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입자크기에 따른 SnO2:Ni 가스센서의 감응 특성 (Effect of the Particle Size of SnO2:Ni on Gas Sensing Properties)

  • 이지영;유일
    • 한국재료학회지
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    • 제21권4호
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    • pp.207-211
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    • 2011
  • Ni 8 wt.%-doped tin oxide ($SnO_2$) thick films were fabricated into gas sensors by the method of screen printing onto alumina substrates. The particle size of $SnO_2$ was controlled by changing the ball-mill time between 0~120 h. The structural and morphological properties of these thick films were investigated using X-ray diffraction and scanning electron microscopy. The structural properties of $SnO_2$ powders showed a tetragonal phase with (110) dominant orientation. The particle size of the $SnO_2$:Ni powders after ball-mill of 120 h was about 0.05 ${\mu}m$. The gas sensitivity (S = Rg/Ra) to 5 ppm $CH_4$ gas and $CH_3CH_2CH_3$ gas was measured at room temperature by comparing the resistance in air (Ra) with that of the target gases (Rg). The sensitivity of the $SnO_2$ gas sensors was enhanced by increasing the ball-mill time. There was an association between the sensitivity of both the $CH_4$ gas and the $CH_3CH_2CH_3$ gas and the particle size of the $SnO_2$. $SnO_2$ gas sensors prepared by 72 h ball-mill showed a sensitivity of about 13 to 5 ppm $CH_4$ gas and $CH_3CH_2CH_3$ gas. The response time of the $SnO_2$:Ni gas sensors to the $CH_4$ gas was about 20 seconds.

음곡 육종용 약침이 난소적출 생쥐의 골다공증에 미치는 영향 (Effects of Herbal-Acupuncture with Cistanches Herba Extract at KI10 (Eumgok) on Osteoporosis in Ovariectomized Mice)

  • 정년식;이병렬;구성태;임윤경
    • Korean Journal of Acupuncture
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    • 제25권3호
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    • pp.97-115
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    • 2008
  • Objective & Methods : This study aimed to evaluate the effects of Cistanches Herba herbal-acupuncture (CH-HA) at KI10 (Umgok) on osteoporosis induced by ovariectomy in mice. The results were as follows; Results : CH-HA at KI10 significantly inhibited the overgrowth of tibia, the elevation of serum osteocalcin level, the reduction of tibial Ca and P level, the increase of tibial osteoclast like cells, the reduction of tibial TBV (trabecular bone volume), the overgrowth of tibial GPL (growth plate length) in ovariectomized mice. NP at KI10 significantly inhibited the reduction of BMD (bone mineral density) in ovariectomized mice, but CH-HA did not. Conclusion : Taken together, CH-HA at KI10 has a protective or therapeutic effect for osteoporosis in ovariectomized mice. Therefore, it is suggested that CH-HA may be an useful therapeutics in clinical filed after further researches.

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1930년대 조선성악연구회(朝鮮聲樂硏究會)의 창극적 상상력과 식민성 (Ch'anggŭk Imagination and Coloniality of Chosŏn Sŏngak Yŏn'guhoe in the 1930s)

  • 김향
    • 공연문화연구
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    • 제39호
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    • pp.357-392
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    • 2019
  • 이 논문은 1930년대 창극 형성 과정을 창극 유성기음반과 조선성악연구회(朝鮮聲樂硏究會)의 창극 레퍼토리들을 중심으로 재고찰한 것이다. 1930년대 창극 형성의 중심에 있었던 조선성악연구회의 구체적인 활동을 살피면서 그 의의와 한계를 논했다. 창극 유성기음반에서 구현되는 '입체창'과 '해설자' 역할은 조선성악연구회 회원들이 판소리와 변별되는 '극적 공간과 무대'를 인식하게 된 창극적 상상력의 구현으로 보았다. 그리고 창극 형성으로 파생된 서항석과 송석하의 '신창극' 개념의 차이와 의미를 논했다. 1930년대 무대 창극 공연은 '가극'이라는 지향점에 도달해야 한다는 논의의 반복이었는데, 당시 '가극'이라는 용어가 '창극'으로 대체되는 과정을 살폈으며 그 과정에서 창극 무대가 온전한 형태를 갖추게 된 것을 논했다. 조선성악연구회 회원들의 창극 만들기는 창극사적으로는 중요한 업적일 수 있으나 일제의 문화정책에 따른 '정제'와 '배제'로 인해 형식적 측면에서는 한계를 드러낼 수밖에 없었다. 판소리 음악성은 고양되었으나 시대정신과 다양성을 담을 수 없었기에 초보적인 창극적 상상력에 그칠 수밖에 없었다고 할 수 있다. 창극은 태생적으로 한계를 지닌 장르였지만 시대의 흐름 속에서 극복되고 있다고 할 수 있으며 이는 후속 논문에서 다루고자 한다.

Density Functional Studies of Ring-Opening Reactions of Li+-(ethylene carbonate) and Li+-(vinylene carbonate)

  • Han, Young-Kyu;Lee, Sang-Uck
    • Bulletin of the Korean Chemical Society
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    • 제26권1호
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    • pp.43-46
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    • 2005
  • Reaction energies were determined for reductive ring-opening reactions of Li$^+$-coordinated ethylene carbonate (EC) and vinylene carbonate (VC) by a density functional method. We have also explored the ring-opening of Li$^+$-EC and Li$^+$-VC by reaction with a nucleophile (CH$_3$O$^-$.) thermodynamically. Our thermodynamic calculations led us to conclude that the possible reaction products are CH$_3$OCH$_2$CH$_2$OCO$_2$Li (O$_2$-C$_3$ cleavage) for Li$^+$-EC +CH$_3$O$^-$., and CH$_3$OCHCHOCO$_2$Li (O$_2$-C$_3$ cleavage) and CH$_3$OCO$_2$CHCHOLi (C$_1$-O$_2$ cleavage) for Li$^+$-VC +CH$_3$O$^-$.. The opening of VC would occur at the C$_1$-O$_2$ side by a kinetic reason, although the opening at the O$_2$-C$_3$ side is more favorable thermodynamically.

An Energy Efficient Multi-hop Cluster-Head Election Strategy for Wireless Sensor Networks

  • Zhao, Liquan;Guo, Shuaichao
    • Journal of Information Processing Systems
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    • 제17권1호
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    • pp.63-74
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    • 2021
  • According to the double-phase cluster-head election method (DCE), the final cluster heads (CHs) sometimes are located at the edge of cluster. They have a long distance from the base station (BS). Sensor data is directly transmitted to BS by CHs. This makes some nodes consume much energy for transmitting data and die earlier. To address this problem, energy efficient multi-hop cluster-head election strategy (EEMCE) is proposed in this paper. To avoid taking these nodes far from BS as CH, this strategy first introduces the distance from the sensor nodes to the BS into the tentative CH election. Subsequently, in the same cluster, the energy of tentative CH is compared with those of other nodes, and then the node that has more energy than the tentative CH and being nearest the tentative CH are taken as the final CH. Lastly, if the CH is located at the periphery of the network, the multi-hop method will be employed to reduce the energy that is consumed by CHs. The simulation results suggest that the proposed method exhibits higher energy efficiency, longer stability period and better scalability than other protocols.

WRF-CMAQ 모델을 이용한 한반도 CH4 배출의 기여농도 추정 및 검증 (Verification and Estimation of the Contributed Concentration of CH4 Emissions Using the WRF-CMAQ Model in Korea)

  • 문윤섭;임윤규;홍성욱;장은미
    • 한국지구과학회지
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    • 제34권3호
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    • pp.209-223
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    • 2013
  • 이 연구의 목적은 한반도에서 $CH_4$ 농도의 수치모의 검증을 통하여 $CH_4$ 배출원의 기여 농도를 추정하는 것이고, 이 수치모의에 사용된 $CH_4$ 배출량을 상자모델로부터 추정된 $CH_4$ 배출량과 비교하는 것이다. 한반도에서 2010년 4월 1일부터 8월 22일까지 $CH_4$의 평균 농도를 추정하기 위해 WRF-CMAQ 모델이 사용되었다. 모델에서 $CH_4$ 배출량은 전지구 배출량인 EDGAR와 한국에서의 온실기체 배출량인 GHG-CAPSS로부터 인위적 배출 인벤토리와 전지구 자연적 인벤토리인 MEGAN이 적용되었다. 이들 $CH_4$ 배출량은 안면도 및 울릉도에서 측정된 $CH_4$ 농도와 모델링 농도 자료를 비교함으로써 검증되었다. 울릉도에서 국내 배출원으로부터 추정된 $CH_4$의 기여 농도는 약 20%로 나타났고, 이것은 한반도 내 농장(8%), 에너지 기여 및 산업공정(6%), 일반폐기물(5%), 생체 및 토지이용(1%) 등 $CH_4$ 배출원으로부터 기원하였다. 그리고 중국으로부터 수송된 $CH_4$의 기여 농도는 약 9%였고, 나머지 배경농도는 약 70%로 나타났다. 박스모델로 추정된 $CH_4$ 배출량은 WRF-CMAQ 모델에서 사용한 $CH_4$ 배출량과 유의미한 결과를 얻었다.

소화성 궤양 흰쥐에서 체내 질소이용율 증진을 위한 체내 질소원에 관한 연구 - 단백질과 단백질 가수분해물의 비율을 중심으로 - (A Study on the Nitrogen Sources for the Enhancement of the Nitrogen Bioavailability in Rats with Peptic Ulcer -The Ratio of Casein and Casein Hydrolysate-)

  • 김창임;이연숙
    • 한국식품영양과학회지
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    • 제27권1호
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    • pp.132-140
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    • 1998
  • This study aimed to verify the nutritional and curative effects of protein hydroysate and optimal ratio between protein and protein hydroysate as nitrogen source in rats with cysteamine-induced duodenal ulcer. Duodenal ulcer rat model was established by intraperitoneal injections of cysteamine. Sprague-Dawley, female rats weighing approximately 200g were intrapertionealy injected twice cysteamine(13mg/100g BW) at intervals of 3hours per day. This procedure was repeated 3 times at intervals of 3 days. Animals fed on 10% casein diet for injection periods. After last injection, 5 kinds of kiets (the ratio of casein and casein hydrolysate was 100 : 0(C100), 75 : 25(CH 25), 50 : 50(CH 50), 25 : 75(CH 75), 0 : 100(CH 100)) were given. The rate were sacrificed after feeding diet, 1, 3, 5 days. Ulcer index, hexosamine content of stomach and duodeum, gastric motility, trypsin activity, blood glutathione, plasma total protein, albumin, amino-N, urinalry urea nitrogen, creatinine, hydroxyproline and retention rate of nitrogen were analyzed for nutritional effects of diet treatments. There were no differences among diet groups in the view of the growth and diet treatments. There difference of ulcer curation by diet was appeared after 3 days. The ulcer indexes of C100 and CH 25 of 3, 5 days were significantly higher than those of CH 50, CH 75 and CH 100. This result was the same as hexosamine content of stomach, plasma protein, albumin concentration and nitrogen retention rate. The more casein hydrolysate diet had, the lower trypsin activity was. The more casein gydroysate diet had, the higher excretion of hydroxyproline was. These results show that protein hydrolysate can be applied in diet therapy for the patients with gastronitestinal ulcer. It suggests that it has curative effect of diet when nitogen sources include at least over than 50% of protein hydrolysate.

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Generation of Si-O-C Bond without Si-$CH_3$ Bond in Hybrid Type SiOC Film

  • Oh, Teresa
    • 반도체디스플레이기술학회지
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    • 제7권3호
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    • pp.1-4
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    • 2008
  • The chemical shift of SiOC film was observed according to the flow rate ratio. SiOC film had the broad main band of $880\sim1190cm^{-1}$ and the sharp Si-$CH_3$ bond at $1252cm^{-1}$, and the peak position of the main bond in the infrared spectra moved to high frequency according to the increasing of an BTMSM flow rate. So the increment of the alkyl group induced the C-H bond condensation in the film, and shows the blueshift in the infrared spectra. In the case of P5000 system of Applied Materials Corporation, the strong bond of Si-CH3 bond in precursor does not enough to dissociated and ionized, because low plasma energy due to the capactive coupled CVD. Therefore, there was the sharp peak of Si-$CH_3$ bond at $1252cm^{-1}$.

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ANALYSIS OF THE KOREAN CELESTIAL PLANISPHERE: CH'ON-SANG-YUL-CHA-BUN-YA-JI-DO

  • PARK CHANGBOM
    • 천문학회지
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    • 제29권spc1호
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    • pp.433-437
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    • 1996
  • We have analyzed the content of the Korean stone star chart. Ch'on-Sang-Yul-Cha-Bun-Ya-Ji-Do(here-after Ch'on-Sang-Do). In the star map we have found 1468 stars, 4 more than the Chinese star catalog Bo-Chun-Ga. The four extra stars form a constellation, Jong Dae Boo. The map projection law used in the star chart is found to be the polar equtorial and equidistance projection. The linear distance of an object on Ch'on-Sang-Do from the center is linearly proportional to the north polar angular distance. We have found from a statistical analysis that most stars with declination lower than 50 are at positions representing the epoch of around the first century. On the other hand, stars near the north pole with declination higher than 50 are at the epoch of about 1300, which is close to the time the chart was engraved. This implies that the original Ko-Gu-Rye Dynasty's star chart has been revised by astronomers of Cho-Sun Dynasty. We have also shown that stars on Ch'on-Sang-Do are engraved in such a way that their area is linearly proportional to the visual magnitude.

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Excitation Processes of the CH4 Aurorae of Jupiter and Saturn

  • Kim, Sang Joon
    • 천문학회보
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    • 제43권1호
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    • pp.72.1-72.1
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    • 2018
  • Recently, an analysis of 3-micron spectra of CH4 line emission from our Gemini/GNIRS observations of Jupiter's polar regions yielded an unexpected result: The homopause (~1 microbar pressure level) located directly above the long-lasting 8-micron CH4 north-polar hot spot (Great 8-micron Hot Spot: GHS) is cool compared with the temperatures of nearby auroral regions (Kim et al. 2017). Most of the 8-micron emission of the GHS originates from CH4 at the ~1 mbar level (i.e., deeper in the stratosphere, where cooling time is several years), much longer than at the altitude of the homopause. We propose a mechanism to explain the temperature difference: locally-fixed and transient, but energetic auroral particles, which can penetrate to the 1 mbar level and deposit energy there creating and maintaining the GHS. For Saturn, thus far we have not detected distinctive 8-micron nor 3-micron CH4 hot spots in the polar regions. We will present a possible implication for this difference between Jupiter and Saturn.

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