• 제목/요약/키워드: Changes of ion content

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근적외선 필터용 인산계 유리의 광학적 특성 및 구조적 특성에 미치는 CuO 의 영향 (Effect of CuO on the Optical and Structural Properties of Phosphate Glass for Near-Infrard Filter)

  • 김성일;황종희;임태영;김진호;김영호;이종화;최덕균
    • 한국재료학회지
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    • 제19권12호
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    • pp.657-660
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    • 2009
  • Optical characteristics and structural changes depending on CuO content in phosphate glasses that are used in near-infrared (near-IR) filters were investigated. With phosphate glasses that contain 1-9 mol% CuO, changes in optical transmittance, optical absorption, and color coordinate were measured with a UV-VIS spectrophotometer. An XPS (X-ray photoelectron spectroscopy) analysis was performed to determine valence of copper ion that influences optical characteristics in near-IR filter glasses. Structural changes in glasses depending on CuO content were also analyzed by FT-IR (Fourier transform infrared) and Raman spectrophotometers. From the UV-VIS spectrophotometer results, strong absorption peaks at 220 & 900 nm were found and transmittance was decreased. The color coordinates of the glasses were shifted to the green color direction with CuO addition for increasing absorption of long wavelength range spectra, in spite of the amount of $Cu^{2+}$, which gives a blue color to glasses, and which was increased in XPS results. Also, structural de-polymerization of glasses with CuO addition were found by FT-IR and Raman results.

간척년수(干拓年數)에 따른 토성(土性) 및 작토층위별(作土層位別) 수종(數種) 화학성분변화(化學成分變化) 차이(差異)에 관(關)한 연구(硏究) (Changes of some chemical constituents in different soil depth with textures of Fluvio-marine soil under assessment of reclamation duration)

  • 김성채
    • 한국토양비료학회지
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    • 제20권1호
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    • pp.23-28
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    • 1987
  • 간척년수(干拓年數)에 따라 토층별(土層別) 토성(土性)이 다른 토양(土壤)에서 수종토양화학성분(數種土壤化學成分) 변화정도(變化程度)를 알고저 봉남통(鳳南統), 광활통(廣活統) 및 만경통(萬頃統)의 답토양(畓土壤)을 공시(供試)하여 시험(試驗)한 결과(結果)를 보면 다음과 같다. 1. 토양중(土壤中) 가리(加里), 석회(石灰), 고토(苦土), 소-다, 망간, 규산(硅酸) 및 양(陽)ion 치환용량등(置換容量等)은 간척년수(干拓年數)가 경과(經過)할수록 현저(顯著)한 감소(減少)를 보였음. 2. 토양유기물함량(土壤有機物含量)은 간척년수(干拓年數)의 경과(經過)에 따라 증가(增加) 되었는데 증가정도(增加程度)는 사질토양(砂質土壤)에서 현저(顯著)하였다. 그리고 우리나라 전국답토양(全國沓土壤) 평균치(平均値) 2.5%에 달(達)하기 위해서는 간척후(干拓後) 식질토양(埴質土壤)은 30년(年) 양질(壤質)과 사질토양(砂質土壤)은 약(約) 80년(年)이 경과(經過)되어야 할 것으로 예측(豫測)되어짐. 3. 토양중(土壤中) 가리활성도비(加里活性度比)는 토성(土性) 및 작토층위(作土層位)에 따라 상이(相異)했으나 일반답토양(一般沓土壤)의 평균(平均) 0.05~0.2 정도(程度)에 달(達)하기 위해서는 약(約) 50년(年)이 소요(消要)될 것으로 예측(豫測)되어짐. 4. $Na^{{+}{+}}$ion의 흡수율(吸收率), 흡착비등(吸着比等)은 간척년수(干拓年數)에 따라 현저(顯著)한 차이(差異)를 보였는데 특(特)히 사질토양(砂質土壤)에서 감소(減少)의 정도(程度)가 뚜렷하였음. 5. 간척년수(干拓年數)에 따른 점토함량변화(粘土含量變化)는 토층별(土層別)로 상이(相異)했는데 간척후(干拓後) 30년경(年頃)까지는 심토(深土)의 용탈(溶脫)이 현저(顯著)했으나 50년(年) 이후(以後)는 표토(表土)에서 용탈(溶脫)이 큰 경향(傾向)을 보였음.

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시판되는 각종 음료수내 불소 함량과 소아의 불소섭취에 관한 연구 (A STUDY ON THE FLUORIDE CONTENT OF THE COMMERCIALLY AVAILABLE BEVERAGES AND THE FLUORIDE INTAKE OF CHILDREN)

  • 이미나;이상훈;김종철
    • 대한소아치과학회지
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    • 제24권1호
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    • pp.125-138
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    • 1997
  • Along with recent economic prosperity, the consumption of commercially available beverages has increased dramatically. Beverages on the market are replacing tap water and constituting an increasing large proportion of the total daily fluoride intake. If such changes in the source of fluid intake are not taken into consideration, effective fluoride intake would become difficult in the fluoridated area while there would be confusion as to the basis for proper fluoride supplement prescription in the nonfluoridated area. So, dietary consultation is recommended for every pediatric patient. This study was conducted to provide the reference for dietary consultations on the subject of fluoride supplement using 72 beverages on the market. The fluoride content was measured and the fluoride intake from each age groups was calculated using fluoride ion specific electrode and HMDS-microdiffusion technique. 1. The average fluoride concentration of the 72 beverages was $0.23{\pm}0.10ppm$, from 0.0106ppm to 2.2050ppm. 2. Natural fruit juices, diluted fruit juices, carbonated beverages and mixed beverages showed average fluoride concentration of $0.15{\pm}0.66ppm$, $0.09{\pm}0.11ppm$, $0.15{\pm}0.23ppm$, $0.50{\pm}0.66ppm$, respectively. There were significant differrence between diluted friut juice drinks and mixed beverage, and between the carbonated beverages and mixed beverges(p<0.05). 3. Using available data on the daily total consumption of beverages and the relative consumption of beverages on the market according to age, daily fluoride intake for various age groups was calculated. According to the results, 2 to 3 year-old children need 0.13mgF/day, those between 4 and 6 year-old need 0.15mgF/day, and those between 7 and 10 year-old need 0.17mgF/day.

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RF 마그네트론 스퍼터링법으로 증착된 Li$_2$O-B$_2$O$_3$-SiO$_2$ 계 비정질 박막 고체전해질의 증착변수에 따른 이온전도 특성에 관한 연구 (Effect of Deposition Parameter on Ionic Conductivity of RF Magnetron Sputtered Li$_2$O-B$_2$O$_3$-SiO$_2$ Solid Electroiyte Films)

  • 노남석;권혁상
    • 한국표면공학회지
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    • 제27권2호
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    • pp.65-73
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    • 1994
  • Effects of deposition parameter on the ionic conductivity and structural change of the Lithium borosili-cate solid electrolyte films, prepared by rf sputtering using 7$LI_2O-3B_2O_3-1SiO_2$ single phase target and also a mosaic target enriched with $LI_2O$, were analyzed by measuring AC impedance and IR absorption spectra for the films. Thed solid electrolyte film deposited from the single phase target exhibited very low ionic conductivi-ty of $10^{-10}{\Omega}^{-1}cm{-1}$ at room temperature, a result of low $Li^+$ ion content(7.52 at%) in the film. The $Li^+$ con-ductivity for the films deposited from the mosaic target, however, significantly increased to $10^{-7}{\Omega}^{-1}cm{-1}$ due to both an increased $Li^+$content (14.75 at %) and a structural change of the films. The increased ionic conduc-tivity of the film appears to be associated with an easiness of ionic mobility by structural change of glassy film from a some close packed network structure to a open one. These structural changes of film were found to be closely related to the increase in the peak intensity at~$960cm^{-1}$ of IR absorption spectra for the glassy films. With increasing either argon pressure from 3 to 21 mtorr or rf power from 2 to 3 W/$cm^2$, the $Li^+$ conduc-tivity for the films significantly increased to an order of $10^{-6}{\Omega}^{-1}cm{-1}$ due to an increase in openness of film structure, as confirmed by both an increase in the IR absorption peak intensity at ~$960cm^{-1}$ and a resultant reduction of activation energy for mobility of $Li^+$ ion.

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토양 중 NaCl 농도에 따른 느티나무의 생리적 특성 변화 (Changes of Physiological Properties of Zelkova serrata to NaCl Concentration in Soil)

  • 송근준;한심희;하태주
    • 한국농림기상학회지
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    • 제5권3호
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    • pp.166-171
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    • 2003
  • 본 연구는 가로수의 염류 피해 원인을 밝히고, 생리생화학적 내성 특성을 구명하고자 하였다. 공시재료는 2년생 느티나무를 사용하였으며, NaCl을 0, 3, 14, 56, 112mM로 토양에 처리한 후, 근원경, 형성층 전기저항치와 잎 내 탄수화물 및 이온 함량 등을 측정하여 생리적인 피해 반응을 비교 분석하였다. 느티나무는 NaCl처리에 의해 생리적인 대사과정이 저해를 받은 것으로 나타났다. 특히 염류농도가 증가함에 따라 활력이 감소하였으며, 체내 이온농도가 변하여 이온 불균형이 발생하였다. 이러한 결과는 염류 처리에 의해 식물의 뿌리에서 수분 흡수력이 저해되면서 수분 스트레스가 유발되었기 때문인 것으로 판단된다. 반면 생장과 체내 탄수화물 대사에는 큰 영향을 주지 않았는데, 이것은 NaCl 처리 농도가 너무 낮았거나 처리 기간이 너무 짧았기 때문인 것으로 판단된다. 그러나 느티나무 가로수가 장기적으로 염류에 노출되었을 경우, 생장에 심각한 장애가 발생할 것으로 예측된다.

Analysis of Trans Fat in Edible Oils with Cooking Process

  • Song, Juhee;Park, Joohyeok;Jung, Jinyeong;Lee, Chankyu;Gim, Seo Yeoung;Ka, HyeJung;Yi, BoRa;Kim, Mi-Ja;Kim, Cho-il;Lee, JaeHwan
    • Toxicological Research
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    • 제31권3호
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    • pp.307-312
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    • 2015
  • Trans fat is a unsaturated fatty acid with trans configuration and separated double bonds. Analytical methods have been introduced to analyze trans fat content in foods including infrared (IR) spectroscopy, gas chromatography (GC), Fourier transform-infrared (FT-IR) spectroscopy, reverses-phase silver ion high performance liquid chromatography, and silver nitrate thin layer chromatography. Currently, FT-IR spectroscopy and GC are mostly used methods. Trans fat content in 6 vegetable oils were analyzed and processing effects including baking, stir-frying, pan-frying, and frying on the formation of trans fat in corn oil was evaluated by GC. Among tested vegetable oils, corn oil has 0.25 g trans fat/100 g, whereas other oils including rapeseed, soybean, olive, perilla, and sesame oils did not have detectable amount of trans fat content. Among cooking methods, stir-frying increased trans fat in corn oil whereas baking, pan-frying, and frying procedures did not make changes in trans fat content compared to untreated corn oils. However, the trans fat content was so low and food label can be declared as '0' trans based on the regulation of Ministry of Food ad Drug Safety (MFDS) (< 2 g/100 g edible oil).

Comparative Response of Callus and Seedling of Jatropha curcas L. to Salinity Stress

  • Kumar, Nitish;Kaur, Meenakshi;Pamidimarri, D.V.N. Sudheer;Boricha, Girish;Reddy, Muppala P.
    • Journal of Forest and Environmental Science
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    • 제24권2호
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    • pp.69-77
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    • 2008
  • Jatropha curcas L. is an oil bearing species with many uses and considerable economic potential as a biofuel crop. Salt stress effect on growth, ion accumulation, contents of protein, proline and antioxidant enzymes activity was determined in callus and seedling to understand the salt tolerance of the species. Exposure of callus and seedling to salt stress reduced growth in a concentration dependent manner. Under salt stress Na content increased significantly in both callus and seedling whereas, differential accumulation in the contents of K, Ca, and Mg was observed in callus and seedling. Soluble protein content differed significantly in callus as compared to seedling, however proline accumulation remained more or less constant with treatments. The proline concentration was ~2 to 3 times more in callus than in seedling. Salt stress induced qualitative and quantitative differences in superoxide dismutase (SOD; E.C. 1.15.1.1) and peroxidase (POX; E.C. 1.11.1.7) in callus and seedling. Salt induced changes of the recorded parameters were discussed in relation to salinity tolerance.

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Seasonal Characteristics of the Longitudinal Wavenumber-4 Structure in the Equatorial Ionospheric Anomaly

  • Kim, E.;Jee, G.;Kim, Y.H.
    • Journal of Astronomy and Space Sciences
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    • 제25권4호
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    • pp.335-346
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    • 2008
  • Using the global total electron contents (TEC) measured by the TOPEX satellite from Aug. 1992 to Oct. 2005, we investigate the variations of the longitudinal wavenumber-4 (LW-4) structure in the equatorial anomaly (EA) crests with season, local time, and solar activity. Our study shows that the LW-4 structure in the EA crests ($5{\sim}20^{\circ}$ MLAT in both hemispheres) has clear four peaks at fixed longitude sectors during the daytime for both equinoxes and June solstice. In spite of being called a wavelike structure, however, the magnitudes and spatial intervals of the four peaks are far from being the same or regular. After sunset, the four-peak structure begins to move eastward with gradual weakening in its amplitude during equinoxes and this weakening proceeds much faster during June solstice. Interestingly, the longitudinal variations during December solstice do not show clear four-peak structure. All these features of the LW-4 structure are almost the same for both low and high solar activity conditions although the ion densities are greatly enhanced from low to high solar activities. With the irrelevancy of the magnetic activity in the LW-4, this implies that the large changes of the upper atmospheric ion densities, one of the important factors for ion-neutral interactions, have little effect on the formation of the LW-4 structure. On the other hand, we found that the monthly variation of the LW-4 is remarkably similar to that of the zonal component of wavenumber-3 diurnal tides at low latitudes, which implies that the lower atmospheric tidal forcing, transferred to the upper atmosphere, seems to have a dominant role in producing the LW-4 structure in the EA crests via the E-region dynamo.

부유 단감 과실의 과육 갈변에 대한 에틸렌의 영향 (The Effect of Ethylene on the Fruit Flesh Browning in Fuyu Persimmon)

  • 최성진
    • 한국식품저장유통학회지
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    • 제4권1호
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    • pp.39-44
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    • 1997
  • Ethylene was treated or inhibited to investigate its effect on the physiological changes related to induction of flesh browning in Fuyu persimmon fruit. The response of fruit to ethylene was so slight, that the Fuyu fruit seemed to possess a similar characteristic to non-climacteric fruit. The flesh browning was however enhanced by ethylene treatment, although any significant increment of phenolic content or PPO activity in flesh tissue was not detected. Ethylene induced not only increasing of ion leakage from fruit tissue, but the fatty acids extracted from ethylene-treated fruit tissue were also more saturated. It was suggested that ethylene be related in the changing of membrane permeablity via saturating of fatty acid in membrane lipid. That could result in increased leakage of vacuole-stored phenolic compounds, which oxidized further by PPO to cause fruit flesh to brown.

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Spermidine이 배추 잎 원형절편의 노쇠과정에 미치는 효과 (Effects of Spermidine on the Senescence in Leaf Discs of Chinese Cabbage)

  • 신정림
    • Journal of Plant Biology
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    • 제31권2호
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    • pp.155-164
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    • 1988
  • The rapid senescence of detached Chinese cabbage leaf discs in darkness is first manifested by a sharp rise in malondialdehyde content (indicated by distruption of membrane structure), then by a rise in peroxidase activity and a decrease in catalase activity, and ultimately by chlorophyll degradation. These changes in parameters besides the catalase activity during senescence were delayed by application of spermidine. Especially, 10-4M spermidine almost completely arrested chlorophyll degradation after incubaton over 5 days. Spermidine reduced the amount of ethylene produced by senescing leaf discs. Additionally, it also reduced IAA-induced ethylene production. Calcium ion (1mM, 10mM) supplied together with the spermidine diminished the spermidine action, indicating probable involvement of an initial ionic attachment mechanism. These results suggest that spermidine can be used as an anti-senescence agent for plants and that this agent may stabilize membrane structure through interaction with the negatively charged loci on the membrane and exert the influence during senescence.

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