• Journal of the Korean Chemical Society
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• v.30 no.5
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• pp.488-492
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• 1986

The $Ca^{++}$ and $Mg^{++}$ released during Ca, Mg-Na exchange on Kampo 78 montmorillonite which was treated with various concentrations of NaCl solution, were measured with EDTA titration metbod in the leaching solutions. Lanthanide montmorillonite was prepared with various neutral lanthanide ions from sodium montmorillonite in which the exchangeable ions are displaced from the exchanger, such as the displacement of $Na^+$ by $Ln^{3+}$ ions, Cation exchange capacity (CEC) is determined on remaining lanthanides in the leaching solutions with E. D. T. A titration method. As a results of this study, there were no difference of C. E. C in series of lanthanide contraction, but C. E. C depends on charge density of montmorillonite. When we conformed the structure of Ln-montmorillonite by X-ray diffraction. It was found that there was much difference of pattern between Na-montmorillonite and Ln-montmorillonite.

• Journal of the Korean Electrochemical Society
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• v.14 no.4
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• pp.239-244
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• 2011

In this study, $Fe_3O_4$/graphene and CuO/graphene composites were synthesized by the polyol reduction method using ethylene glycol, and their performances as the anodes of lithium ion batteries were evaluated. The physical characteristics of the synthesized composites were analyzed by SEM, XRD, and TGA. In addition, their electrochemical properties were examined by the electrochemical analysis techniques such as charge/discharge performance, cyclic voltammetry, and AC impedance spectroscopy. The cells composed of $Fe_3O_4$/graphene and CuO/graphene composites showed better performance than the graphene electrode, due to the dispersion of nanosized $Fe_3O_4$ or CuO on the surface of graphene and the formation of good electrical network in the electrode. Their composites kept the reversible capacity more than 600 mAh/g even after the charging/discharging of 30 cycles.

• ETRI Journal
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• v.42 no.1
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• pp.129-137
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• 2020

All-solid-state batteries are promising energy storage devices in which high-energy-density and superior safety can be obtained by efficient cell design and the use of nonflammable solid electrolytes, respectively. This paper presents a systematic study of experimental factors that affect the electrochemical performance of all-solid-state batteries. The morphological changes in composite electrodes fabricated using different mixing speeds are carefully observed, and the corresponding electrochemical performances are evaluated in symmetric cell and half-cell configurations. We also investigate the effect of the composite electrode thickness at different charge/discharge rates for the realization of all-solid-state batteries with high-energy-density. The results of this investigation confirm a consistent relationship between the cell capacity and the ionic resistance within the composite electrodes. Finally, a concentration-gradient composite electrode design is presented for enhanced power density in thick composite electrodes; it provides a promising route to improving the cell performance simply by composite electrode design.

• The Journal of Fisheries Business Administration
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• v.14 no.1
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• pp.19-43
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• 1983

Mankind has made traditional use of various ocean resources in such several forms as fish, plants food, means of transportation, and military purpose, followed by the recent exploitation of offshore subsoil or sea-bed minerals, energies, and utilization of ocean space. These available ocean resources come from the marine natural environment which has a distinct feature in view of the relationship between human wants and their capacity to meet them. Though these socially basic resources however bring forth the so-called scarcity or differential rent, their communal nature of ownership dissipates free gifts of nature endowed to society as a whole. Thus to maximize these rents and social welfare thereof, rents should be secured and preserved through a well-defined arrangements of property-ownership as well as appropriate comparison of competing uses of marine resources, taking full cognizance of their irreversible adverse effects of a specific choice on the alternatives. Here I showed the sources of rent yielded from the multiple uses of navigation, fishery, mariculture, minerals, and recreation site, and also summarized the presently widely-known analytic tool to measure these rents with emphasis on due care of the telescopic faulty of the appraiser in charge, viewed from the communal point, Finally, as communal property is in strict sense owned by the public at large, notwithstanding the restricted communal ownership at government or local governments control, effectiveness of competition I expect should be kept while transferring claims of these resources from the legal owner to private enterprise as well as while extracting their rent by her. In particular, various national or social objectives look forward to tile maximization of social efficiency. Discretionary system in noncompetitive method thus, is exceptionally suggested because of probable suspicion from the public whether these resources are transferred as a give away or not in discretion. And these realized rent payments, I propose, should be wisely taken advantage of in advancement of scientific research in marine nature to bring an incremental rent therefrom successively.

• Membrane and Water Treatment
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• v.11 no.3
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• pp.207-215
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• 2020

Vivianite (Fe₃²⁺(PO₄)2·8H₂O) and green rust ([Fe₄²⁺Fe₂³⁺(OH)^-₁₂][SO₄^2-·2H₂O]^2-), ferrous containing minerals, could remove aqueous U(VI) in 5 min. and the efficiencies of green rust were roughly 2 times higher than that of vivianite. The zeta potential measurement results implies that the better performance of green rust might be attributed to the favorable surface charge toward uranyl phosphate species. The removal behaviors of the minerals were well fitted by pseudo-second order kinetic model (R² > 0.990) indicating the dominant removal process was chemical adsorption. Effects of Ca²⁺ and CO₃^2- at pH 7 were examined in terms of removal kinetic and capacity. The kinetic constants of aqueous U(VI) were 8 and 13 times lower (0.492 × 10^-3 g/(mg·min); 0.305 × 10^-3 g/(mg·min)) compared to the value in the absence of the ions. The thermodynamic equilibrium calculation showed that the stable uranyl species (uranyl tri-carbonate) were newly formed at the condition. Surface investigation on the reacted mineral with uranyl phosphates species were carried out by XPS. Ferrous iron and U(VI) on the green rust surface were completely oxidized and reduced into Fe(III) and U(IV) after 7 d. It suggests that the ferrous minerals can retard U(VI) migration in phosphate-rich groundwater through the adsorption and subsequent reduction processes.

• Journal of the Korean Electrochemical Society
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• v.3 no.2
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• pp.90-95
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• 2000

Cycle life test was carried out to evaluate the failure modes of the gel type nth batteries at $C_5$ currents and $100\%$ DOD. When the batteries were charged at constant voltage of 2.40 V and 2.50 Vi respectively, cycle lift was over 1,000 cycles. The batteries lost 426.4 g and 391.2 g of electrolyte far each case after the weight measurement. The battery charged at 2.50 V was shown to have a better cyclic performance than charged at 2.40 V, and the amounts of electrolyte loss was proportional to charge factor. After cycle test, the micro-structure of positive active material was completely changed and the corrosion layer of positive grid was about $50{\mu}m$. Failure mode of the positive plate of the gel type battery was a shedding of the positive active material, and the cause of discharge capacity decrease was found to be a electrolyte loss.

• Korea Journal of Hospital Management
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• v.9 no.1
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• pp.46-65
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• 2004

The study was designed to investigate what effect of working time reduction which will be gradually expanded to corporate size from June, 2004 could give to medical industries, and to provide basic information for hospitals and government to prepare the policy. 276 hospitals were surveyed about medical service income and manpower realities during the first half of 2003, using a structured survey tool. Response rate was 8% and 20 hospitals were finally analyzed. The effect of working time reduction in hospital management was different to the size of hospitals and the alternative. Income to existing service income was decreased by $2.2{\sim}4.6%$ in tertiary hospitals, by $3.2{\sim}5.7%$ in general hospitals with more than 300 beds, and by $3.7{\sim}6.0%$ in general hospitals with less than 300 beds. In preparation against such decrease in income, government is required to raise insurance payment, to calculate added service charge for day-off on Saturday forenoon, to retain emergency care payment, to expand emergency care facilities, to secure duty doctors, and to support middle and small sized hospitals. Hospitals are required to give self improving efforts such as fortifying of weekday care, development of weekend care program, strengthening of care capacity and function of emergency care center, and making manpower operation efficient.

• Korea Journal of Hospital Management
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• v.21 no.1
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• pp.1-13
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• 2016

As the importance of strengthening the competency of managers who are in charge of cash collection and disbursement, and preparing for financial statements becomes more visible, this study examined the competency of middle-level managers of accounting department in general hospitals in Korea. Based on the literature, competency was measured by seven components: achievement and action, service, influence, management, cognition, individual effectiveness, and change management. Survey questionnaires included the respondents' perceived importance and performance of each of the seven components of competency. A total of 84 managers from 29 general hospitals responded to the survey between October 2015 and November 2015. Descriptive statistics, mean comparison (t-tests and ANOVAs), and multiple linear regression were conducted. The results of this study are as follows. Overall perceived importance of the competency was 4.16, while the performance was 3.87, and thus, the difference was 0.29. Among the seven components of the competency, cognition and change management had higher scores in terms of difference between the importance and performance. The regression analyses found that female managers had higher perceived importance and performance of competencies in achievement and action, and influence compared to male counterparts. In addition, participants in this study responded that main reasons for the gap between the perceived importance and performance are low compensation, lack of support, lack of knowledge, insufficient technical experience, excessive workload, and regulations. The results of this study can be used when designing capacity building training opportunities for the hospital accounting department. Also, the managers may evaluate themselves and look at the areas where they can narrow the gap between the perceived importance and performance of the competency that is required for today's leading managers.

• Applied Chemistry for Engineering
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• v.10 no.1
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• pp.80-84
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• 1999

$Li_{4/3}Mn_{5/3}O_4$ having a defect structure was prepared by sol-gel process using lithium acetate and manganese acetate as starting materials, and their electrode characteristics in the lithium secondary battery was investigated. The reaction mole ratio was determined as $AA/Mn(OAc)_2$ of 0.2 and $NH_4OH/Mn(OAc)_2$ to $H_2O/Mn(OAc)_2$ of 0.4. The product was obtained through heat treatment at $350^{\circ}C$ for 12hrs after 1'st heat treatment at $150^{\circ}C$ of xerogel under oxygen atmosphere. When the charge and discharge cycles were performed between 2.0 V and 3.2 V, $Li/Li_{4/3}Mn_{5/3}O_4$ cell showed the dicharge capacity of 84.23 mAh/g and the good cycleability was obtained in the plateau region.

• Journal of Korean Society of Water and Wastewater
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• v.28 no.4
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• pp.473-478
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• 2014

Microalgae is known as one alternative energy source of the fossil fuel with the small size of $5{\sim}50{\mu}m$ and negative charge. Currently, the cost of microalgae recovery process take a large part, about 20 - 30% of total operating cost. Thus, the microalgae recovery method with low cost is needed. In this study, the optimum current for Scenedesmus dimorphus recovery process using electrocoagulation techniques was investigated. Under the electrical current, Al metal in anode electrode is oxidized to oxidation state of $Al^{3+}$. In the cathode electrode, the water electrolysis generated $OH^-$ which combine with $Al^{3+}$ to produce $Al(OH)_3$. This hydroxide acts as a coagulant to harvest microalgae. Before applying in 1.5 L capacity electrocoagulation reactor, Scenedesmus dimorphus was cultured in 20 L cylindrical reactor to concentration of 1 OD. The microalgae recovery efficiency of electrocoagulation reactor was evaluated under different current conditions from 0.1 ~ 0.3 A. The results show that, the fastest and highest recovery efficiency were achieved at the current or 0.3 A, which the highest energy efficiency was achieved at 0.15 A.