• 제목/요약/키워드: Ceramic-polymer composites

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세라믹/유리섬유강화복합재 적층판의 고속충돌에 의한 파괴거동 (Fracture Mechanism of Ceramic/Glass-fiber-reinforced-composites Laminate by High Velocity Impact)

  • 정우균;이우일;김희재;권정원;안성훈
    • 한국정밀공학회지
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    • 제23권5호
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    • pp.170-176
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    • 2006
  • Multi-layered laminate made of ceramic/composite have been developed to prevent penetration by high velocity impact. In this study, three-layered plates consisted of 1) cover layer (glass fiber reinforced polymer), 2) $Al_{2}O_{3}$, ceramic plate, and 3) backing plate (glass fiber reinforced polymer) were fabricated with various conditions and tested for their ballistic protection characteristic. The ceramic composite laminates, with thin backing plate, were completely penetrated by armor piercing projectile. The plate with inserted rubber between ceramic and backing plate showed excellent ballistic protection, though completely penetrated by the second shoot.

알루미나-지르코니아 복합체의 제조공정 및 미세구조에 미치는 폴리머 첨가의 영향 (Effect of Polymer Content on Synthesis Process and Microstructure of Alumina-Zirconia Composite)

  • 이상진;권명도;이충효;조경식
    • 한국분말재료학회지
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    • 제10권5호
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    • pp.310-317
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    • 2003
  • Two-component ceramic (alumina-zirconia) composites were fabricated by a soft-solution process in which polyethylene glycol (PEG) was used as a polymeric carrier. Metal salts and PEG were dissolved in ethyl alcohol without any precipitation in 1:1 volume ratio of alumina and zirconia. In the non-aqueous system, the flammable solvent made explosive, exothermic reaction during drying process. The reaction resulted in formation of volume expanded, porous precursor powders by a vigorous decomposition of organic components in the precursor sol. The PEG content affected the grain size of sintered composites as well as the morphology of precursor powders. The difference of microstructure in sintered composite was attribute to the solubility and homogeneity of metal cations in precursor sol. At the optimum amount of the PEG polymer, the metal ions were dispersed effectively in solution and a homogeneous polymeric network was formed. It made less agglomerated particles in the precursor sol and affected on uniform grain size in sintered composite.

3-3 결합으로 이루어진 PZT/고분자 압전복합체 (Piezoelectric PZT/Polymer Composite with 3-3 Connectivity)

  • 윤기현;염상덕
    • 한국세라믹학회지
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    • 제25권2호
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    • pp.125-130
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    • 1988
  • The characteristics of the PZT/PMM and PZT/Butadiene composites with 3 dimensional network structure have been investigated as a function of the PZT volume fraction. The dielectric constants of the PZT composites increased linearly as the PZT volume fraction increased. However, they are not significantly affected by the polymer compliance. The piezoelectric d33 coefficients of the PZT/Butadiene are largest than the PZT/PMM because of the high elastic compliance which promotes stress transfer. The values of the mechanical quality factor adn frequency factor of the PZT/PMM composite are slightly larger, while the planar coupling factor is smaller, than the PZT/Butadiene composite. These results are due to strong interaction and mechanical coupling between PZT and PMM.

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화학침착법과 고분자함침 열분해법의 복합공정으로 제조한 SiCf/SiC 복합체의 제조 공정에 따른 파괴거동 (Fracture Behaviors of SiCf/SiC Composites Prepared by Hybrid Processes of CVI and PIP)

  • 박지연;한장원;김대종;김원주;이세훈
    • 한국세라믹학회지
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    • 제51권5호
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    • pp.430-434
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    • 2014
  • $SiC_f$/SiC composites were prepared using the hybrid process of chemical vapor infiltration (CVI) and polymer impregnation and pyrolysis (PIP). Before the application of PIP, partially matrix-filled preform composites with different densities were fabricated by control of chemical vapor infiltration time and temperature. The changes of the final density of the $SiC_f$/SiC composites had a tendency similar to that of preform composites partially filled by CVI. Composites with lower density after the CVI process had a larger increment of density during the PIP process. Three types of microstructures were observed on the fractured surface of the composite: 1) well pulled-out fibers and lower density, 2) slightly pulled-out fibers and higher density, and 3) only bulk SiC. The different fractions and distributions of the microstructures could have an effect on the mechanical properties of the composites. In this study, $SiC_f$/SiC composites prepared using a hybrid process of CVI and PIP had density values in the range of $1.05{\sim}1.44g/cm^3$, tensile strength values in the range of 76.4 ~ 130.7 MPa, and fracture toughness values in the range of $11.2{\sim}13.5MPa{\cdot}m^{1/2}$.

LCP(Liquid Crystal Polymer)와 BaTiO3복합체의 제조 및 유전특성 (Preparation and Dielectric Properties of LCP and BaTiO3 Composites)

  • 윤기현;이승주;양병덕;김종희
    • 한국세라믹학회지
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    • 제40권12호
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    • pp.1183-1188
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    • 2003
  • LCP(Liquid Crystal Polymer)와 BT(BaTiO$_3$) 복합체를 LCP varnish와 BT 슬러리를 혼합하여 제조하고, BT 슬러리 내에서 BT 입자의 분산 특성과 LCP-BT 복합체의 조성 및 BT 분말 크기가 유전 특성에 미치는 영향에 대하여 연구하였다. 분말 크기가 다른 BT 분말에 대하여 분산제 GLYMO(3-glycidyloxypropyltrimethoxysilane) 첨가량에 따른 용매 ODBZ(o-dichlorobenzene) 내에서의 분산 특성을 측정한 결과, BT분말 크기가 증가할수록 비표면적의 감소로 인하여 소요되는 최적 분산제의 양이 감소하였다. 분산된 BT슬러리를 LCP와 혼합하고 테잎 케스팅법을 이용하여 LCP-BT복합체를 제조하였다. BT 입자의 크기가 100nm에서 500nm로 증가함에 따라 복합체의 유전 상수는 34.3에서 44.1로, 유전 손실은 0.05 에서 0.063으로 증가하였다.

Composite Foams for Sandwich Structures

  • Nutt, Steven R.;Shen, B.;Vaikhanski, Lev
    • 한국세라믹학회지
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    • 제40권7호
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    • pp.625-631
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    • 2003
  • Recent work at USC has focused on strategies to enhance the toughness and overall mechanical performance of polymer foams for use in lightweight sandwich structures. Both mechanical and chemical approaches have been employed with reasonable success. Fiber reinforcement, though difficult from a processing perspective, can lead to substantial enhancements in toughness and strength, while reducing friability. Chemical modifications are also challenging from a processing perspective, but can produce similar enhancements in performance. Efforts to enhance performance of phenolic foam and PVC foam through fiber reinforcement and chemical modification are described, along with the resulting enhancements in performance.

탄소/탄소 복합재를 위한 메조페이스 핏치의 안정화 (Stabilization of Mesophase Pitch for Carbon/Carbon Composites)

  • 임연수
    • 한국세라믹학회지
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    • 제34권8호
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    • pp.817-824
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    • 1997
  • Stabilization is a key stage in the production of advanced carbon/carbon composites (ACC) from mesophase pitch, to render the mesophase infusible and the prevention of puffing during the subsequent carbonization. It is generally known that stabilization process as well as properties of mesophase pitch has a great deal of influence on the properties of the resultant ACC. Hence, it is possible to infer the properties of ACC by examing the stabilized mesophase pitch. In this study, extractions by solvents or acidified solvents extraction were carried out from the A-240 petroleum pitch. The extracted pitches were made into mesophase by heat treatments. Oxidative stabilization by air and non-oxidative stabilization by a chemical free radical initiator were performed. When a soluble polymer is fully stabilized, it should become insoluble in solvents. This phenomenon was used to estimated the degree of stabilization. The non-oxygen stabilized mesophase pitch powder was compared with the air stabilized mesophase pitch powder. FTIR provided additional information on the functional groups.

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