• 전기의세계
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• v.26 no.2
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• pp.57-65
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• 1977

In roder to investigate the influence of treeing on electric breakdown of solid organic insulator the initiation and growing mechanism of tree itself, and the correlation between corona discharge and treeing phenomena in solid orgainc insulating materials, several experiments were carried out by means of needle test on polymethyl-methacrylate. The obtained results showed that the existence of voids in specimen had important effects on initiation voltage of trees and, when the direct voltage was applied, the initiation voltage of trees increased by space charge effect. And also the stagnation phenomena due to the transfer of vacancy cluster or polymekr cage in specimen might beconsidered in process of growth of trees, and corona discharge seemed to be the pre-phenomena of treeing because trees were normally initiated by internal discharge in voids.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.14 no.6
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• pp.267-271
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• 2004

Lithium cobalt oxide $(LiCoO_2)$ cathode powders for rechargeable battery have been successfully prepared using urea hydrolysis method. The obtained hydrolysis-derived precursors with different Li/Co molar ratio were calcined at various temperatures. Low temperature phase $(LT-LiCoO_2)$ and high temperature phase $(HT-LiCoO_2)$ were obtained after calcination at $500^{\circ}C$ for 2 hr, and phase transformation from $LT-LiCoO_2{\;}to{\;}HT-LiCoO_2$ was completely occurred over $700^{\circ}C$. The layered structure of $LiCoO_2$ was well developed with a rise in the calcination temperature. Charge-discharge test show that the lithium cobalt oxide with 1.2 molar ratio prepared at $800^{\circ}C$ has an initial discharge capacity as high as 152 mAh/g, and the relatively stable cycling characteristic with 9.2 % of capacity fading was obtained after 40th charge-discharge test.

• Transactions of the Korean hydrogen and new energy society
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• v.13 no.4
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• pp.259-269
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• 2002

A battery based on the lithium/elemental sulfur redox couple has the advantage of high theoretical specific capacity of 1,675 mAh/g-sulfur. However, Li/S battery has bad cyclic durability at room temperature due to sulfur active material loss resulting from lithium polysulfide dissolution. To improve the cycle life of Li/S battery, PEGDME (Poly(ethylene glycol) dimethyl ether) 500 containing 1M LiTFSI salt which has high viscosity was used as electrolyte to retard the polysulfide dissolution and nano-sized $Mg_{0.6}Ni_{0.4}O$ was added to sulfur cathode as additive to adsorb soluble polysulfide within sulfur cathode. From experimental results, the improvement of the capacity and cycle life of Li/S battery was observed( maximum discharge capacity : 1,185 mAh/g-sulfur, C50/C1 = 85 % ). Through the charge-discharge test, we knew that PEGDME 500 played a role of preventing incomplete charge-discharge $behavior^{1,2)$. And then, in sulfur dissolution analysis and rate capability test, we first confirmed that nano-sized $Mg_{0.6}Ni_{0.4}O$ had polysulfide adsorbing effect and catalytic effect of promoting the Li/S redox reaction. In addition, from BET surface area analysis, we also verified that it played the part of increasing the porosity of sulfur cathode.

• Advances in Energy Research
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• v.8 no.1
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• pp.41-57
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• 2022

Electrochemical double-layer capacitors (EDLCs) based on solid polymer electrolytes (SPEs) have gained an immense recognition in the present world due to their unique properties. This study is about preparing and characterizing EDLCs using a natural rubber (NR) based SPE with natural graphite (NG) electrodes. NR electrolyte was consisted with 49% methyl grafted natural rubber (MG49) and zinc trifluoromethanesulfonate ((Zn(CF₃SO₃)₂-ZnTF). It was characterized using electrochemical impedance spectroscopy (EIS) test, dc polarization test and linear sweep voltammetry (LSV) test. NG electrodes were made using a slurry of NG and acetone. EIS test, cyclic voltammetry (CV) test and galvanostatic charge discharge (GCD) test have been done to characterize the EDLC. Optimized electrolyte composition with NR: 0.6 ZnTF (weight basis) exhibited a conductivity of 0.6 x 10^-4 Scm^-1 at room temperature. Conductivity was predominantly due to ions. The electrochemical stability window was found to be from 0.25 V to 2.500 V. Electrolyte was sandwiched between two identical NG electrodes to fabricate an EDLC. Single electrode specific capacitance was about 2.26 Fg^-1 whereas the single electrode discharge capacitance was about 1.17 Fg^-1. The EDLC with this novel NR-ZnTF based SPE evidences its suitability to be used for different applications with further improvement.

• Advances in Energy Research
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• v.7 no.1
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• pp.21-34
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• 2020

Energy storage devices have received a keen interest throughout the world due to high power consumption. A large number of research activities are being conducted on electrochemical double layer capacitors (EDLCs) because of their high power density and higher energy density. In the present study, an EDLC was fabricated using natural graphite based electrodes and ionic liquid (IL) based gel polymer electrolyte (GPE). The IL based GPE was prepared using the IL, 1-ethyl-3-methylimidazolium trifluoromethanesulfonate (1E3MITF) with the polymer poly(vinyl chloride) (PVC) and the salt magnesium trifluoromethanesulfonate (Mg(CF₃SO₃)₂ - MgTF). GPE was characterized by electrochemical impedance spectroscopy (EIS), DC polarization test, linear sweep voltammetry (LSV) test and cyclic voltammetry (CV) test. The maximum room temperature conductivity of the sample was 1.64 × 10^-4 Scm^-1. The electrolyte was purely an ionic conductor and the anionic contribution was prominent. Fabricated EDLC was characterized by EIS, CV and galvanostatic charge discharge (GCD) tests. CV test of the EDLC exhibits a single electrode specific capacitance of 1.44 Fg^-1 initially and GCD test gives 0.83 Fg^-1 as initial single electrode specific discharge capacitance. Moreover, a good stability was observed for prolonged cycling and the device can be used for applications with further modifications.

• Journal of the Korea Computer Industry Society
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• v.3 no.12
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• pp.1651-1658
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• 2002

Recently power cable used generally in Korea, because installation is very simple and it has high stability. It confirms to the requirements of IEEE std. 404-1993 by factory testing, but many problems of insulated cable systems are caused by internal defects of the joint part which have to be mounted ensile. Especially, fault rates are arise from impurities or voids. A suitable solution for a monitoring of power cable during the after-laying test and service is partial discharge detection. The artificial defects between cable joint(EPR) and insulator(XLPE) interface are considered in this research to investigating the partial discharge characteristics. ${\varphi}$-q-n properties were detected using data acquisition system and Maximum charge($q_{max}$), repetition rate(${\={n}$), average charge(${\={q}$), Unbalance rate of ${\={n}$ and ${\={q}$ are calculated in order to analysis partial discharge properties quantitatively from this statistic value.

• Korean Chemical Engineering Research
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• v.50 no.6
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• pp.1043-1048
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• 2012

In this study, activated carbons (ACs) were modified as electrode materials for an electric double layer capacitor (EDLC) by controlling oxygen- and nitrogen-containing functional groups. The morphological and chemical properties of ACs were analyzed through scanning electron microscopy (SEM), fourier transform infrared (FTIR) spectrometer, automatic elemental analyzer (EA) and Boehm titration. Also, charge/discharge tests were performed to investigate the EDLC performance. Oxygen- and nitrogen-containing functional groups were introduced on the surface of ACs through acid and urea treatments, respectively. ACs with nitrogen-containing functional groups showed 2 mA increase of gravimetric discharge capacity and quick achievement of maximum charge/discharge performance. However, ACs with oxygen-containing functional groups showed low discharge capacity and its gradual decrease during further cyclic test, since the functional groups interrupted adsorption/desorption of charges in the electrolyte on the surface of ACs.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.27 no.6
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• pp.321-327
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• 2015

This study presents an HFC152a refrigerant air conditioner as an alternative to HFC134a, which is currently used in mobile air conditioning systems. Cool-down performance tests of an HFC152a air conditioning system were conducted and compared to a baseline HFC134a air conditioner. The experimental set-up consisted of a belt-driven compressor, a sub-cooled type condenser, an evaporator, and a block-type thermal expansion valve (TXV). A drop-in test was carried out on the mobile air conditioning system under various vehicle running speeds in a climate-controlled wind tunnel (CWT). Additionally, to optimize the HFC152a air conditioning system, the effects of the TXVs on the performance were studied. The results show that compared to the HFC134a air conditioning system, the refrigerant charge quantity was reduced by approximately 20%, the discharge pressure was reduced by about 350~430 kPa, and the air discharge temperature at vehicle running conditions was $0.5{\sim}1.5^{\circ}C$ lower. In addition, good compressor durability was expected due to the lower compression ratio.

• Progress in Superconductivity and Cryogenics
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• v.14 no.4
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• pp.41-45
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• 2012

An HTS (high temperature superconducting) coil without insulation has been investigated since a metallic insulation was suggested in the mid-1980s. The advantage of an insulationless HTS pancake coil is that it is more stable than an insulated HTS pancake coil. This paper focuses on the various characteristics of the insulationless HTS pancake coil related with stability, especially under the external magnetic field. Because HTS pancake coil may be influenced by the external magnetic field in a real operational environment of electrical devices. First, charge-discharge test was performed for the characteristics evaluation of the insulationless HTS pancake coil as compared with insulated HTS pancake coil in liquid nitrogen at 77 K. Based on the experiment results, characteristics evaluation of the insulationless HTS pancake coil was implemented under the external magnetic field. In order to carry out the experiment, we have fabricated a cylindrical solenoid coil to apply the magnetic field. The various characteristics of the insulationless HTS pancake coil were evaluated for charge-discharge and over-current conditions. This paper proves that the insulationless HTS pancake coil is more stable than the insulated HTS pancake under the external magnetic field.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.64 no.12
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• pp.1776-1781
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• 2015

Electric power trains receive electric power from overhead cables via a pantograph system. Power collector system in trains increase the cross section of tunnel and require a massive coreless filter reactor in propulsion inverter because of the power disturbance by contact loss phenomenon of a train. In this paper we proposed a wireless train which can run to next station with charging energy of ultra-capacitor module block. We designed DC-DC converter to charge and discharge ultra-capacitor modules by using Next Train running test results and confirm the feasibility of the proposed system through simulation.