• Bulletin of the Korean Chemical Society
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• v.8 no.1
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• pp.31-39
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• 1987

By using a complete rate constant($k_e$) which treats a solvent (water) as a reactant, and a conventional rate constant($k_c$), which ignores the solvent in describing the rate, the parameters ${\Delta}V^{\neq}_s,\;{\Delta}H^{\neq}_s\;and\;{\Delta}S^{\neq}_s$ were introduced. These quantities represent the volume change, the enthalpy change, and the entropy change accompanying the electrostriction which occurs when solvent molecules condense on the activated complex. The authors measured the rates of the solvolysis of benzoyl chloride in water-acetone mixtures at $15^{\circ}$ to $30^{\circ}C$ and 1 bar to 2500 bars. Applying the authors' theory to the experimental results, the parameters, ${\Delta}V^{\neq}_s,\;{\Delta}H^{\neq}_s\;and\;{\Delta}S^{\neq}_s$ were evaluated, and it was found that they are all negative, indicating that water dipoles condense on the activated complex. They also proposed the following equations: ${\Delta}H^{\neq}_c\;=\;{\Delta}H^{\neq}_e\;+\;{\Delta}H^{\neq}_s\;and\; {\Delta}S^{\neq}_c\;=\;{\Delta}S^{\neq}_e\;+{\Delta}S^{\neq}_s\;,\;where\;{\Delta}H^{\neq}_c\;and\;{\Delta}H^{\neq}_c\;and\;{\Delta}S^{\neq}_s $are the activation enthalpy change and the activation entropy change for the conventional reaction rate, respectively, and ${\Delta}H^{\neq}_e$ and ${\Delta}S^{\neq}_e$ are the corresponding quantities for the complete reaction rate. The authors proposed that for the $SN_1$ type, all the quantities, ${\Delta}V^{\neq}_s,\;{\Delta}S^{\neq}_s\;,{\Delta}H^{\neq}_s\;and\;{\Delta}S^{\neq}_s$ are comparatively large, and for the $SN_2$ type, these quantities are smaller than for the $SN_1$ type, and occasionally the case ${\Delta}S^{\neq}_e$ < 0 occurs. Using these criteria, the authors concluded that at high temperature, high pressure and for a high water content solvent, the SN_1$ type mechanism predominates whereas in the reversed case the $SN_2$M type predominates.

• Journal of Korea Port Economic Association
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• v.34 no.4
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• pp.125-140
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• 2018

This study uses daily price data on three major types of crude oil (Brent, Dubai, and WTI) and BDI from January 2, 2009 to June 29, 2018, to compare the relationship between crude oil prices and BDI for rate of change and volatility. Unlike previous studies, the correlation between BDI and crude oil prices was analyzed both the rate of change and variability, VARs, Granger Causality Test, and the GARCH and DCC models were employed. The correlation analysis, indicated that the crude oil price change rate and volatility affect the BDI change rate and that BDI volatility affects the crude oil price change rate and volatility. The relationship between oil prices and BDI is identified, but their correlation is low, which is likely a result of lower dependence on crude oil as demand for natural gas increases worldwide and demand for renewable energy decreases. These trends could result in lower correlations over time. Therefore, focusing on the changing demand for raw materials in future investments in international shipping(real economy) and oil markets and macroeconomic analysis is necessary.

• Journal of Environmental Impact Assessment
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• v.12 no.1
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• pp.45-54
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• 2003

The purpose of this paper is to examine the trend on the change of the cherry blossom flowering time due to the temperature change by selecting regions that have long periods of cherry blossom flowering time data as cases. With the flowering time data, the distribution of cherry blossom flowering time, time series change and change rate of cherry blossom flowering time were analyzed. Also, the correlation between the cherry blossom flowering time and the temperature was analyzed. The flowering of cherry blossom is earlier in metropolitan areas, and in the east coastal region than the west coastal region. The trend on the change of the cherry blossom flowering time is very similar to change the temperature. The change rate of the cherry blossom flowering time is rising up in the whole regions under study, and is relatively high in metropolitan areas. Especially, the cherry blossom flowering time festinated greatly in Pohang that is one of the heavily industrialized cities. From the analysis of correlation analysis between cherry blossom flowering time and temperature elements, the cherry blossom flowering time is highly related with mean temperature of March, which the month is just before the beginning of flowering.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2011.11a
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• pp.111-113
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• 2011

This study investigated about how much the limestone's volume was changed as time passed while maintaining a certain level of moisture condition in the limestone material for concrete under high temperature. The result is summarized as follows: It was appeared that the limestone material under high temperature emitted some CO₂ resulting from the decarboxylation, so that as the heating temperature was increased, the limestone's length change rate was decreased. In the leave time change after heating the stone, the both conditions of 50% and 100% made the limestone create Ca(OH)₂ using some H₂O. So it was appeared that as time passed, the limestone's length change rate first increased because of its volume expansion, but the rate was reduced after the limestone material was crumbled.

• Particle and aerosol research
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• v.17 no.2
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• pp.29-36
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• 2021

In this study, the clean air delivery rate (CADR) of ceiling air circulator (CAA) was determined under indoor environmental simulation conditions. An air filter was used to provide air cleaning ability to the CAA. The CADR of filter adapted CAA was evaluated and compared with the value of commercial air purifier. The installation of mesh-shaped filter on the CAA showed particle reduction effect on the particles over 0.4 ㎛ in diameter, but the CADR was up to 0.25 m³/min. When the filter having 99.9% in collection efficiency was installed on the CAA, its CADR was 1.52 m³/min, while the CADR of commercial air purifier was 3.19 m³/min.

• Journal of KSNVE
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• v.11 no.1
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• pp.57-67
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• 2001

Proposed in this paper is a method of measurement of the flow rate in a pipe. The sound waves which are propagated within a pipe are characterized by that the wavenumber in the axial direction is changed according to the flow rate, and these characteristics are used in the present method of measurement of the flow rate. The amount of change in wavenumber of sound waves according to the flow rate can be obtained from the relationship among acoustic pressure signals within a pipe, which are measured by using a microphone array. The flow rate can be obtained by using the amount of change in wavenumber of sound waves and the relational equation of the flow rate. With respect to errors that can occur during the measurement of the flow rate, the types of errors and the method of correction of those errors are presented. This method of measurement of the flow rate has application limitation conditions due to the sensor interval, assumption of sound waves as plane waves, etc. The numerical simulation and experiments for measuring the flow rate of air in a pipe are performed in order to verify the applicability of this method of measurement of the flow rate. The experimental results are shown to be similar to those of the numerical simulation. And the flow rate measured is shown to be consistent with the actual value within 5% error bound.

• Journal of the Korean earth science society
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• v.23 no.2
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• pp.132-139
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• 2002

One of the prime objectives of school science is to help the children learn science concepts and conceptual schemes that will help them understand and interpret their environment. One of the basic scientific concepts is 'Change -everything existing in universe is changing always'. The purpose of this study was to investigate the characteristics of elementary and secondary students' conception of change. The subjects for this study were 489 students in Korea; 111 fourth graders, 95 sixth graders, 140 seventh graders and 143 ninth graders. Four items - mountain, river, ground, sea -were used for investigating students conception of change because representing the nature world in elementary and secondary level. The subjects were asked to check whether each item was changing and to explain each their check. Students' explanations were classified by whether they were sound understanding geologically, or not. The rate of responses that each item was changing was compared by grades and the rate of geological explanations was also compared by grades. Because students' conceptions of change might were effected by time scale, the additional questions that asked students whether the present status of four items were equivalent to the that of several points of time. As a result, the rate of scientific answers and patterns of explanations were similar by grade and the rate of geological understandings was relatively low. The frequencies of concept of change were more dropped as the point of time was closer to present.

• Magazine of the Korean Society of Agricultural Engineers
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• v.15 no.2
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• pp.2980-3001
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• 1973

Nozzle is a part of sprayer and is consists of several elements; swirl plate, vortexchamber, cap and body. The travelling distance of sprayed particles is important in the wide reach nozzle. The factors to influence the travelling distance of the sprayed particles may be the helical angle of swirl plate, the distance of vortex hamber, the slope and the size of cap hole. The study was conducted to examine the effects of these factors on the travelling distance. The results of this study are summarized as follows; 1) There was higher positive correlation(+0.96) between the maximum travelling distance for which amount of sprayed particles was 5cc/cm min. and centro-position of the travelling distance. 2) There was a higher positive correlation(+0.85) between total discharge of sprayed particles and the centro-position of the travelling distance. 3) Main effects and interaction effects of helical angle, pressure, vortex chamber distance and cap slope were significantly affected the travelling distance of sprayed particles. 4) Main effects of helical angle, pressure and cap slope were especially highly significant to influence the travelling disance. 5) Helical angle, pressure, vortex chamber distance and cap slope influenced spraying forward velocity of dise hole, among which cap slope and pressure of nozzle was the most important factors. 6) Effect of change of helical angle on the travelling distance of sprayed particles, was generally a quadratic, the least value of the distance being showed about $45^{\circ}$ and the largest at about $15^{\circ}\;and\;55^{\circ}$, the decreasing rate of the change between $15^{\circ};and\;25^{\circ}$ was very small. 7) Effect of change of pressure on the travelling distance sprayed particles was generally a linear, the increasing rate of the charge was about 1.68, which was the most effective compared to the change of the other factors. 8) Effect of change of vortex chamber distance on the spraying distance was also generally a linear, the increasing rate being about 0.16, which was the least effective. 9) Effect of change of cap slope on the travelling distance was also generally a linear, the increasing rate was about 0.61 and its effect was about medium.

• Journal of KIISE:Databases
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• v.32 no.2
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• pp.151-160
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• 2005

As web pages are created, destroyed, and updated frequently, web databases should be updated to keep up-to-date web pages. In order to keep web databases fresh effectively, we need to understand the change of real web pages. Previous researches on the change of the web pages have directed their efforts on the contents modification of web pages only, and have not taken into account the factors of creation and destruction of web pages In their research. This paper investigates the web page changes, which include contents modification, page creation, and page destruction. We introduce three metrics, namely DR (Download Rate), MR (Modification Rate), and CAV (Coefficient of Age Variation) to represent the change of the web pages. We have monitored three million web pages collected from the famous and random sites every other day for one hundred days. With the Download Rate and the Modification Rate, we learned that the download success and the modification depends on the past change of them, and proposes two estimation formulae that predict the download success and modification. With the Coefficient of Age Variation, we show how web pages do not change periodically.

• The Journal of Fisheries Business Administration
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• v.44 no.2
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• pp.1-17
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• 2013

We investigate the appropriateness of the fixed 12% discount rate to be used in estimating the amount of compensation for revoking a license for fishery business by the Enforcement Decree of Fisheries Act in Korea. We also suggest the appropriate discount rate fully reflecting the change of market interest rate in the Korean financial market. The capital asset pricing model, or, CAPM is the best known model of risk and return, and is widely used to estimate the expected rate of return for the risky projects. Even though the CAPM implies that the discount rate or the expected rate of return should change as the related market factors do, the discount rate used to estimate compensation for revoking a license for fishery business remains to be the same 12% rate for the last 15 years by law. During this period, however, the yield to maturity for the 5-year government bonds in Korea has dramatically changed from about 12% to less than 3%. In order to provide the fair compensation for the damages against the coastal fisheries and evaluate the intrinsic value of fishery resources in the coastal areas, we suggest that the appropriate discount rate should be determined by the yield to maturity of the government bonds with 5-year maturity, instead of the current fixed 12% interest rate.