• Title/Summary/Keyword: Ceramic-glass

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Implementation of the Vehicle Antenna for the AM/FM/TDMB/GPS Receiver (AM/FM/TDMB/GPS 수신용 전장 안테나 제작)

  • Kim, Joo-Man;Son, Tae-Ho
    • The Journal of The Korea Institute of Intelligent Transport Systems
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    • v.8 no.5
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    • pp.105-113
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    • 2009
  • In this paper, a vehicle antenna for AM, FM, TDMB, GPS systems was designed and implemented. AM antenna loaded into small space of shark shape was designed by ferrite turn style antenna. For the FM and TDMB antenna, folded monopole antenna which helical is folded was applied. GPS antenna for achieving characteristics both bandwidth and gain improvement was designed microstrip patch that has air substrate and fractal structure. Receiving signal strengths by the measurement were presented for the AM, FM and TDMB antenna. AM signal strength was -65.7dBm, this strength is almost as same conventional pole antenna as -63.4dBm. It can be replaced conventional pole or glass antenna by the studied antenna. Signal strengths for FM and TDMB were -55.66 and -43.50dBm at center frequency, they are 5~10dB higher than conventional antenna. Measurements of bandwidth and gain for the GPS antenna showed 135 MHz under VSWR 2 : 1 and 4.31dBi, gains over GPS band were 3~5dB higher than ceramic patch antenna.

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Preparation of Ultra-Low Thermal Expansion L$i_2$O-A$l_2$$O_3$-Si$O_2$ Glass-Ceramics by Sol-gel Technique (졸-겔 방법에 의한 $Li_2O-Al_2O_3-SiO_2$계 저열팽상성 결정화유리의 제조)

  • Yang, Jung-Sik;Kim, Jong-Beom;Yang, Jung-Sik
    • Korean Journal of Materials Research
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    • v.3 no.3
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    • pp.207-214
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    • 1993
  • Glass-ceramic monoliths with an ultra-low thermal expansion coefficient have been synthesized by the sol-gel technique using metal alkoxides as starting materials and dimethyl formamide as a drying control chemical additive. The ternary gels: $Li_2O\cdot Al_2O_3\cdot 2, 4 or $6SiO_2$ were obtained by hydrolysis and polycondensation reactions of metal alkoxides of silicon, aluminum and lithium. To produce cylindrical crack-free gel monoliths, excess water was used to the starting solutions and drying rates were controlled precisely to prevent cracking. In conversion process ,${\beta}$-eucryptite, $Li_2O\cdot Al_2O_3\cdot 3SiO_2$ and P-spodumene with ,${\beta}$-quartz solid solution phase were obtained by heating at the range of 750 ~$1000^{\circ}C$. Above $800^{\circ}C$, the ,${\beta}$-spodumene phase increased while ,${\beta}$-eucryptite phase decreased. The thermal expansion coefficient of the crystallized specimens were -15~ $+5{\times}{10^{-7}}/{\circ}C$ over the temperature range from room temperature to $600^{\circ}C$.

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The Study on Fabrication of LAS System Ceramics for Thermal Shock Resistance from Silicate Minerals (III) Sintering Characteristics of Eucryptite and Spodumene (실리케이트 광물을 이용한 내열충격성 LAS계 세라믹스의 제조에 관한 연구 (III) Eucryptite와 Spondumene 소결특성)

  • 박한수;조경식;문종수
    • Journal of the Korean Ceramic Society
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    • v.32 no.2
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    • pp.171-182
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    • 1995
  • Five eucryptite and ten spodumene compositional powders were syntehsized from three sillimanite group, two kaolin group, and five pyrophyllite group silicate minerals. Those powders were isotatically pressed and fired at 1200~135$0^{\circ}C$ for 2 hrs, and then the sintered bodies were characterized. Silicate minerals with molar ratio of Al2O3 to SiO2 correspond to those of eucryptite and spodumene are kaolin and pyrophyllite group silicate minerals, respectively. Sintering characteristics of eucryptite from kaolin group and spodumene from pyrophyllite group mineral were superior to those from other silicate minerals. Eucryptite sintered bodies with 95~97% relative densities and densified microstructures can be obtained using Hadong pink kaolin as starting materials by sintering over broad temperature zone(1250~135$0^{\circ}C$). The eucryptite sintered bodies which were fired at 130$0^{\circ}C$ for 2hrs, from Hadong pink kaolin had within 3.0wt% microstructural compositional variations compaired with stoichiometric compound, and had good negative thermal expansiion property with -3.55$\times$10-6/$^{\circ}C$ thermal expansion coefficient. Spodumene sintered bodies which were prepared from pyrophyllite group silicate minerals, had dense microstructures and high densities by densification through liquid phase sintering with enlarged temperature range. The specimens which were fired at 130$0^{\circ}C$ for 2 hrs from Gusipyrophillite, had dense microstructure with crystallines mainly, and low thermal expansion property with 0.62$\times$10-6/$^{\circ}C$ thermal expansion coefficient. The porous texture and residual glass phase in LAS system ceramics which were prepared from silicate minerals, tend to increase the thermal expansion properties of sintered bodies to positive direction.

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Characteristics of Nano-Size Au Fine Particles Doped TiO2 Thin Films by Sol-Gel Method (졸-겔법에 의한 나노크기 Au 미립자 분산 TiO2 박막의 특성)

  • Park, Min-Jung;Koo, Se-Na;Lee, Kyoung-Seok;Mun, Chong-Soo
    • Journal of the Korean Ceramic Society
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    • v.43 no.2 s.285
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    • pp.114-120
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    • 2006
  • Nano-size Au particle doped $TiO_2$ films were prepared with $Ti(OC_3H_7^i)_4$, polyvinylpyrrolidone(PVP), $HAuCl_4$ and $C_3H_7OH$ etc. by sol-gel method. $TiO_2$ gel films were obtained by the dip-coating method on the $SiO_2$ glass substrates, and then heat-treated at $700^{\circ}C$ for 10 min. The thickness of $TiO_2$ films were $0.7\~1.8\;{\mu}m$. It was found that the thickness of films prepared from PVP containing solution was about $2\~8$ times higher values than that of thin films without PVP. The size of Au particles doped in the films were about $350\~750\;nm$. Nano-size Au particle dispersed $TiO_2$ films showed high absorption peak at visible region 450nm, which made them good candidates for non-linear optical materials and photo-catalytic materials. The contact angle of $TiO_2$ film for water was $12.5^{\circ}$, and therefore it is clear that $TiO_2$ films have very high hydrophilic properties and the self-cleaning effects.

Effect of Pulse Frequency on the Properties of ZnO:Al Thin Films Prepared by Pulsed DC Magnetron Sputtering (펄스 DC 마그네트론 스퍼터링법에 의한 ZnO:Al 박막 증착시 펄스 주파수의 영향)

  • 고형덕;이충선;태원필;서수정;김용성
    • Journal of the Korean Ceramic Society
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    • v.41 no.6
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    • pp.476-480
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    • 2004
  • AZO (Al-doped ZnO) thin films were deposited on glass by pulsed magnetron sputtering method, and their structural, electrical and optical properties were investigated. XRD patterns showed that a highly c-axis preferred AZO film was grown in perpendicular to the substrate when pulse frequency of 30 ㎑ was applied to the target. Microstructure of thin films showed that the fibrous grain of tight dome shape was grown. The deposition rate decreased linearly with increase of pulse frequency, and the lowest resistivity was 8.67${\times}$10$\^$-4/ $\Omega$-cm for the film prepared at pulse frequency of 30 ㎑. The optical transmittance spectra of the films showed a very high transmittance of 85∼90%, within visible wavelength region and exhibited the absorption edge of about 350 nm. The characteristics of the low electrical resistivity and high optical transmittance of AXO films suggested a possibility for the application to transparent conducting oxides.

Abnormality of P2O5-Na2O-MgO Glasses by Raman and Infrared Spectroscopy (라만과 적외선 분광기를 이용한 P2O5-Na2O-MgO 유리의 이상성에 관한 연구)

  • Lee, Byung-Chul;Kwon, Young-Jun;Ryu, Bong-Ki
    • Journal of the Korean Ceramic Society
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    • v.39 no.3
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    • pp.265-271
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    • 2002
  • Density, water resistance, Raman and infrared spectroscopy were used to investigate the change of structural characteristics with the composition of phosphate galss samples made by melting method. The structural abnormality of the density and water resistance were rapidly increased and shown near the 60mol% of $P_2O_5$. This result could be explained by the structural changes owing to the strong shrinkage of glass network by the coordination of DBO(Double-Bonded Oxygen) around $Mg^{2+}$ cations. In addition, it seems that the DBOs coordinating $Mg^{2+}$ cations lose its characteristics of double bonding and resonate with other NBOs(Non-Bonding Oxygen).

Amorphous Chalcogenide Solids Doped with Rare-Earth Element : Fluorescence Lifetimes and the Glass Structural Changes (희토류 원소 첨가 비정질 찰코지나이드 : 형광 수명과 유리 구조 변화의 관계)

  • Choi Yong Gyu
    • Journal of the Korean Ceramic Society
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    • v.41 no.9
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    • pp.696-702
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    • 2004
  • Lifetime of excited electronic states inside the 4f configuration of rare-earth elements embedded in chalcogenide glasses is very sensitive to medium-range structural changes of the host glasses. We have measured lifetimes of the 1.6$\mu\textrm{m}$ emission originating from Pr$\^$3+/ : ($^3$F$_3$, $^3$F$_4$)\longrightarrow$^3$H$_4$ transition in amorphous chalcogenide samples consisting of Ge, Sb, and Se elements. The measured lifetimes fumed out to have their maximum at the mean coordination number of -2.67, which arises accordingly from structural changes of the host glasses from 2 dimensional layers to 3 dimensional networks. This new finding supports that the so-called topological structure model together with chemically ordered network model is adequate to explain relationship between the emission properties of rare-earth elements and the medium-range structures of amorphous chalcogenide hosts with a large covalent bond nature. Thus, it is validated to predict site distribution and lifetime of rare-earth elements doped in chalcogenide glasses simply based on their mean coordination number.

The Behaviour of Ru Based Thick Film Resistor as a Comonent of LCR Network (LCR Network을 구성하는 Ru계 후막저항계의 거동)

  • 박지애;이홍림;문지웅;김구대;이동아;손용배
    • Journal of the Korean Ceramic Society
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    • v.34 no.3
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    • pp.233-240
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    • 1997
  • The Ru-based thick film resistor(TFR) for sintering at 90$0^{\circ}C$ was synthesized to prepare the LCR net-work. These compositions of pyrochlore could be prepared by decreasing the amount of PbO and increasing alumina and silica contents of glass frit. In this study, the sheet resistances of the TFTs. which sint-ered at 90$0^{\circ}C$ after printing on alumina substrate, the sheet resistances of the TFRs on inductor and capa-citor substrate and the interphase between TFR and substrate were observed. And the changes of the sheet resistance were obtained with the contents of RuO2. In case of the TFR sintered at 90$0^{\circ}C$, the sheet resis-tances on alumina substrates were in the range of 103~106$\Omega$/$\square$, but the sheet resistances of TFR on in-ductor and capacitor substrate were not obtained.

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Ecological Studies on Togyo Reservoir in Chulwon, Korea. 7. The Colonization of Epilithic Algae on Artificial Substrata (Tiles) at Mesocosm

  • Lee, Kyung;Yoon, Sook-Kyung;Ki, Jang-Seu;Han, Myung-Soo
    • ALGAE
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    • v.19 no.2
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    • pp.107-114
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    • 2004
  • Patterns of epilithic algal colonization on artificial substrata (unglazed ceramic tiles) were investigated from 23rd April to 3rd July 1999 at weekly intervals over a 10 weeks period outside and inside the mesocosm in Togyo reservoir within the Civilian Passage Restriction Line near Demilitarized Zone (DMZ) in Korea. The highest standing crops of epilithic algae was 1,798$\cdot$10³ cells$\cdot$$cm^{-2}$ outside the mesocosm on 26th June and also inside the mesocosm those was 2,391$\cdot$10³ cells$\cdot$$cm^{-2}$ on 26th June, 9 weeks after the experiment began. The dominants outside the mesocosm were Achnanthes minutissima, Navicula bicephala, Oscillatoria angusta, Synedra delicastissima, S. tenuissima, S. ulna v. danica and Tabellaria flocculosa, and those inside the mesocosm were Achnanthes minitissima, Coenochloris polycocca, Fragilaria crotonenesis, Peridinium cinctum, Synedra delicatissima, Tabellaria flocculosa and Ulothrix subtilissima. Diatoms were most abundant and Achnanthes minutissima was the most important species colonizing on the tiles. Chlorophyll-a content was highest value of 5.4 mg$\cdot$$m^{-2}$ on 19th June after 8 weeks growth outside the mesocosm and was 24.4 mg$\cdot$$m^{-2}$ on 26th June, 9 weeks after the experiment began on tiles inside the mesocosm. It was also shown that unglazed ceramic tiles were a more suitable substratum for colonization than the glass slides. Consequently the substratum selection plays an important role in the colonization by the epilithic algal community.

Effect of Degraded Al-doped ZnO Thin Films on Performance Deterioration of CIGS Solar Cell (고온 및 고온고습 환경 내에서 ZnO:Al 투명전극의 열화가 CIGS 박막형 태양전지의 성능 저하에 미치는 영향)

  • Kim, Do-Wan;Lee, Dong-Won;Lee, Hee-Soo;Kim, Seung-Tae;Park, Chi-Hong;Kim, Yong-Nam
    • Journal of the Korean Ceramic Society
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    • v.48 no.4
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    • pp.328-333
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    • 2011
  • The influence of Al-doped ZnO (AZO) thin films degraded under high temperature and damp heat on the performance deterioration of Cu(In,Ga)$Se_2$ (CIGS) solar cells was investigated. CIGS solar cells with AZO/CdS/CIGS/Mo structure were prepared on glass substrate and exposed to high temperature ($85^{\circ}C$) and damp heat ($85^{\circ}C$/85% RH) for 1000 h. As-prepared CIGS solar cells had 64.91% in fill factor (FF) and 12.04% in conversion efficiency. After exposed to high temperature, CIGS solar cell had 59.14% in FF and 9.78% in efficiency, while after exposed to damp heat, it had 54.00% in FF and 8.78% in efficiency. AZO thin films in the deteriorated CIGS solar cells showed increases in resistivity up to 3.1 times and 4.4 times compared to their initial resistivity after 1000 h of high temperature and damp heat exposure, respectively. These results can be explained by the decreases in carrier concentration and mobility due to diffusion or adsorption of oxygen and moisture in AZO thin films. It can be inferred that decreases in FF and conversion efficiency were caused by an increase in series resistance, which resulted from an increase in resistivity of AZO thin films degraded under high temperature and damp heat.