• Proceedings of the Polymer Society of Korea Conference
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• 2006.10a
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• pp.192-192
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• 2006

Organic/organic and organic/inorganic multilayer films composed of organic polyelectrolytes (PE) and inorganic nanoparticles/platelets were prepared from the layer-by-layer (LbL) deposition using both spinning and dipping. The difference in both LbL methods is quantitatively compared in terms of internal layer ordering and physical properties of the multilayered films. Additionally, we suggest that the patterned multilayer films can be easily prepared by the combination of the spin SA and the lift-off method. Freestanding films were also prepared with the LbL deposition on low energy substrates, which allows the detailed analysis of composition within the films. Other LbL thin films prepared with block copolymer micelles will be discussed.

• Proceedings of the Polymer Society of Korea Conference
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• 2006.10a
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• pp.282-282
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• 2006

Nanoporous organosilicate thin films were realized by the microphase separation of pore generating components mixed with an organosilicate matrix. The refractive index of such nanoporous organosilicate films can be tuned in the range of $1.40{\sim}1.22$. With a nanoporous single layer with n ${\sim}1.225,\;99.85\;%$ transmittance in the visible range was achieved. In order to overcome the limitation on the narrow wavelength for high transmittance imposed by single nanoporous thin films, bilayer thin films with different reflectance for each layer were prepared by inserting high refractive index layer with a refractive index of 1.447. It is demonstrated that the novel broadband antireflection coating with improved transmittance can be easily achieved by the nanoporous bilayer thin films described in present study.

• Journal of Energy Engineering
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• v.20 no.3
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• pp.191-199
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• 2011

The char burn-out and NOx emissions from sub-bituminous coal were investigated in drop tube furnace under $O_2/N_2$ and $O_2/CO_2$ environments with different $O_2$ concentrations of 12, 21 and 31%. Results show that the char burn-out rate is faster as $O_2$ concentration increases higher and char burn-out rate under $O_2/CO_2$ decreases due to the lower oxygen diffusion into coal surface through the $CO_2$ rich boundary layer. NO concentration increases with increasing $O_2$ concentration, but declines at $O_2$ concentration of 31%. Meanwhile, NO emission indexes decreases monotonically with increasing $O_2$ concentration, which indicates that more NO reduction occurs with higher $O_2$ concentration probably due to greater HCN formation. For all conditions of $O_2$ concentration, the NO concentration under $O_2/N_2$ maintains higher than those of $O_2/CO_2$ due to presence of thermal NO.

• Journal of the Korean Society of Combustion
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• v.14 no.2
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• pp.1-9
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• 2009

New way to effectively capture $CO_2$ in coal fired power plant is the combustion of coal using oxy-fuel technology. Combustion characteristics of Minco sub-bituminous coal at oxy-fuel conditions using TGA and drop tube furnace (DTF) were included activation energy about the char burnout, volatile yield and combustion efficiency of raw coal, the porosity of pyrolyzed char and fusion temperature of by-product ash. TGA result shows that the effect of $CO_2$ on combustion kinetics reduces activation energy by approximately 7 kJ/mol at air oxygen level(21% $O_2$) and decreases the burning time by approximately 16%. The results from DTF indicated similar combustion efficiency under $O_2/CO_2$ and $O_2/N_2$ atmospheres for equivalent $O_2$ concentration whereas high combustion efficiency under $O_2/N_2$ than $O_2/CO_2$ was obtained for high temperature of more than $1,100^{\circ}C$. Overall coal burning rate under $O_2/CO_2$ is decreased due to the lower rate of oxygen diffusion into coal surface through the $CO_2$ rich boundary layer. By-product ash produced under $O_2/CO_2$ and $O_2/N_2$ was similar IDT in irrelevant to $O_2$ concentration and atmospheres gas during the coal combustion.

• Proceedings of the Polymer Society of Korea Conference
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• 2006.10a
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• pp.295-295
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• 2006

In present study, poly(acrylic acid) (PAA) and hydrophobically modified poly(ethylene oxide) (HM-PEO) multilayers based on the hydrogen bonding between the component polymer pair have been prepared by the LbL deposition method. Dip assembled HM-PEO/PAA multilayers yield unique film morphologies in comparison with PEO/PAA multilayers due to the micellar formation of HM-PEO owing to the hydrophobic attraction between alkyl chains end-capped with the PEO chains. Individual HM-PEO micelles were connected through the bridging PEO chains to form temporary networks on multilayer surface and induced peculiar surface morphology on HM-PEO/PAA multilayers above the critical number of bilayers.

• Proceedings of the Polymer Society of Korea Conference
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• 2006.10a
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• pp.310-310
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• 2006

We have demonstrated the formation of highly nanoporous films composed of two different BCMs through layer-by-layer (LbL) assembly on substrates. The films thus prepared showed tunable optical properties, with strong antireflective properties with light transmission above 99%. Considering the wide application areas of both LbL multilayers and block copolymer thin films, the approaches introduced in present study are likely to open up new possibilities for devices with multifunctional properties.

• Journal of Information Display
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• v.11 no.3
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• pp.123-127
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• 2010

Fluorescent white organic light-emitting diodes showing high color-rendering indices (CRIs) of up to 81 was demonstrated, with a silicon-cored anthracene derivative (PATSPA) doped with DPAVBi utilized as the deep-blue host and dye materials, and the commercial dyes rubrene and DCM2 utilized as the orange- and red-light-emitting dyes. The devices, consisting of three emissive layers, showed bright-white-light emission, but the ratio of the blue peak to the orange and red peaks changed with the current density and the thickness of the blue emissive layer. A high CRI was achieved with the use of a deep-blue emitter doped in a novel host and by optimizing the blue-layer thickness. The device with a blue-layer thickness of 10 nm showed the Commission Internationale de l'Eclairage (CIE) color coordinate of (0.33, 0.35), a high CRI of 81, and a moderate external quantum efficiency of 2% at a current density of $2.5\;mA/cm^2$.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2017.05a
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• pp.651-663
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• 2017

Experimental results of $30^{\circ}-15^{\circ}$ nozzles were compared with numerically calculated convective heat transfer coefficients using FLUENT, Boundary Layer Integration Method and Bartz predictions. Also, the convective heat transfer coefficients were calculated by using FLUENT and boundary layer integration method for NASA HIPPO nozzles according to the characteristics of combustion gas and the correlation between pressure and pressure was compared. Finally, thermal analysis of NASA HIPPO nozzle was performed to compare the ablation thickness and char depth according to the combustion gas characteristics.

• Journal of Korean Society for Atmospheric Environment
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• v.19 no.4
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• pp.427-436
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• 2003

This study is to establish a waste bed combustion model that can be available to assist the design of incinerators for efficient operation control of municipal waste incinerators. An unsteady one -dimensional bed combustion modeling was developed which incorporates the various sub-process models and solves the governing equations for both gases and solids in the waste bed combustion phenomena. The combustion characteristics and the properties of the combustion gas released from the bed were investigated by using a developed model. Besides, a sub-model which predicts the formation and destruction of nitrogen oxides in the waste bed was also developed as a post-processor for the waste combustion model. It is found that the reduction rate of nitrogen oxides is enhanced in the char layer.

• Journal of the korean Society of Automotive Engineers
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• v.4 no.2
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• pp.69-78
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• 1982

The purpose of this study is to investigate the flame propagation phenomenon in the combustion chamber of spark-ignition gasoline engine for the idling condition. by means of four ion probes located through the cylinder head, the time intervals for the flame to arrive at the respective probes are read on th visicorder char. As results, the flame is considered to initiate after some ignition delay and to propagate through the central space of combustion chamber with rather constant speed on the order of 25m/sec, and thereafter to be slowed down approaching the wall. Additionally, the retardation of flame in the wall boundary layer could be inferred. The maximum pressure is developed when the flame nearly touches the wall diagonal to the spark plug. And some features of flame propagation are elucidate.