• 제목/요약/키워드: Chain Structure

검색결과 1,302건 처리시간 0.023초

Rheological properties of branched polycarbonate prepared by an ultrasound-assisted intensive mixer

  • Kim, Hyung-Su;Lee, Hoo-Seok;Lee, Jae-Wook
    • Korea-Australia Rheology Journal
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    • 제19권1호
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    • pp.1-5
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    • 2007
  • By combining ultrasonic energy which is essential for the chain scission of polymer molecules and a multifunctional agent (MFA) having double bonds at its ends, we were able to modify the molecular structure of polycarbonate (PC) from linear to a branched structure during melt processing. The three double bonds in chain ends of MFA were expected to act as sites for trapping macroradicals of PC during the course of ultrasound-assisted mixing process. The transformation of molecular structure of PC was confirmed by the measurements of rheological properties of the modified PC. After the ultrasonic irradiation of PC together with MFA, increase in complex viscosities and shear-thinning behavior were observed. The Cole-Cole plot and measurement of extensional viscosities revealed the characteristic features of branched structure with well-defined extensional behavior which is comparable to that of a commercial branched PC.

Thermal and Mechanical Properties of Polyurethanes based on Novel Chain Extender

  • Lee Dong-Won;Kim Won-Gi;Park Jun-Ho;Im Sang-Gyu;Son Tae-Won
    • 한국섬유공학회:학술대회논문집
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    • 한국섬유공학회 1998년도 가을 학술발표회논문집
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    • pp.66-69
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    • 1998
  • Most segmented polyurethanes are prepared from a two-step method where the polyol is end-capped with an excess of diisocyanate, followed by chain extension with stoichiometric amount of chain extender, In the final polymer the hard and soft segments tend to segregate, due to thermodynamic immiscibility and the differences in chemical structure between hard and soft segments, and produce a phase separated morphology of hard segment-rich and soft segment-rich phase. (omitted)

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Bayesian Conjugate Analysis for Transition Probabilities of Non-Homogeneous Markov Chain: A Survey

  • Sung, Minje
    • Communications for Statistical Applications and Methods
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    • 제21권2호
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    • pp.135-145
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    • 2014
  • The present study surveys Bayesian modeling structure for inferences about transition probabilities of Markov chain. The motivation of the study came from the data that shows transitional behaviors of emotionally disturbed children undergoing residential treatment program. Dirichlet distribution was used as prior for the multinomial distribution. The analysis with real data was implemented in WinBUGS programming environment. The performance of the model was compared to that of alternative approaches.

역삼투막 재료

  • 김창근
    • 한국막학회:학술대회논문집
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    • 한국막학회 1998년도 심포지움시리즈 Jan-98 역삼투용 분리막 기술 및 응용
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    • pp.31-55
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    • 1998
  • 1. Performance of RO membrane depends on chain structure (packing density) 2. Crosslinking of main chain is essential for the high performance RO membranes 3. Various bisphenols and polyaminostyrene can be promising materials for the fabrication of RO membranes. 4. By using of blend technique of reactant, we can expect broad spectrum of RO membrane and synergetic effects in membrane performance.

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콜드체인 시스템의 센서태그 운영 최적화를 위한 DEVS 기반 시뮬레이션 모델 (DEVS-Based Simulation Model for Optimization of Sensor-Tag Operations in Cold Chain Systems)

  • 류옥현;강용신;진희주;이용한
    • 대한산업공학회지
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    • 제41권2호
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    • pp.173-184
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    • 2015
  • The application of radio frequency identification (RFID) sensor-tags in cold chain systems has recently received a great deal of attention. To design cold chain systems with RFID sensor-tags that minimize the initial investment and operational cost while fulfilling the functional and operational requirements, simulation study is one of the preferable and effective approaches. To simulate the possible design configurations, the individual components in a cold chain system can be extracted and implemented as a DEVS (Discrete Event System Specification) model. Based on the proposed DEVS model, a new cold chain simulation model can be efficiently created by simply connecting each DEVS model around the RFID sensor-tag of interest in sequence according to the structure of the cold chain system, and then executed (or simulated) on Java programming environments by the DEVSJAVA simulator. As a result of simulation, some key performance indexes such as reliability, accuracy or timeliness can be calculated and used to choose better components or to compare different system configurations of cold chain systems.

고하중용 버킷 롤러체인 시스템의 다물체 동역학 해석 및 내구성 연구 (Study on Multibody Dynamic Analysis and Durability of Heavy Load Bucket Roller Chain System)

  • 김창욱;박진철;이동우;송정일
    • 한국정밀공학회지
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    • 제33권11호
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    • pp.919-925
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    • 2016
  • In this study, multibody dynamic and mechanical analyses were conducted for the structure of roller chain bucket elevator system. The fatigue life of the roller chain elevator system was determined under static and fatigue loadings. Results of multibody dynamic analysis suggested that the maximum contact force occurred at the drive sprocket engagement point with the roller chain due to maximum tension. Fatigue analysis results suggest that the high load roller chain system is durable and safe because its life time is more than 700,000 cycles, close to its designed value (1,000,000 cycle). However, the contact portion of plate and pin needed a safety factor. The dynamic analysis of the heavy load roller chain was conducted with a multibody dynamic analysis program. The results obtained in this study can be utilized for dynamic analysis of roller chain systems in all industries.

Varietal Variations in Physicochemical Characteristics and Amylopectin Structure of Grain in Glutinous Rice

  • Choi, Hae-Chune;Hong, Ha-Cheol;Kim, Yeon-Gyu;Nahm, Baek-Hie
    • 한국작물학회지
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    • 제44권3호
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    • pp.207-213
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    • 1999
  • Thirty-eight glutinous rice varieties were classified into nine groups on the scatter diagram by the upper two principal components (56% contribution to the total information) based on eleven physicochemical characteristics including the viscograms and physical properties of cooked rice. The first principal component was the factor mainly associated with the viscogram characteristics of rice flour emulsion and the second was the factor chiefly related to the physical properties of cooked rice and water absorbability of rice grain. Indica glutinous rices were clearly distinguished from japonica ones by the first principal component score. Javanica glutinous rices were widely distributed on the intermediate zone between indica and japonica or on several japonica rice groups. Significant positive or negative correlations were found among water absorption rates of rice grain, physical properties of cooked rice, and viscogram characteristics of rice flour. Especially in japonica glutinous rices, the breakdown and setback viscosities of rice flour were closely associated with the alkali digestion value of milled rice and the stickiness of cooked rice. The frequency ratio of short glucose chains (A-chain) to intermediate glucose chains (B-chain), the ratio of B- chains to long glucose chains (C-chain) and the relative frequency of A- or B-chain fractions representing the amylopection structure of rice starch was closely associated with the breakdown and setback viscosities of rice flour.

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IEEE 1149.1 표준에 근거한 다중 클럭을 이용한 단일 캡쳐 스캔 설계에 적용되는 경계 주사 테스트 기법에 관한 연구 (Test Methodology for Multiple Clocks Single Capture Scan Design based on JTAG IEEE1149.1 Standard)

  • 김인수;민형복
    • 전기학회논문지
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    • 제56권5호
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    • pp.980-986
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    • 2007
  • Boundary scan test structure(JTAG IEEE 1149.1 standard) that supports an internal scan chain is generally being used to test CUT(circuit under test). Since the internal scan chain can only have a single scan-in port and a single scan-out port; however, existing boundary test methods can not be used when multiple scan chains are present in CUT. Those chains must be stitched to form a single scan chain as shown in this paper. We propose an efficient boundary scan test structure that adds a circuit called Clock Group Register(CGR) for multiple clocks testing within the design of multiple scan chains. The proposed CGR has the function of grouping clocks. By adding CGR to a previously existing boundary scan design, the design is modified. This revised scan design overcomes the limitation of supporting a single scan-in port and out port, and it bolsters multiple scan-in ports and out ports. Through our experiments, the effectiveness of CGR is proved. With this, it is possible to test more complicated designs that have high density with a little effort. Furthermore, it will also benefit in designing those complicated circuits.