $3.12{\mu}mole{\cdot}h^{-1}{\cdot}g$ fresh $weight^{-1}\;-\;15.1\;{\mu}mole{\cdot}h^{-1}{\cdot}g$ fresh $weight^{-1}$. Neutral amino acids cotransported with one $H^{+}per$ one molecule and one $K^{+}-efflux$ per one molecule for charge compensation. Histidine cotransported with proton per one molecule, however the movement of cotransported proton can't detectable because of the release of proton from the charged molecules of histidine in the medium.

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Dependence of Extinction Ratio on the Carrier Transport in $1.55{\mu}m$ InGaAsP/InGaAsP Multiple-Quantum-Well Electroabsorption Modulators ($1.55{\mu}m$ InGaAsP/InGaAsP 다중양자우물구조 전계흡수형 광변조기에서 캐리어 수송현상이 소광특성에 미치는 영향)

  • Shim, Jong-In;Eo, Yung-Seon
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.37 no.9
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    • pp.15-22
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    • 2000
  • The effects of carrier transport and input power on the extinction ratio was theoretically analyzed in a 1.55${\mu}m$ InGaAsP/InGaAsP multiple-quantum-well(MQW) electroabsorption(EA) modulator. Poisson's equation, current continuity equations for electrons and holes, and optical field distribution were self-consistently solved by considering electric field dependent absorption coefficients. The field screening effect due to the carrier accumulation in heterointerface and the space-charge region occurred more seriously at the input side of modulator as input optical intensity increased. It was revealed that extinction ratio could be steeply degraded for modulator with the length of 200${\mu}m$ when an input power exceeds 10mW. A degradation of extinction ratio due to the field screening effect would be more significantly at high-performance devices such as a 1.55${\mu}m$DFB-LD/EA-modulator integrated source where optical coupling efficiency is almost complete or a very high-speed modulator with its length as short as a few tens ${\mu}m$.

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Preparation and Characterization of Chitosan-coated PLGA Nanoparticle (키토산이 코팅된 PLGA 나노입자의 제조 및 특성)

  • Yu, Su-Gyeong;Nah, Jae-Woon;Jeong, Gyeong-Won
    • Applied Chemistry for Engineering
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    • v.32 no.5
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    • pp.509-515
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    • 2021
  • In this study, poly lactic-co-glycolic acid (PLGA) nanoparticles (PNP) were prepared through double (w/o/w) emlusion and emulsifying solvent-evaporation technique using PLGA, which has biocompatibility and biodegradability. To maximize stability and bioavailability of the particles, chitosan-coated PLGA nanoparticles (CPNP) were prepared by charge interaction between PNP and chitosan. We demonstrated that CPNP can be utilized as a drug carrier of oral administration. The chemical structure of CPNP was analyzed by 1H-NMR and FT-IR, and all characteristic peaks appeared, confirming that it was successfully prepared. In addition, particle size and zeta potential of CPNP were analyzed using dynamic light scattering (DLS) while morphological images were obtained using transmission electron microscope (TEM). Thermal decomposition behavior of CPNP was observed through thermogravimetric analysis (TGA). In addition, the cytotoxicity of CPNP was confirmed by MTT assay at HEK293 and L929 cell lines, and it was proved that there is no toxicity confirmed by the cell viability of above 70% at all concentrations. These results suggest that the CPNP developed in this study may be used as an oral drug delivery carrier.

Expression of Low Voltage-Activated $Ca^{2+}$ Channels in Xenopus Oocytes

  • Lee, Jung-Ha;Han, Dong-Pyo
    • Journal of Microbiology and Biotechnology
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    • v.11 no.4
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    • pp.614-618
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    • 2001
  • Low-threshold T-type $Ca^{2+}$ channels are distinctive voltage-operated gates for external $Ca^{2+}$ entry around a resting membrane potential due to their low voltage activation. These phenomena have already been extensively studied due to their relevance in diverse physiological functions. Recently, three T-type $Ca^{2+}$ channel ${\alpha}$$_1$subunits were cloned and their biophysical properties were characterized after expression in mammalian expression systems. In this study, ${\alpha_IG} and {\alpha_IH}$ low-threshold $Ca^{2+}$ channels were expressed and characterized in Xenopus oocytes after adding 5' and 3'untranslated portions of a Xenopus ${\beta}$ globin to improve their expression levels. The added portions dramatically enhanced the expression levels of the ${\alpha_IG} and {\alpha_IH}$ T-type channels. When currents were recorded in 10 mM $Ba^{2+}$ as the charge carrier, the activation thresholds were about -60 mV, peak currents appeared at -20 mV, and the reversal potentials were between +40 and +45. The activation time constants were very similar to each other, while the inactivation time constants of the ${\alpha_IG}$ currents were smaller than those of ${\alpha_IH}$. Taken together, the electrophysiological properties of the ${\alpha_IG} and {\alpha_IH}$ channels expressed in Xenopus oocytes were similar to the previously reported characteristics of low-threshold $Ca^{2+}$ channel currents.

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A Study on the Feasibility of the Electrostatic Cell (PN접합 SCR내 전하주입을 통한 정전기전지 제작 가능성에 관한 연구)

  • Kang Hoe-Jong
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.42 no.12
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    • pp.9-12
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    • 2005
  • This paper describes the feasibility of the electrostatic cell using carrier injection in SCR(space charge region) of PN junction. It compares the principle of the electrostatic cell's operation with the solar cell's. According to the experiment and calculation of this paper, when the cross section area of the device is $0.0001cm^2$, the device current becomes 0.15mA which is practically high enough. This paper proposes that the electrostatic cell can be used as a physical battery.

The Electronic and Thermoelectric Properties of Si1-xVx Alloys from First Principles

  • Ramanathan, Amall Ahmed;Khalifeh, Jamil Mahmoud
    • Applied Microscopy
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    • v.47 no.3
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    • pp.105-109
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    • 2017
  • The effect of temperature and vanadium metal concentration on the electronic and thermoelectric properties of Si in the diamond cubic structure has been investigated using a combination of density functional theory simulations and the semi classical Boltzmann's theory. The BotzTrap code within the constant relaxation time approximation has been used to obtain the Seebeck coefficient and other transport properties of interest for alloys of the structure $Si_{1-x}V_x$, where x is 0, 0.125, 0.25, 0.375, and 0.5. The thermoelectric properties have been extracted for a temperature range of 300 K to 1,000 K. The general trend with V atom substitution for Si causes the Seeback coefficient to increase and the thermal conductivity to decrease for the various alloys. The optimum values are for $Si_5V_3$ and $Si_4V_4$ alloys for charge carrier concentrations of $10^{21}cm^{-3}$ in the mid temperature range of 500~800 K. This is a very desirable effect for a promising thermoelectric and the figure of merit ZT approaches 0.2 at 600 K for the p-type $Si_5V_3$ alloy.

Ultra-Clean Patterned Transfer of Single-Layer Graphene by Recyclable Pressure Sensitive Adhesive Films

  • Kim, Sang Jin;Lee, Bora;Choi, Yong Seok;Kim, Philip;Hone, James;Hong, Byung Hee;Bae, Sukang
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.301.1-301.1
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    • 2016
  • We report an ultraclean, cost-effective, and easily scalable method of transferring and patterning large-area graphene using pressure sensitive adhesive films (PSAFs) at room temperature. This simple transfer is enabled by the difference in wettability and adhesion energy of graphene with respect to PSAF and a target substrate. The PSAF transferred graphene is found to be free from residues, and shows excellent charge carrier mobility as high as ${\sim}17,700cm^2/V{\cdot}s$ with less doping compared to the graphene transferred by thermal release tape (TRT) or poly(methyl methacrylate) (PMMA) as well as good uniformity over large areas. In addition, the sheet resistance of graphene transferred by recycled PSAF does not change considerably up to 4 times, which would be advantageous for more cost-effective and environmentally friendly production of large-area graphene films for practical applications.

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New Design and Synthesis of Donor-Acceptor units by Introducing Boron Based to Non-Boron based Semiconductor for high Voc OPV

  • Ryu, Ka Yeon;Cho, Kyuwan;Kim, Won-Suk;Kim, Kyungkon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.432.2-432.2
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    • 2016
  • A new A-D-A type (Acceptor-Donor-Acceptor) conjugated based on pyridine-borane complex (Donor), non-boron fluorine (Donor) and 2,5-bis(alkyl)-3,6-di(thiophen-2-yl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione (DPP) (Acceptor) were designed and synthesized via Pd-catalyzed Suzuki cross-coupling reaction. The synthesized boron based complex exhibited high electron affinity, which indicates deep HOMO energy levels and good visible absorption led to their use as donors in BHJ (bulk heterojunction) solar cells. Inverted devices were fabricated, reaching open-circuit voltage as high as 0.91eV. To probe structure-property relationship and search for design principle, we have synthesized pyridine-boron based electron donating small molecules. In this study, we report a new synthetic approach, molecular structure, charge carrier mobility and morphology of blended film and their correlation with the photovoltaic J-V characteristics in details.

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Effect of chemical doping on heterostructured Fe-based superconductor Sr2VO3FeAs

  • Ok, Jong Mok;Na, Se Woong;Kim, Jun Sung
    • Progress in Superconductivity and Cryogenics
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    • v.20 no.1
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    • pp.28-31
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    • 2018
  • Phase diagrams of electron- and hole-doped $Sr_2VO_3FeAs$ are investigated using Co and Mn substitution at Fe site. Metallic nature survives only for Co (electron) doping, not for Mn (hole) doping. The conductivity of $Sr_2VO_3(Fe,M)As$ (M=Mn,Co) is sensitive to the structural modification of FeAs microstructure rather than carrier doping. This finding implies that the FeAs layer plays a dominant role on the charge conduction, thus the $SrVO_3$ layers should be considered as an insulating block. Also, we found that the superconductivity is rapidly suppressed by both dopants. This result is different from the conventional behavior that superconductivity is induced by doping in the most of Fe pnictides. Our finding strongly supports the uniqueness of $Sr_2VO_3FeAs$ among the Fe pnictide superconductors.