• Title/Summary/Keyword: Chain length

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Chain Length Dependence of Confined Liquid Crystals Configuration

  • Finotello, Daniele;Jin, Tao
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.256-259
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    • 2003
  • The study of confined liquid crystals flourished in the decade of the nineties. Liquid crystals properties have been probed after confinement in well-defined or interconnected geometries as those available in porous media and in polymer networks. In this work we emphasized the power of the nuclear magnetic resonance technique to determine the confined liquid crystal structures. We also present unexpected results on the dependence of the confined liquid crystal configuration on the chain length.

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Chain Length Dependence of Confined Liquid Crystals Configuration

  • Finotello, Daniele;Jin, Tao
    • Journal of Information Display
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    • v.4 no.1
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    • pp.14-16
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    • 2003
  • The study of confined liquid crystals flourished in the decade of the nineties. Liquid crystals properties have been probed after confinement in well-defined or interconnected geometries as those available in porous media and in polymer networks. In this work we emphasized the power of the nuclear magnetic resonance technique to determine the confined liquid crystal structures. We also present unexpected results on the dependence of the confined liquid crystal configuration on the chain length.

Cytotoxic activity of (2S, 3R, 4E) 5-Aryl-4-pentene-1,3-diol-2-aminoueras

  • Im, C.U.;Kim, Y.H.;Jyung, M.L.;Lim, C.B.
    • Proceedings of the PSK Conference
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    • 2003.04a
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    • pp.248.2-248.2
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    • 2003
  • The 18 ureidoceramide derivatives had been investigated for their cytotoxic activity against HT-29 colon cancer, Caki-2 renal cancer, A549 lung cancer, PC-3 prostate cancer, HL -60 leukemia cell using MTT assay. Cytotoxic activity was strongly influenced by the substituted alkyl chain length and the optimal alkyl chain length for cytotoxicity was C9-C12. (omitted)

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Cytotoxic activity of 1-phenyl-2-alkylsulfonylamido propanol derivatives

  • Im, Cha-Euk;Chung, Mi-Ryang;Kim, Yong-Hyun;Yin, Chul-Bu
    • Proceedings of the PSK Conference
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    • 2003.10b
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    • pp.185.1-185.1
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    • 2003
  • The 20 alkylsulfonylamido propanol derivatives had been investigated for their cytotoxic activity against HT-29 colon cancer, Caki-2 renal cancer, A549 lung cancer, PC-3 prostate cancer, HL-60 leukemia cell using MTT assay. Cytotoxic activity was strongly influenced by the substituted alkyl chain length and the optimal alkyl chain length for cytotoxicity was C11. Some of alkylsulfonylamido porpanol derivatives showed stronger activity than reference compound, B13.

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Cytotoxic activity of 1-phenyl-2-substituted thiourea derivatives

  • Im, C.U.;Park, Sang-Min;Jun, S.C.;Yim, C.B.
    • Proceedings of the PSK Conference
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    • 2002.10a
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    • pp.358.1-358.1
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    • 2002
  • The 20 thiourea derivatives had been investigated for their cytotoxic activity using MTT assay. Cytotoxic activity was strongly influenced by the substituted alkyl chain length. but not by configuration of Cl and C2. The optimal alkyl chain length for cytotoxicity was C12. The 9 thiourea derivatives showed stronger activity than reference compound. B13. some of them gave 2-3 times stronger activity than B13. (omitted)

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Highly flexible dielectric composite based on passivated single-wall carbon nanotubes (SWNTs)

  • Jeong, Hyeon-Taek;Kim, Yong-Ryeol
    • Journal of the Korean Applied Science and Technology
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    • v.32 no.1
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    • pp.40-47
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    • 2015
  • Single-walled carbon nanotubes (SWNTs) was modified with various length of linear alkyl chains and passivated to form dielectric filler. The modified SWNTs embedded into epoxy matrix to fabricate a flexible composite with high dielectric constant. The dielectric behavior of the composite was significantly changed with various alkyl chain length(n) of pyrene. The dielectric constant of the epoxy/SWNTs composite significantly increased with respect to increase in length of alkyl chain at the frequency range from 10 to 105Hz (n=12and18).We also found that the passivated epoxy/SWNTs composite with high dielectric constant presented low dielectric loss. The resulted dielectric performances corresponded to de-bundling of nanotubes and their distribution behavior in the matrix in terms of tail length of alkyl pyrene in the passivation layer.

Effect of Carboxylic Acid on Optical Properties of CuInS2/ZnS Semiconductor Nanocrystals (Carboxylic acid가 CuInS2/ZnS 반도체 나노입자의 광학적 특성에 미치는 영향)

  • Ahn, Si-Hyun;Choi, Gyu-Che;Beak, Yeun-Kyung;Kim, Young-Kuk;Kim, Yang-Do
    • Journal of Powder Materials
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    • v.19 no.5
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    • pp.362-366
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    • 2012
  • We report the effect of the chain length of carboxylic acid on the photoluminescence(PL) of $CuInS_2$/ZnS nanocrystals. $CuInS_2$/ZnS nanocrystals with emission wavelength ranging from 566 nm through 583 nm were synthesized with zinc acetate and carboxylic acids with various chain length. In this study, $CuInS_2$/ZnS nanocrystals prepared using long chain carboxylic acid showed more improved PL intensity. The origin of strong photoluminescence of the nanocrystals prepared with zinc acetate and long chain carboxylic acid was ascribed to improved size distribution due to strong reactivity between long chain carboxylic acid and zinc acetate.

Self-Updating One-Time Password Mutual Authentication Protocol for Ad Hoc Network

  • Xu, Feng;Lv, Xin;Zhou, Qi;Liu, Xuan
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.8 no.5
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    • pp.1817-1827
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    • 2014
  • As a new type of wireless network, Ad hoc network does not depend on any pre-founded infrastructure, and it has no centralized control unit. The computation and transmission capability of each node are limited. In this paper, a self-updating one-time password mutual authentication protocol for Ad hoc network is proposed. The most significant feature is that a hash chain can update by itself smoothly and securely through capturing the secure bit of the tip. The updating process does not need any additional protocol or re-initialization process and can be continued indefinitely to give rise to an infinite length hash chain, that is, the times of authentication is unlimited without reconstructing a new hash chain. Besides, two random variable are added into the messages interacted during the mutual authentication, enabling the protocol to resist man-in-the-middle attack. Also, the user's identity information is introduced into the seed of hash chain, so the scheme achieves anonymity and traceability at the same time.

Isolation of a Pseudomonas sp. Strain Exhibiting Unusual Behavior of Poly(3-hydroxyalkanoates) Biosynthesis and Characterization of Synthesized Polyesters

  • Chung, Chung-Wook;Kim, Yoon-Seok;Kim, Young-Baek;Bae, Kyung-Sook;Rhee, Young-Ha
    • Journal of Microbiology and Biotechnology
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    • v.9 no.6
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    • pp.847-853
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    • 1999
  • A Pseudomonas sp. strain that is capable of utilizing dicarboxylic acids as a sole carbon source was isolated from activated sludge by using the enrichment culture technique. This organism accumulated polyhydroxyalkanoates (PHAs) with an unusual pattern of monomer units that depends on the carbon sources used. Polyhydroxybutyrate (PHB) homopolyester was synthesized from glucose or small $C_{-even}$ alkanoic acids, such as butyric acid and hexanoic acid. Accumulation of PHB homopolyester was also observed in the cells grown on $C_{-odd}$ dicarboxylic acids, such as heptanedioic acid and nonanedioic acid as the sole carbon sources. In contrast, a copolyester consisting of 6 mol% 3-hydroxybutyrate (3HB) and 94 mol% 3-hydroxyvalerate (3HV) was produced with a PHA content of as much as 36% of the cellular dry matter. This strain produced PHAs consisting both of the short-chain-length (SCL) and the medium-chain-length (MCL) 3-hydroxyacid units when heptanoic acid to undecanoic acid were fed as the sole carbon sources. Most interestingly, polyester consisting of significant amount of relevant fractions, 3HB, 3HV, and 3-hydroxyheptanoate (3HHp), was accumulated from heptanoic acid. According to solvent fractionation experiments, the polymer produced from heptanoic acid was a blend of poly(3HHp) and of a copolyester of 3HB, 3HV, and 3HHp units. The hexane soluble fractions contained only 3HHp units while the hexane-insoluble fractions contained 3HB and 3HV units with a small amount of 3HHp unit. The copolyester was an elastomer with unusual mechanical properties. The maximum elongation ratio of the copolyester was 460% with an ultimate strength of 10 MPa, which was very different from those of poly(3HB-co-3HV) copolyesters having similar compositions produced from other microorganisms.

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Liquid crystal alignment on rubbed self-assembled monolayers according to alkyl chain length (알킬 사슬 길이에 따른 러빙 처리된 자기 조립 단분자막의 액정 배향 연구)

  • Park, Hong-Gyu;Park, Mu-Hun
    • The Journal of Korea Institute of Information, Electronics, and Communication Technology
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    • v.14 no.5
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    • pp.362-368
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    • 2021
  • A homeotropic liquid crystal (LC) alignment state on rubbed fluorinated self-assembled monolayers (FSAMs) is described according to alkyl chain length. A simple procedure, gas-phase method, for the preparation of FSAM was used. The average optical transmittance in the visible light range of FSAMs were 76.63% to 78.21%, which were superior to the conventional polyimide layer having a transmittance of 75.89%. In addition, the excellent homeotropic LC alignment characteristics of FSAMs were observed through pretilt angle measurement and polarized optical microscope images. By measuring the contact angles and the surface energies of FSAMs, it was confirmed that pretilt angles of LC molecules increased according to the alkyl chain length. High optical transparency and uniform homeotropic LC alignment characteristics of FSAMs showed the possibility of FSAMs as an LC alignment layers.