• Title/Summary/Keyword: Chain matrix

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Effect of Rubber Particle Size and Polymer Properties on Impact Strength and Fracture Behavior of Rubber/Polymer Composites (고무입자의 크기와 폴리머의 물성이 고무/폴리머 복합재료의 충격강도 및 파괴거동에 미치는 영향)

  • 이창수;강병일;조길원;황운봉
    • Composites Research
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    • v.12 no.6
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    • pp.83-89
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    • 1999
  • The impact strength and fracture behavior of rubber/polymer composites were investigated with respect to two factors: (i) characteristic ratio, $C_{\infty}$ as a measure of chain flexibility of the polymer matrix and (ii) the rubber particle size in polymer blend system. In this study C was controlled by the composition ratio of polyphenylene oxide (PPO) and polystyene (PS). Izod impact test and fractographic observation of the fracture surface using scanning electron microscope were conducted. Finite element analysis were carried out to gain understanding of plastic deformation mechanism (shear yielding and crazing) of these materials. Shear yielding was found to be enhanced when the flexibility of matrix polymer was relatively low and the rubber particles were small.

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Enhanced Mechanical Properties of Functionalized Graphene Oxide/linear Low Density Polyethylene Composites Prepared by Melt Mixing

  • Chhetri, Suman;Samanta, Pranab;Murmu, Naresh Chandra;Kuila, Tapas;Lee, Joong Hee
    • Composites Research
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    • v.29 no.4
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    • pp.173-178
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    • 2016
  • Graphene oxide (GO) was concurrently reduced and functionalized using long alkyl chain dodecyl amine (DA). The DA functionalized GO (DA-G) was assumed to disperse homogenously in linear low density polyethylene (LLDPE). Subsequently, DA-G was used to fabricate DA-G/LLDPE composites by melt mixing technique. Fourier transform infrared spectra analysis was performed to ascertain the simultaneous reduction and functionlization of GO. Field emission scanning electron microscopy analysis was performed to ensure the homogenous distribution and dispersion of DA-G in LLDPE matrix. The enhanced storage modulus value of the composites validates the homogenous dispersion of DA-G and its good interfacial interaction with LLDPE matrix. An increased in tensile strength value by ~ 64% also confirms the generation of good interface between the two constituents, through which efficient load transfer is possible. However, no significant improvement in glass transition temperature was observed. This simple technique of fabricating LLDPE composites following industrially viable melt mixing procedure could be realizable to developed mechanically strong graphene based LLDPE composites for future applications.

Measurement of mechanical properties of Magneto-rhological Elastomer due to current and volume ratio of Carbonyl Iron Power (인가전류 세기와 CIP 성분비에 따른 MRE 의 기계적 물성 측정)

  • Oh, Jae-Eung;Yoon, Ji-Hyun;Yoon, Kyu-Seo;Chung, Kyung-Ho;Cho, Hyun-Chul;Lee, Seong-Hoon
    • Proceedings of the KSME Conference
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    • 2008.11a
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    • pp.791-794
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    • 2008
  • MRE(Magneto-rheological Elastomer) is a material which shows reversible and various modulus in magnetic field. Comparing to conventional rubber vibration isolator, MREs are able to absorb broader frequency range of vibration. These characteristic phenomena result from the orientation of magnetic particle (i.e., chain-like formation) in rubber matrix. In this study, NR was used as a matrix in order to manufacture MREs. Magnetic reactive powder(MRP), having rapid magnetic reaction, was selected as a magnetic particle to give magnetic field reactive modulus. The mechanical properties of manufactured MREs were measured without the application of magnetic field. The results showed that the tensile property and resilience were decreased while the hardness was increased with the addition of CIP. The analysis of MR effect was carried out by FFT analyzer with various magnetic flux. As the addition of MRP and magnetic flux increased, increment of MR effect was observed.

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Application of Quality Statistical Techniques Based on the Review and the Interpretation of Medical Decision Metrics (의학적 의사결정 지표의 고찰 및 해석에 기초한 품질통계기법의 적용)

  • Choi, Sungwoon
    • Journal of the Korea Safety Management & Science
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    • v.15 no.2
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    • pp.243-253
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    • 2013
  • This research paper introduces the application and implementation of medical decision metrics that classifies medical decision-making into four different metrics using statistical diagnostic tools, such as confusion matrix, normal distribution, Bayesian prediction and Receiver Operating Curve(ROC). In this study, the metrics are developed based on cross-section study, cohort study and case-control study done by systematic literature review and reformulated the structure of type I error, type II error, confidence level and power of detection. The study proposed implementation strategies for 10 quality improvement activities via 14 medical decision metrics which consider specificity and sensitivity in terms of ${\alpha}$ and ${\beta}$. Examples of ROC implication are depicted in this paper with a useful guidelines to implement a continuous quality improvement, not only in a variable acceptance sampling in Quality Control(QC) but also in a supplier grading score chart in Supplier Chain Management(SCM) quality. This research paper is the first to apply and implement medical decision-making tools as quality improvement activities. These proposed models will help quality practitioners to enhance the process and product quality level.

A Study on the Preparation of Nylon6,6/Polypyrrole Conducting Composite (Nylon6,6/Polypyrrole 전도성 복합체의 제조에 관한 연구)

  • Lee, Wan-Jin;Kim, Hyo-Yong
    • Applied Chemistry for Engineering
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    • v.10 no.2
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    • pp.281-286
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    • 1999
  • The conducting composites were prepared by blending polypyrrole (PPy) as a conducting polymer and nylon6,6 as a matrix. In chemical polymerization of PPy, the oxidizing agent was $FeCl_3$ and dopant was alkylbenzenesulfonic acid, such as camphorsulfonic acid (CSA) or dodecylbenzene sulfonic acid (DBSA). The electrical conductivity and mechanical properties were measured for the amount of dopant and PPy complex, and these morphology observed. When it was doped with DBSA having long alkyl chain and added the PPy complex of 25 wt %, the electrical conductivity was increased up to 0.64 S/cm.

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A Study on Statistical Modeling of Spatial Land-use Change Prediction (토지이용 공간변화 예측의 통계학적 모형에 관한 연구)

  • 김의홍
    • Spatial Information Research
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    • v.5 no.2
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    • pp.177-183
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    • 1997
  • S1he concept of a class in the land-use classification system can be equally applied to a class in the land-use-change classification. The maximum likelihood method using linear discriminant function and Markov transition matrix method were integrated to a synthetic modeling effort in order to project spatial allocation of land-use-change and quantitative assignment of that prediction as a whole. The algorithm of both the multivariate discriminant function and the Markov chain matrix were discussed and the test of synthetic model on the study area was resulted in the projection of '90 year as well as '95 year land -use classification. The accuracy and the issue of modeling improvement were discussed eventually.

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Mangiferin inhibits tumor necrosis factor-α-induced matrix metalloproteinase-9 expression and cellular invasion by suppressing nuclear factor-κB activity

  • Dilshara, Matharage Gayani;Kang, Chang-Hee;Choi, Yung Hyun;Kim, Gi-Young
    • BMB Reports
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    • v.48 no.10
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    • pp.559-564
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    • 2015
  • We investigated the effects of mangiferin on the expression and activity of metalloproteinase (MMP)-9 and the invasion of tumor necrosis factor (TNF)-$\alpha$-stimulated human LNCaP prostate carcinoma cells. Reverse-transcription polymerase chain reaction (RT-PCR) and western blot analysis showed that mangiferin significantly reversed TNF-$\alpha$-induced mRNA and protein expression of MMP-9 expression. Zymography data confirmed that stimulation of cells with TNF-$\alpha$ significantly increased MMP-9 activity. However, mangiferin substantially reduced the TNF-$\alpha$-induced activity of MMP-9. Additionally, a matrigel invasion assay showed that mangiferin significantly reduced TNF-$\alpha$-induced invasion of LNCaP cells. Compared to untreated controls, TNF-$\alpha$-stimulated LNCaP cells showed a significant increase in nuclear factor-${\kappa}B$ (NF-${\kappa}B$) luciferase activity. However, mangiferin treatment markedly decreased TNF-$\alpha$-induced NF-${\kappa}B$ luciferase activity. Furthermore, mangiferin suppressed nuclear translocation of the NF-${\kappa}B$ subunits p65 and p50. Collectively, our results indicate that mangiferin is a potential anti-invasive agent that acts by suppressing NF-${\kappa}B$-mediated MMP-9 expression.

Free vibration and harmonic response of cracked frames using a single variable shear deformation theory

  • Bozyigit, Baran;Yesilce, Yusuf;Wahab, Magd Abdel
    • Structural Engineering and Mechanics
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    • v.74 no.1
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    • pp.33-54
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    • 2020
  • The aim of this study is to calculate natural frequencies and harmonic responses of cracked frames with general boundary conditions by using transfer matrix method (TMM). The TMM is a straightforward technique to obtain harmonic responses and natural frequencies of frame structures as the method is based on constructing a relationship between state vectors of two ends of structure by a chain multiplication procedure. A single variable shear deformation theory (SVSDT) is applied, as well as, Timoshenko beam theory (TBT) and Euler-Bernoulli beam theory (EBT) for comparison purposes. Firstly, free vibration analysis of intact and cracked frames are performed for different crack ratios using TMM. The crack is modelled by means of a linear rotational spring that divides frame members into segments. The results are verified by experimental data and finite element method (FEM) solutions. The harmonic response curves that represent resonant and anti-resonant frequencies directly are plotted for various crack lengths. It is seen that the TMM can be used effectively for harmonic response analysis of cracked frames as well as natural frequencies calculation. The results imply that the SVSDT is an efficient alternative for investigation of cracked frame vibrations especially with thick frame members. Moreover, EBT results can easily be obtained by ignoring shear deformation related terms from governing equation of motion of SVSDT.

Effect of Linker for Immobilization of Glutathione on BSA-Assembled Controlled Pore Glass Beads

  • Chen, Li-Hua;Choi, Young-Seo;Park, Jung-Won;Kwon, Joseph;Wang, Rong-Shun;Lee, Tae-Hoon;Ryu, Sung-Ho;Park, Joon-Won
    • Bulletin of the Korean Chemical Society
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    • v.25 no.9
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    • pp.1366-1370
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    • 2004
  • Controlled pore glass bead was modified with bovine serum albumin (BSA), and glutathione (GSH) was immobilized through three kinds of linkers on top of BSA. Bis(3-sulfo-N-hydroxysuccinimide suberate) sodium salt $(BS^3)$, N-hydroxysuccinimide 3-(2-pyridyldithio)propionate (SPDP), or N-hydroxysuccinimide 4-maleimidobutyrate (GMBS) was introduced into the BSA-bound matrix. Subsequently, GSH was immobilized by addition of thiol side chain into the maleimido moiety, replacing a disulfide group, or formation of an amide group upon releasing 3-sulfo-N-hydroxysuccimide group. It was observed that conjugation methodology played a critical role for activity of the immobilized GSH. SDS-PAGE chromatogram showed that the matrix of glutathione immobilized on BSA through GMBS manifested high selectivity towards glutathione-S-transferase (GST) in cell lysate.

Dynamic response of underground box structure subjected to explosion seismic wave

  • Huang, Houxu;Li, Jie;Rong, Xiaoli;Fan, Pengxian;Feng, Shufang
    • Earthquakes and Structures
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    • v.10 no.3
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    • pp.669-680
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    • 2016
  • In this paper, the underground box structure is discretized as a system with limited freedoms, and the explosion seismic wave is regarded as series of dynamic force acting on the lumped masses. Based on the local deformation theory, the elastic resistances of the soil are simplified as the effects of numbers of elastic chain-poles. Matrix force method is adopted to analyze the deformation of the structure in elastic half space. The structural dynamic equations are established and by solving these equations, the axial force, the moment and the displacement of the structure are all obtained. The influences of size ratio, the incident angle and the rock type on the dynamic response of the underground box structure are all investigated through a case study by using the proposed method.