• 제목/요약/키워드: Chain Structure

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Molecular Structure and Gelatinization Properties of Turnip Starch (Brassica rapa L.)

  • Kim, Nam-Hee;Yoo, Sang-Ho
    • Food Science and Biotechnology
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    • 제14권4호
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    • pp.470-473
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    • 2005
  • Starch was isolated from turnip (Brassica rapa L.), and to elucidate the structure-function relationship its structural and physical properties were characterized. Morphological structure of the starch was analyzed by SEM (Scanning Electron Microscopy). Most of the starch granules were spherical in shape with diameter ranging from 0.5-10mm. Apart from larger granules ($<10\;{\mu}m$) which dominated the population size of turnip starch, significant amount of small ($0.5-2\;{\mu}m$) and mid-size granules (${\sim}\;{\mu}m$) were also detected. It was revealed that presumably, erosion damages occurred due to the attack of amylase-type enzymes on the surface of some granules. Branch chain-length distribution was analyzed by HPAEC (High-Performance Anion-Exchange Chromatography). The chain-length distribution of turnip starch revealed a peak at DP12 with obvious shoulder at DP18-21. The weight-average chain length ($CL_{avg}$) was 16.6, and a large proportion (11.8%) of very short chains (DP6-9) was also observed. The melting properties of starch were determined by DSC (Differential Scanning Calorimetry). The onset temperature ($T_o$) and the enthalpy change (${\Delta}H$) of starch gelatinization were $50.5^{\circ}C$ and 12.5 J/g, respectively. The ${\Delta}H$ of the retrograded turnip starch was 3.5 J/g, which indicates 28.2% of recrystallization. Larger proportion of short chains as well as smaller average chain-length can very well explain relatively lower degree of retrogradation in turnip starch.

공급사슬구조에 따른 경영성과에 관한 연구 (A Study on the Management Performance Depends on the Supply Chain Structure)

  • 장형욱;이상식
    • 한국산업정보학회논문지
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    • 제10권4호
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    • pp.110-119
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    • 2005
  • 본 논문은 공급사슬구조를 크게 공급네트워크(supply network), 전환네트워크(conversion network), 그리고 유통네트워크(distribution network)라는 세 유형의 구조로 구분하였으며 각 공급사슬구조별 경영성과에 어떠한 영향을 미치는가에 대하여 국내 103개 상장기업을 대상으로 실증분석을 하였다. 또한 경영성과에 대하여서는 균형성과표(Balanced Scorecard; BSC) 모형을 이용하였다. 연구결과, 학습 및 성장성과, 고객성과, 재무성과의 경우 공급사슬구조에 따른 경영성과간 차이가 있음이 검증되었으나, 내부프로세스성과의 경우 경영성과간 차이가 통계적으로 유의하지 않았다. 또한, Scheff의 다중비교 결과에 따라 유통네트워크 중심기업의 경우 다른 공급사슬구조보다 상대적으로 경영성과가 높은 것으로 나타났다.

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Effect of Acylation on the Structure of the Acyl Carrier Protein P

  • Hyun, Ja-shil;Park, Sung Jean
    • 한국자기공명학회논문지
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    • 제19권3호
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    • pp.149-155
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    • 2015
  • Acyl carrier protein is related with fatty acid biosynthesis in which specific enzymes are involved. Especially, acyl carrier protein (ACP) is the key component in the growing of fatty acid chain. ACP is the small, very acidic protein that covalently binds various intermediates of fatty acyl chain. Acylation of ACP is mediated by holo-acyl carrier protein synthase (ACPS), which transfers the 4'PP-moiety of CoA to the 36th residue Ser of apo ACP. Acyl carrier protein P (ACPP) is one of ACPs from Helicobacter plyori. The NMR structure of ACPP consists of four helices, which were reported previously. Here we show how acylation of ACPP can affect the overall structure of ACPP and figured out the contact surface of ACPP to acyl chain attached during expression of ACPP in E. coli. Based on the chemical shift perturbation data, the acylation of ACCP seems to affect the conformation of the long loop connecting helix I and helix II as well as the second short loop connecting helix II and helix III. The significant chemical shift change of Ile 54 upon acylation supports the contact of acyl chain and the second loop.

Structure of a single polymer chain confined in a dense array of nanoposts

  • Joo, Heesun;Kim, Jun soo
    • EDISON SW 활용 경진대회 논문집
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    • 제4회(2015년)
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    • pp.48-52
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    • 2015
  • Control of polymer conformations in heterogeneous confinement plays an important role in natural and engineering processes. We present a simulation study on the conformational structure and dynamics of a single, flexible polymer in a dense array of nanoposts with different sizes and separations, especially, when the volume of the interstitial space formed between four nanoposts is less than the size of the polymer chain. When a polymer is placed in the array of nanoposts, the size of polymer increases compared with that in the absence of nanoposts due to the confinement effect. It is shown that when a polymer is confined in the array of nanoposts the chain is elongated in the direction parallel to the nanoposts. As the interstitial volume between four nanoposts decreases either by increasing the nanopost diameter or by decreasing the separation between nanoposts, the chain elongation becomes more pronounced. On the contrary, the polymer size varies in a non-monotonic fashion, with an initial elongation followed by a chain contraction, as the interstitial volume is reduced both by increasing the nanopost diameter and decreasing the separation at the same time while keeping constant the width of the passageway between two nanoposts. The simulation analysis shows that the non-monotonic dependence of polymer size is determined by interplay between the chain alignment along the nanoposts in each interstitial volume and the chain spreading through passageways over several interstitial volume.

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효율적인 NDB 설계 및 유통 정보 NETWORK 활성화 방안 (The Activation Plan of Chain Information Network And Efficent NDB Design)

  • 남태희
    • 한국컴퓨터정보학회지
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    • 제1권2호
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    • pp.73-94
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    • 1995
  • 본 논문은 유통정보 네트워크 활성화 방안에 대하여 효율적인 NDB(Network Data Base)을 설계하였다. NDB(Network Data Base)의 구조는 논리 구조, 격납 구조, 물리 구조로 형성되어 데이터는 하나의 레코드로서 표현되고 데이터들 간의 관계는 링크로서 표현되었다. 또한 데이터베이스의 논리적 구조를 표현한 자료 구조도(Data Structure Diagram:DSD)가 계층 모델로 나타내었다. 각 노드는 레코드 타입을 나타내었고, 타입들을 연결하는 방향을 지닌 링크, 논리적인 격납 형태로 구성되어 데이터베이스를 설계하는데 물리 매체상 서로 연관성 있게 설계되어 자료의 검색과 억세스 효율에 큰 영향을 미쳤다. 또한 설계된 시스템에 네트워크를 형성하고, 네트워크 표준화를 위해 OSI 환경하에서 POS(Point Of Sale)시스템을 이용하여 효율적인 유통 정보 네트워크를 활성화시켰다.

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Acetohydroxyacid Synthase

  • Duggleby, Ronald G.;Pang, Siew Siew
    • BMB Reports
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    • 제33권1호
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    • pp.1-36
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    • 2000
  • Acetohydroxyacid synthase (EC 4.1.3.18) catalyses the first reaction in the pathway for synthesis of the branched-chain amino acids. The enzyme is inhibited by several commercial herbicides and has been subjected to detailed study over the last 20 to 30 years. Here we review the progress that has been made in understanding its structure, regulation, mechanism, and inhibition.

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The Structural Effects on The Pretilt Angle of Alignment Materials with Alkylcyclohexylbenzene as a Side Chain in Polyimides

  • Lee, Jong-Beom;Lee, Hyun-Kyung;Park, Jae-Chul;Kim, Yong-Bae
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2004년도 Asia Display / IMID 04
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    • pp.1188-1192
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    • 2004
  • Polyamic acid precursors were prepared by mixing various main chain dianhydrides, main chain diamines and side chain diamines. Copolyimide films with alkylcyclohexylbenzene as a side chain were prepared by thermal imidization of polyamic acid precursors. Pretilt angles on rubbed polyimides changed according to the side chain and main chain structures of the polyimide. Consequently, we found that LC pretilt angles of polyimide films with a liquid crystal structure as a side chain showed to be approximately 90$^{\circ}$ when a linear and rigid polyimide main chain and a side chain of suitable length were employed.

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Ag(001) 표면 위에 놓인 Fe 선의 자성과 전자구조 (First-principles Study on Magnetism and Electronic Structure of Fe Chain on Ag(001))

  • 김영구;이재일
    • 한국자기학회지
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    • 제15권4호
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    • pp.217-220
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    • 2005
  • 제일원리적 에너지 띠 계산 방법인 전 전자 총 퍼텐셜 선형보강평면파동(all-electron full-potential linearized augmented plane ave) 방법에 일반기울기근사(generalized gradient approximation)를 채용하여 Ag(001) 표면 위에 [110] 방향으로 놓인 Fe 선의 전자구조와 자성을 이론적으로 연구하였다. Fe 선의 원자당 자기모멘트는 $3.02\;{\mu}_B$로 Cu(001) 위에 놓인 Fe[110] 선의 값($2.99\;{\mu}_B$) 보다 약간 컸다. Fe 선의 자기모멘트가 상당히 증가한 것은 이웃한 결합수가 줄어들고 그 결과로 Fe-d 전자상태의 띠폭이 줄어들어 국소화 되고 스핀분리가 증가하였기 때문이다. Fe-d 전자상태의 띠 폭은 약 1.6eV였으며 스핀분리는 약 3.2 eV였다.

실리콘 웨이퍼 공급사슬관리 시스템 구축에 관한 연구: (주) LG 실트론 사례를 중심으로 (A Case Study of Supply Chain Management System of LG Siltron, Korea)

  • 이호창
    • 산업공학
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    • 제18권3호
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    • pp.234-246
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    • 2005
  • A silicon wafer is a highly customized product made to the individual order varying its electrical and physical characteristics. Therefore, it has distinctive supply chain structure that is different from highly standardized commodity product. For high-volume/high-standardization product, it is general that a main stream of information flow initiated by the production planning of the manufacturers is usually directed to push both ways in a supply chain: upstream to the suppliers and downstream to the customers. Contrastingly, for low-volume/high-customization product, the information flow triggered by the fluctuating customer demand usually propagates upward to the suppliers through the manufacturers. Furthermore, for R &D based hi-technology product like silicon wafer, the interactive information feedback mechanism between manufacturer and customer, which is essential to the new product development process, is to be embedded in the supply chain. This article is a case study of supply chain management system of LG Siltron, a major Korean silicon wafer manufacturer. The SCM system entails special information structure fitting well typical high-variety/high-customization product, and also gives application possibilities to the R&D based high-technology product made to the individual customer order.

공급망 구성원 간 역학관계가 R&D 및 시장 성과에 미치는 영향 (Effect of Power Dynamics in a Supply Chain on R&D and Market Performances)

  • 유승호
    • 한국경영과학회지
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    • 제41권1호
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    • pp.113-126
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    • 2016
  • This study investigates the effect of power dynamics on R&D and market performances. Various types of relationships in a supply chain are considered. An R&D company offering new technology for product quality and a manufacturer responsible for both production and sales are utilized as subjects. The company with bargaining power differs with respect to the supply chain situation in practice, and no fixed single relationship and supply chain structure exist. However, only a few studies have considered the various relationships among players in a supply chain and their effects on performance. Therefore, we propose three models with different supply chain structures and power dynamics among players. This study contributes to the academia and supply chain practice by revealing the different characteristics of supply chain models.