• Title/Summary/Keyword: Changes of state of water

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Relationship between the Changes of Catecholamines and Blood Pressure Induced by Exposure to Low- and High-levels of Lead in Rats

  • Yoon, Suh-Young;Yoo, Kyeong-Seok;Cheong, Jae-Hoon
    • Biomolecules & Therapeutics
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    • v.7 no.4
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    • pp.322-328
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    • 1999
  • In this study, it was tested whether the changes of catecholamines and its metabolites are related with the changes of blood pressure(BP) induced by different levels of lead exposure. Adult male SD rats were exposed to lead by giving drinking water containing 50(low doses), 200 and 1,000 ppm(high doses) of lead(as lead acetate) or sodium acetate(for control groups, supplying an identical amount of acetate) for 7 or 16 weeks. The systolic BP was measured in the unanesthetized state by the tail-cuff technique. Levels of catecholamines and its metabolites in urine were measured by HPLC-ECD. Rats receiving 200 and 1,000 ppm developed an elevation of systolic BP at 3 and 7 weeks compared with week 0, but blood pressure levels at 16 weeks returned to normal. For the 50 ppm lead treated group, systolic BP increased significantly at 7 weeks and 16 weeks. The concentrations of norepinephrine and VMA in the urine of lead exposed rats changed similarly to the changes of blood pressure, but blood viscosity levels in all lead treated rats increased continuously during all lead treatment periods. This result suggests that the changes of catecholamines and its metabolites in urine by lead intoxication may influence the changes of blood pressure.

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Longitudinal and Vertical Variations of Long-term Water Quality along with Annual Patterns in Daecheong Reservoir

  • Lee, Sang-Jae;Shin, Jae-Ki;An, Kwang-Guk
    • Korean Journal of Ecology and Environment
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    • v.43 no.2
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    • pp.199-211
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    • 2010
  • The objectives for this study were to evaluate spatial and temporal characteristics of water quality, based on long-term water quality monitoring data during 1993~2008. We found that physico-chemical and ecological conditions in the Daecheong Reservoir (DR) were modified by the construction of upper dam (i.e., Yongdam Reservoir). total phosphorus (TP), Secchi depth (SD), and chlorophyll-a (CHL) in the DR showed significant longitudinal decreases along the headwater-to-the downlake, indicating a large spatial variation, and this gradient was more intensified during the high-flow season (monsoon). Nutrient-rich water containing high nitrogen and phosphorus in the monsoon season (July~August) passed through the reservoir as a density current in the metalimnetic depth, and also high suspended solids increased in the metalimnetic depth, especially during the monsoon. According to the deviation analysis of Trophic State Index (TSI), >50% of TSI (CHL)-TSI (SD) and TSI (CHL)-TSI (TP) values were negatives, so that inorganic suspended solids (non-votatile solids) influenced the underwater light regime against phytoplankton growth. Also, ratios of CHL:TP after the dam construction evidently increased, compared to the values before the upper dam constructions, indicating a greater yield of phytoplankton in the unit phosphorus. Overall data showed that ecological and functional changes in Daecheong Reservoir occurred after the construction of upper dam (Yongdam Reservoir).

Changes in Color Intensity of Extract from Hololeion Maximowiczii Root by Drying Methods (건조방법에 따른 께묵뿌리 추출물의 색도변화)

  • Choi, Dong-Yeon;Do, Jae-Ho;Lee, Kwang-Seung;Yang, Cha-Bum
    • Korean Journal of Food Science and Technology
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    • v.25 no.5
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    • pp.417-420
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    • 1993
  • Changes in color intensity of Hololeion maximowiczii(HM) roots which were treated with freeze drying (FD), $50^{\circ}C$ hot air drying (HAD) and $50^{\circ}C$ hot air drying after steam blanching (HADB) were investigated in this study. Color of HADB was yellow-green while other treatments showed bright brown color. In brown color intensity, optical density at 420 nm of FD treatment was highest but HADB treatment showed the highest value in ultra violet spectrum. Water soluble pigment of HM in state of aquous solution was more unstable for heat treatment than that in state of powder. Activation energy for decomposition of the pigment was 20.9 kcal/mole between $90{\sim}100^{\circ}C$ but 50.6 kcal/mole between $80{\sim}90^{\circ}C$.

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Effect of Number of Shutdown on the Decrease of Performance in PEM Water Electrolysis (PEM 수전해에서 정지횟수가 성능 감소에 미치는 영향)

  • Cheunho Chu;Jongwon Yang;Ilchai Na;Yoonjin Park
    • Korean Chemical Engineering Research
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    • v.61 no.2
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    • pp.202-207
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    • 2023
  • In the case of driving water electrolysis by receiving surplus electricity from solar and wind power generation, operation and stopping must be repeated according to weather fluctuations. When the PEMWE(Polymer Electrolyte Membrane Water Electrolysis) is driven and stopped, the PEM fuel cell is in the same state as the PEM fuel cell due to the residual hydrogen and oxygen, and the high potential of the water electrolysis formed during operation is highly likely to cause degradation of the electrode and membrane even during stopping. In this study, in order to check how much degradation of the electrode and membrane progresses during the repeated driving/shutdown process of PEM water electrolysis, the performance decrease was measured by changing the number of driving/shutdown for 144 hours. Changes in electrode catalyst active area, hydrogen permeability and fluorine emision rate of membranes were analyzed to measure changes in the properties of electrodes and polymer membranes. Overall, the PEMWE performance decreased as the number of stops increased. When stopped 5 times in 144 hours, the IrOx catalyst activity decreased by more than 30%, and the hydrogen permeability increased by 80%, confirming that both the electrode and the membrane were deteriorated.

An analysis on the characteristics of regasification system for LNG-FSRU depending on the changes in performance with vaporization and temperature of the heat source (LNG-FSRU용 재기화 시스템의 열원 온도 및 기화성능의 변동에 따른 시스템 특성분석)

  • Lee, Yoon-Ho;Kim, You-Taek;Kang, Ho-Keun
    • Journal of Advanced Marine Engineering and Technology
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    • v.38 no.6
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    • pp.625-631
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    • 2014
  • In this study, according to increase of thermoelectric power plants that use LNG, LNG-FSRU(Floating-Storage and Regasification Unit) appeared and it is installed on the Topside in order to deliver in a gaseous state to consumers who are in the shore. This study about the study on the characteristics analysis of the system depending on changes in performance with the vaporization and temperature of the heat source. For the characteristics analysis of the system, we devided vaporization method into Ethylene glycol water vaporization method and sea water as a heat source. Then the system that can vaporize 200ton per hour of LNG of $-157.9^{\circ}C$ and 10,400kPa was configured, and according to the temperature of supplied sea water, required minimum flow rate value was calculated. Also in case of using Ethylene glycol Water as a vaporization method, providing for regional and seasonal factors such as decrease of temperature of water. The system is configured by adding a steam boiler of $174.5^{\circ}C$, 775kPa as heat source. The generation amount of the steam required according to the performance of the vaporizer compared to the water temperature changes in the steam boiler and the amount of required evaporative performance due to changes in the quantity of steam and Ethylene glycol Water was confirmed.

Engineered biochar from pine wood: Characterization and potential application for removal of sulfamethoxazole in water

  • Jang, Hyun Min;Yoo, Seunghyun;Park, Sunkyu;Kan, Eunsung
    • Environmental Engineering Research
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    • v.24 no.4
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    • pp.608-617
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    • 2019
  • The adsorption of sulfamethoxazole (SMX) onto a NaOH-activated pine wood-derived biochar was investigated via batch experiments and models. Surprisingly, the maximum adsorption capacity of activated biochar for SMX (397.29 mg/g) was superior than those of pristine biochars from various feedstock, but comparable to those of commercially available activated carbons. Elovich kinetic and Freundlich isotherm models revealed the best fitted ones for the adsorption of SMX onto the activated biochar indicating chemisorptive interaction occurred on surface of the activated biochar. In addition, the intraparticle diffusion limitation was thought to be the major barrier for the adsorption of SMX on the activated biochar. The main mechanisms for the activated biochar would include hydrophobic, π-π interactions and hydrogen bonding. This was consistent with the changes in physicochemical properties of the activated biochar (e.g., increase in sp2 and surface area, but decrease in the ratios of O/C and H/C).

An Experimental Study on Transient Characteristics of PEM Fuel Cell Stack (PEM 연료전지 스택의 과도상태 출력특성에 관한 실험적 연구)

  • Kim, Hyun-il;Hwang, Jae-Soon;Chung, Tae-Yong;Shin, Dong-Hoon;Nam, Jin-Hyun;Kim, Young-Gyu
    • Proceedings of the KSME Conference
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    • 2007.05b
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    • pp.2003-2008
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    • 2007
  • The transient power characteristics of a PEM fuel cell stack was experimentally studied using a commercial 1.2kW PEM fuel cell ($Nexa^{TM}$ Power Module, Ballard Power System Inc.). The conditions in PEM fuel cell stack such as temperature and water content change rather slowly because of their large heat capacity and long channel length, which results in long transient time to converge to a steady state. The steady characteristics of the PEM fuel cell module was determined first, followed by the measurement of its transient characteristics upon stepwise and continuous load current changes. During the stepwise current change from 5A to 25A, the output voltage initially decreased below the steady voltage and then increased gradually. Similar behavior was also observed for the stepwise current change from 25A to 5A. This transient behavior is explained with reference to the evolution of the temperature and water content of the PEM fuel cell stack.

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Fabrication of Spiropyran-functionalized Photochromic Hydrogel Lenses

  • Lee, Cheol Woo;Badon, Isabel Wen;Kim, Boram;Ryu, Geun-Chang;Kim, Ho-Joong
    • Journal of Integrative Natural Science
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    • v.11 no.1
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    • pp.39-43
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    • 2018
  • Poly(hydroxyethyl methacrylate)-based hydrogels were surface-functionalized with spiropyran (SP) derivatives to obtain photochromic contact lenses. The contact lens reversibly changes from colorless to purple as response to UV light since colorless ring-closed SP state converts to purple ring-opened merocyanine (MC) state under UV light irradiation. The purple contact lens emits red light at 640 nm. Importantly, the presence of SP segments did not significantly affect the equilibrium water content (EWC) of the lens. SP-functionalized hydrogel lenses may find potential applications in developing light-adaptive ophthalmic materials.

Characterization of Algal Community of Yongdam Reservoir and Identification of Ecological Factors Inducing the Changes in Community Composition (용담호 조류군집의 시공간적 분포와 조류발생 요인분석)

  • Kim, Hyun-su;Jeong, Il-hwan
    • Journal of Soil and Groundwater Environment
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    • v.20 no.7
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    • pp.121-134
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    • 2015
  • Spatial and temporal changes in algal population in Yongdam reservoir and ecological factors that induced the changes in the size and composition of algal population were investigated by monthly sampling at ten locations in the reservoir. Nutritional state of the reservoir was identified to be phosphorus-limited with nitrogen to phosphorus (N : P) ratio much greater than 17 in most samples. Algal population was dominated by three taxonomic groups, diatoms, chlorophytes and cyanobacteria. Although explosive algal growth was not observed in the summer, algal population showed transition with time of the dominant algal type from diatoms in the winter to cyanobacteria in the summer. Chlorophyta was not the dominant group in the reservoir although they maintained relatively stable number of cells in the reservoir and showed increase in population from March to May. The application of statistical methods revealed that the factors inducing changes in cell number of each group were water temperature for diatoms and cyanobacteria and phosphorus concentration for chlorophyte. Fluctuation of cyanobacterial population was mainly observed near the inlet of tributaries while diatoms showed higher variation inside the reservoir.

Effects of freezing and thawing on retaining wall with changes in groundwater level

  • Kim, Garam;Kim, Incheol;Yun, Tae Sup;Lee, Junhwan
    • Geomechanics and Engineering
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    • v.24 no.6
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    • pp.531-543
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    • 2021
  • Freezing and thawing of pore water within backfill can affect the stability of retaining wall as the phase change of pore water causes changes in the mechanical characteristics of backfill material. In this study, the effects of freezing and thawing on the mechanical performance of retaining wall with granular backfill were investigated for various temperature and groundwater level (GWL) conditions. The thermal and mechanical finite element analyses were performed by assigning the coefficient of lateral earth pressure according to phase change of soil for at-rest, active and passive stress states. For the at-rest condition, the mobilized lateral stress and overturning moment changed markedly during freezing and thawing. Active-state displacements for the thawed condition were larger than for the unfrozen condition whereas the effect of freezing and thawing was small for the passive condition. GWL affected significantly the lateral force and overturning moment (Mo) acting on the wall during freezing and thawing, indicating that the reduction of safety margin and wall collapse due to freezing and thawing can occur in sudden, unexpected patterns. The beneficial effect of an insulation layer between the retaining wall and the backfill in reducing the heat conduction from the wall face was also investigated and presented.