• Title/Summary/Keyword: Charge and discharge current

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Electrochemical Characteristics of EDLC with various Organic Electrolytes (유기전해질에 따른 EDLC의 전기화학적 특성)

  • Yang Chun-Mo;Lee J.K.;Cho W.I.;Cho B.W.;Rim Byung-O
    • Journal of the Korean Electrochemical Society
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    • v.4 no.3
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    • pp.113-117
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    • 2001
  • Specific capacitance and charge-discharge rate of EDLC using activated carbon electrode were affected by the compositions of electrolytes, the conditions of charge-discharge and physical properties of activated carbon materials. The activated carbon electrode was prepared by dip coating method. Charge-discharge test and electrochemical experiments were carried out for various kinds of organic electrolytes. Effects of charge and discharge current density on the specific capacitance were studied. Characteristics of leakage current, self-discharge and time-voltage curves in optimum conditions of organic electrolytes were compared with conventional $1M-Et_4NBF_4/PC$ electrolyte. The EDLC using MSP-20(specific surface area: $2000m^2/g$) electrode and $1M-LiPF_6/PC-DEC(1:1)$ was exhibited th highest specific capacitance of 130F/g and low polarization resistances. The EDLC using MSP-20 electrode at $1M-LiPF_6/PC-DEC(1:1)$ was small leak current of 0.0004A for 15min, long voltage retention of 0.8V after 100h and linear time-voltage curves with small IR-drop.

Charge/discharge Capacity of Natural Graphite Anode According to the Charge/discharge Rate in Lithium Secondary Batteries (리튬 이차전지의 음극재료인 천연흑연의 충방전 속도에 따른 충방전 용량)

  • Ryu Ji Heon;Oh Eun Young;Oh Seung M.
    • Journal of the Korean Electrochemical Society
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    • v.7 no.1
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    • pp.32-37
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    • 2004
  • The charge/discharge capacity of natural graphite anode in lithium secondary batteries was examined as a function of charge/discharge rate. When the natural graphite anode was galvanostatically cycled in the range of 0.0-2.0V $(vs.\;Li/Li^+)$, the charging capacity decreased with an increase in the charging rate, which is caused by an earlier approach to the charging cut-off (0.0 V) before the complete charging that is in turn caused by an ever-increasing overpotential at higher rates. Even if the overpotential of discharging reaction also increased at higher discharge rates, the discharging reaction took place in the range of 0.0-0.3 V that is far below the discharge cut-off (2.0 V). As a result, the discharge capacity was not affected by the discharge rate because all the lithium ions once intercalated are fully discharged even at high current condition. As the overpotential of lithium deposition reaction also increased at high current condition, the charge capacity of natural graphite could be enlarged by lowering the charging cut-off voltage below 0.0 V, There is, however, a limitation for the lowering of cut-off voltage because the resistance for lithium deposition is smaller than that of lithium intercalation into graphite. When the charge cut-off voltage was lowered down to -0.04 V under IC condition, lithium ions were inserted into graphite without lithium deposition such that the discharge capacity could be raised up to $11\%$.

Improved Load Sharing Rate in Paralleled Operated Lead Acid Batteries (납 축전지의 병렬운전시 부하분담률 개선)

  • 반한식;최규하
    • The Transactions of the Korean Institute of Power Electronics
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    • v.6 no.1
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    • pp.34-42
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    • 2001
  • A battery is the device that transforms the chemical energy into the direct-current electrical energy directly without a mechanical process. Unit cells are connected in series to obtain the required voltage, while being connected in parallel to organize capacity for load current and to decrease the internal resistance for corresponding the sudden shift of the load current. Because the voltage droop down in one set of battery is faster than in tow one, it amy result in the low efficiency of power converter with the voltage drop and cause the system shutdown. However, when the system being driven in parallel, a circular-current can be generated. The changing current differs in each set of battery because the system including batteries, rectifiers and loads is connected in parallel and it makes the charge voltage constant. It is shown that, as a result the new batteries are heated by over-charge and over-discharge, and the over charge current increases rust of the positive grid and consequently shortens the lifetime of the new batteries. The difference between the new batteries and old ones is the amount of internal resistance. In this paper, we can detect the unbalance current using the micro-processor and achieve the balance current by adjusting resistance of each set. The internal resistance of each set becomes constant and the current of charge and discharge comes to be balanced by inserting the external resistance into the system and calculating the change of internal resistance.

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Experimental Study on the Discharge Electrode of A Two-Stage Electrostatic Air Cleaner (2단 평행판 전기집진기의 방전부 특성 실험)

  • Kim, I.S.;Lee, J.O.;Kim, Y.J.;Choi, H.O.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.5 no.1
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    • pp.27-34
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    • 1993
  • The two-stage electrostatic air cleaner is a particle control device that uses electrical forces to move particles in the flowing gas stream onto collector plates. Despite a general understanding of electrostatic air cleaner operation and their successful use in industry, many questions regarding flow, electric fields and particle collection have remained unanswered. In this paper, an experimental investigation for designing the discharge electrode, including ionizer wire diameter, plate length and wire-to-plate spacing, is carried out. The electrical conditions, namely the electric field intensity, the space current and the particle charge intensity, in wire-plate electrostatic air cleaner are reported and examined.

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Characteristics of RC Circuit with Transistors in Micro-EDM (트랜지스터 부착 RC 방전회로의 마이크로 방전가공 특성)

  • Cho Pil Joo;Yi Sang Min;Choi Deok Ki;Chu Chong Nam
    • Journal of the Korean Society for Precision Engineering
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    • v.21 no.12
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    • pp.44-51
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    • 2004
  • In a micro-EDM, it is well known that an RC circuit is suitable as a discharge circuit because of its low pulse width and relatively high peak current. To increase machining speed without changing unit discharge energy, charge resistance should be decreased. But, when the resistance is very low, continuous (or normal) arc discharge occurs, electrode wear increases and machining speed is reduced remarkably. In this paper, an RC circuit with transistors is used in a micro-EDM. Experimental results show that the RC circuit with transistors can cut off a continuous (o. normal) arc discharge effectively if the duty factor and switching period of the transistor are set up optimally. Through experiments with varying charge resistances, it is shown that the RC circuit with transistors has about two times faster machining speed than that of an RC circuit.

Charge/Discharge Properties of $V_{2}O_{5}$-Flyash Composite electrode for Supercapacitor (Supercapcitor용 $V_{2}O_{5}$-Flyash Composite 전극의 충방전 특성)

  • 김명산;김종욱;구할본;박복기
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.11a
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    • pp.335-338
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    • 2000
  • Carbon is an attractive candidate for use in eletrochemical supercapacitors that depend on charge storage in the electrode/electrolyte international double layer. Property of an electrical double layer capacitor depend both on the technique used to prepare the electrode and on the current collector structure. The study is to research that V$_2$O$_{5}$-flyash-AC composite electrode for supercapacitor. The discharge capacitance of V$_2$O$_{5}$-flyash-AC(70wt%) in 1st and 50th cycle was 18.6F/g and 15.13F/g at current density of 0.5mA/cm$^2$. The discharge process of V$_2$O$_{5}$-flyash (3 : 97)-AC composite electrode is larger than that others.thers.

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Fabrication of Graphene Supercapacitors for Flexible Energy Storage

  • Habashi, M. Namdar;Asl, Shahab Khameneh
    • Korean Journal of Materials Research
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    • v.27 no.5
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    • pp.248-254
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    • 2017
  • In the present work, graphene powder was synthesized by laser scribing method. The resultant flexible light-scribed graphene is very appropriate for use in micro-supercapacitors. The effect of the laser scribing process in reducing graphene oxide (GO) was investigated. GO was synthesized using a chemical mixture of GO solution; then, it was coated onto a LightScribe DVD disk and laser scribed to reduce GO and create laser-scribed graphene (LSG). The CV curves of pristine rGO at various scan rates showed that the ultimate product possesses the ability to store energy at the supercapacitor level. Charge-discharge curves of pristine rGO at two different current densities indicated that the specific capacitance ($C_m$) increases due to the reduction of the discharge current density. Finally, the long-term charge-discharge stability of the LSG was plotted and indicates that the specific capacitance decreases very slightly from its primary capacitance of ${\sim}10F\;cm^{-3}$ and that the cyclic stability is favorable over 1000 cycles.

An Experimental Study on the Implementation and Stabilization of Atmospheric Pressure Glow Discharge (대기압 글로우 방전의 구현 및 안정화에 대한 실험적 연구)

  • Choi, Sang-Won
    • Journal of the Korean Society of Safety
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    • v.23 no.4
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    • pp.42-46
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    • 2008
  • Ionizers are essential in various areas of manufacturing industries to protect electrostatic hazards and to reduce inferior products. For ion sources used in the charge neutralizers, there are corona discharge, soft X-ray, ultraviolet and glow discharge. Glow discharge has lots of attractive properties, such as lower discharge sustaining voltage, no generation of ozone, and so on. In this paper, we did an experimental study to trace the mechanism and stabilization of atmospheric pressure glow discharge using the several size and shape of electrodes. As an experimental result, to sustain conditions of atmospheric pressure glow discharge is that discharge voltage is 360V, discharge current is 12mA, apply frequency is 1kHz between electrodes when positive electrode is molybdenum(Mo) and negative electrode is copper(Cu). We confirmed that the mechanism and stabilization of atmospheric glow discharge is deeply concerned with the shape and material of electrode for discharge. Especially, glow discharge in atmospheric pressure was well generated and sustained according with the physical properties used electrode materials, example melting point, thermal conductivity, and etc.

A Study on the Performance of Recycled Cells for application to Residential BESS (주택용 BESS에 적용하기 위한 재활용 셀의 성능에 관한 연구)

  • Phil-Jung Kim;Seong-Soo Yang
    • Journal of IKEEE
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    • v.28 no.1
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    • pp.14-19
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    • 2024
  • To determine the performance of recycled cells for application to residential BESS, cells used over the past 5 years were selected. The basic specifications of the cell used in the test are nominal voltage of 3.7[V], nominal capacity of 2,200[mAh], charging voltage of 4.05[V], continuous discharge current of 1[C](2,200[mA]), continuous charging current of 0.5[C](1,100[mA]). For new cells, the internal resistance was 21.3±1[mΩ], but for recycled cells, the average internal resistance was 25.38[mΩ], an increase of about 19.1[%]. The charge·discharge capacity was approximately 18.9~19.3[%] lower than that of a new cell. Because internal resistance and charge·discharge capacity are closely related to cell aging, cells to be applied to BESS need to use products with an initial internal resistance of 1.5 times or less and a charge·discharge capacity performance of 70[%] or more.

Analysis of Space Charge Propagation in a Dielectric liquid Employing Field-Thermal Electron Emission Model and Finite Element Method (유한요소법과 전계-열전자 방출 모델에 의한 절연유체 내 공간전하 전파해석)

  • Lee, Ho-Young;Lee, Se-Hee
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.58 no.10
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    • pp.2011-2015
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    • 2009
  • In an insulating dielectric liquid such as transformer oil, space charge injection and propagation were analyzed under the Fowler-Nordheim and Richardson-Dushman's thermal emission charge injection conditions for blade-plane electrodes stressed by a step voltage. The governing equations were composed of all five equations such as the Poisson's equation for electric fields, three continuity equations for electrons, negative, and positive ions, and energy balanced equation for temperature distributions. The governing equations for each carrier, the continuity equations, belong to the hyperbolic-type PDE of which the solution has a step change at the space charge front resulting in numerical instabilities. To decrease these instabilities, the governing equations were solved simultaneously by the Finite Element Method (FEM) employing the artificial diffusion scheme as a stabilization technique. Additionally, the terminal current was calculated by using the generalized energy method which is based on the Poynting's theorem, and represents more reliable and stable approach for evaluating discharge current. To verify the proposed method, the discharge phenomena were successfully applied to the blade~plane electrodes, where the radius of blade cap was $50{\mu}m$.