• Title/Summary/Keyword: Ceramic-glass

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Mechanical properties of sheet molding compounds (SMC) with different size and contents of ground calcium carbonate (중질 탄산칼슘의 입자크기 및 첨가량 변화에 따라 제조된 시트몰딩 컴파운드(SMC)의 기계적 특징)

  • Lee, Yoonjoo;Koh, Kwang-Woon;Kwon, Woo-Teck;Kim, Younghee;Shin, Dong-Geun
    • Journal of Energy Engineering
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    • v.26 no.4
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    • pp.84-91
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    • 2017
  • Fiber reinforced plastic (FRP) is a typical plastic composite which is fabricated using fiber reinforcement with resin to represent the high strength properties. The mechanical properties of FRP should be determined by a fibrous material, and the studies about the role of fiber as a reinforcement has been an interested subject, whereas a study along the effect of filler is not so big. However, the filler effect must be considered on the properties of the composite, because the filler influence on the plastic or resin compound which reacts as a matrix material of the composite. Thus, in this work, we studied the filler effect with size and content using $3-6{\mu}m$ of ground calcium carbonate. The specimen was prepared by sheet molding compound (SMC) method, and the mechanical properties were compared with bending strength and tensile strength. As a result, it was confirmed that the size and contents of calcium carbonate affected the strength of composites, and the condition of $2.8{\mu}m$ which was the smallest size condition showed the highest strength.

High Thermal Conductivity h-BN/PVA Composite Films for High Power Electronic Packaging Substrate (고출력 전자 패키지 기판용 고열전도 h-BN/PVA 복합필름)

  • Lee, Seong Tae;Kim, Chi Heon;Kim, Hyo Tae
    • Journal of the Microelectronics and Packaging Society
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    • v.25 no.4
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    • pp.95-99
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    • 2018
  • High thermal conductivity films with electrically insulating properties have a great potential for the effective heat transfer as substrate and thermal interface materials in high density and high power electronic packages. There have been lots of studies to achieve high thermal conductivity composites using high thermal conductivity fillers such alumina, aluminum nitride, boron nitride, CNT and graphene, recently. Among them, hexagonal-boron nitride (h-BN) nano-sheet is a promising candidate for high thermal conductivity with electrically insulating filler material. This work presents an enhanced heat transfer properties of ceramic/polymer composite films using h-BN nano-sheets and PVA polymer resins. The h-BN nano-sheets were prepared by a mechanical exfoliation of h-BN flakes using organic media and subsequent ultrasonic treatment. High thermal conductivities over $2.8W/m{\cdot}K$ for transverse and $10W/m{\cdot}K$ for in-plane direction of the cast films were achieved for casted h-BN/PVA composite films. Further improvement of thermal conductivity up to $13.5W/m{\cdot}K$ at in-plane mode was achieved by applying uniaxial compression at the temperature above glass transition of PVA to enhance the alignment of the h-BN nano-sheets.

The Properties of Natural Hydroxyapatite Isolated from Tuna Bone (참치뼈로 부터 추출한 천연 Hydroxyapatite의 특성)

  • LEE Chang-kook;CHOI Jin-Sam;JEON You-Jin;BYUN Hee-Guk;KIM Se-Kwon
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.30 no.4
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    • pp.652-659
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    • 1997
  • For the effective utilization of the fish bone waste from seafood industry, the physical properties of the isolated hydroxyapatite from tuna bon have been investigated. On X-ray measurements, the chemical formula and phase of the bone calcined by various temperature were detected as $Ca_{10}\;(PO_4)_6\;(OH)_2$, and hydroxyapatite, respectively. It was shown that the chemical properties of apatite separated from tuna bone were controlled by Ca/P ratio. The mean agglomerate particle diameter was changed as a function of temperature. However, the particle shape has a geometrically non-regular types. These trends are consistent with SEM images. The composition of the glass-ceramic batch by calcined tuna bone was not perfectly agreed with the suggested data, but the partially substituted composition possibly shows the application of it as a bioceramic material.

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A STUDY ON THE MICROSTRUCTURE OF IPS EMPRESS CERAMICS ACCORDING TO THE HEAT TREATMENT AND SPRUE TYPE (주입선 및 열처리에 따른 IPS Empress 도재의 미세구조에 관한 연구)

  • Dong, Jin-Keun;Oh, Sang-Chun
    • The Journal of Korean Academy of Prosthodontics
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    • v.36 no.5
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    • pp.772-785
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    • 1998
  • This study was undertaken to clarify the microstructure of the different IPS Empress ingots by etching and to observe the change of leucite crystal structure according to subsequent heat treatment and the crystal distribution according to sprue types(${\phi}2.8mm$, single sprue; ${\phi}1.8mm$, double sprue) by scanning electron microscopy. IPS Empress T1, O1 ingots used for staining technique, and Dentin(A2) ingots used for layering technique were selected for this study. To observe the microstructures of these ingots before pressing, the specimens were prepared in splinters($3{\times}3{\times}3mm$) taken from the original ingots. And to estimate crystal distribution and microstructural change by sprue type and subsequent heat treatment. the specimens($3{\times}3{\times}3mm$) were heat-pressed through the two types of sprues with different diameters and numbers, and all specimens were fired according to the recommended firing schedule. The observed surface was ground with waterproof papers($#800{\sim}#1800$) on the grind polisher and was cleaned ultrasonically. All specimen were etched with 0.5% hydrofluoric acid. After etching, the surface was treated by ion sputter coating for SEM observation at an accelerating voltage of 20kV. In all specimens, the central area of ground surface was observed because there was less difference in microstructure between the peripheral area and the central area. The results were as follows ; 1. In the microstructure according to the ingot type, there was a wide difference between the staining (T1,O1) and layering(Dentin A2) ingots, but there was not a considerable difference between the T1 ingot and the O1 ingot for staining technique. 2. In all specimens, the crystal dispersion of IPS Empress ceramic using double sprue was significantly more scattered than that of IPS Empress ceramic using single sprue. The degree of scattering was strongest in the Dentin(A2) specimen and weakest in the O1 ingot. 3. In the microstructural change according to the subsequent heat treatment, all of ingots had some microcracks in the inside of the leucite crystal and the glass matrix after pressing. The inner splinters of the leucite crystal became smaller, and more microcracks occurred in the glass matrix due to increasing heat treatment times. 4. The size of leucite crystals varied from $1{\mu}m\;to\;5{\mu}m$. The mean size of mature crystals was about $5{\mu}m$. The form of the crystal was similar to a circle when it was smaller and similar to an ellipse when it was larger.

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A Study on STR Analysis According to the Method of Developing Latent Fngerprints Deposited on Non-Porous Surfaces in the Marine Environment (해양환경 내 비다공성 표면에 유류된 잠재지문 현출방법에 따른 STR 분석 연구)

  • Kim, Jin-Sun;Kim, Sea-In;Yoon, Hyun-Kyoung;Choo, Min-kyu
    • The Journal of the Korea Contents Association
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    • v.22 no.10
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    • pp.733-741
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    • 2022
  • Among the various evidence found in maritime crimes, fingerprints and DNA are very important in that they can identify a suspect. In this study, 5 types of non-porous surfaces (plastic, stainless, glass, ceramic, FRP), which are often found as evidence in the actual marine environment, were selected, and latent and blood fingerprints were passed down and immersed at the Donghae Maritime Police Station's exclusive pier for about 7 days. After that, DNA extraction, quantification, and STR profile were analyzed after fingerprint developing CA fumming method and 4 powder methods (Swedish black powder, Concentrated black powder, Supranano red powder, Dazzle orange powder). Among the fingerprint developing methods, when Supranano red powder was applied, a relatively high amount of DNA was found. As a result of STR profile analysis, an average of 16.8 to 9 loci were secured, and all 20 were confirmed in glass and ceramic materials. As a result of the study, it was possible to secure the STR profile by extracting and quantifying DNA after applying the fingerprint developing method to virtual evidence immersed for about 7 days, and further research is needed to secure the STR profile by analyzing DNA after applying various fingerprint developing methods such as VMD and SPR.

Active Shark Antenna for the Vehicle AM/FM/TDMB/GPS Receiver (자동차용 AM/FM/TDMB/GPS 통합 능동형 샤크 안테나)

  • Kim, Joo-Man;Son, Tae-Ho
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.21 no.6
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    • pp.698-705
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    • 2010
  • A vehicle antenna for AM, FM, TDMB, GPS systems was designed and implemented. Omnidirectional AM antenna was designed by ferrite turn style antenna. For the FM and TDMB antenna, folded monopole antenna which helical is folded was applied. GPS antenna for the bandwidth achievement was designed by trapezoidal microstrip patch that has air substrate. Receiving signal strengths by the measurement were presented for the AM, FM and TDMB antenna. AM signal strength was -65.7 dBm, this strength is almost as same conventional pole antenna as -63.4 dBm. It can be replaced conventional pole or glass antenna by the studied antenna. Signal strengths for FM and TDMB were -55.66 and -43.50 dBm at center frequency, they are 5~10 dB higher than conventional antenna. Measurements of bandwidth and gain for the GPS antenna showed 135 MHz under VSWR 2 : 1 and 4.31 dBi, gains over GPS band were 3~5 dB higher than ceramic patch antenna.

Experimental Investigations into the Precision Cutting of High-pressured Jet for Thin Multi-layered Material (다층박판재료의 초고압 젯 정밀가공에 대한 실험적 연구)

  • Park, Kang-Su;Bahk, Yeon-Kyeung;Lee, Jung-Han;Lee, Chae-Moon;Go, Jeung-Sang;Shin, Bo-Sung
    • Journal of the Korean Society for Precision Engineering
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    • v.26 no.7
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    • pp.44-50
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    • 2009
  • High-pressured jetting is now widely used in the advanced cutting processes of polymers, metals, glass, ceramics and composite materials because of some advantages such as heatless and non-contacting cutting. Similarly to the focused laser beam machining, it is well known as a type of high-density energy processes. High-pressured jetting is going to be developed not only to minimize the cutting line width but also to achieve the short cutting time as soon as possible. However, the interaction behavior between a work piece and high-velocity abrasive particles during the high-pressured jet cutting makes the impact mechanism even more complicated. Conventional high-pressured jetting is still difficult to apply to precision cutting of micro-scaled thin work piece such as thin metal sheets, thin ceramic substrates, thin glass plates and TMM (Thin multi-layered materials). In this paper, we proposed the advanced high-pressured jetting technology by introducing a new abrasives supplying method and investigated the optimal process conditions of the cutting pressure, the cutting velocity and SOD (Standoff distance).

Eu-doped LGF Luminescent Down Converter Possible for TiO2 Dye Sensitized Solar Cells

  • Kim, Hyun-Ju;Song, Jae-Sung;Lee, Dong-Yun;Lee, Won-Jae
    • Transactions on Electrical and Electronic Materials
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    • v.5 no.3
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    • pp.89-92
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    • 2004
  • For improving solar efficiencies, down conversion of high-energy photons to visible lights is discussed. The losses due to thermalization of charge carriers generated by the absorption of high-energy photons, can largely be reduced in a solar cell if more than one electron-hole pair can be generated per incident photon. The solar cell was constructed of dye-sensitized anatase-based TiO$_2$, approximately 30nm particle size, 6$\mu\textrm{m}$thickness, and 6${\times}$6$\textrm{mm}^2$ active area, Pt counter electrode and I$_3$$\^$-/I$_2$$\^$-/ electrolyte. After correction for losses due to light reflection and absorption by the conducting glass, the conversion of photons to electric current is practically quantitative in the plateau region of the curves. The incident photon to current conversion efficiency(IPCE) of N3 used as a dye in this work is about 80% at around 590nm and 610nm which is the emission spectrum of Eu doped LGF. The Eu doped LGF powder was prepared by conventional ceramic process, and used as a down converter for DSC after spin coated on the slide glass and fired.

Piezoelectric property variation with respect to the frit addition for lower temperature sintering in PNW-PMN-PZT ceramic system (PNW-PMN-PZT 압전 세라믹의 저온소결을 위한 프리트 첨가 압전 특성평가)

  • Ryu, Sung-Lim;Kwon, Soon-Yong;Woo, Duck-Hyun;An, Sang-Gi;Jeong, Ji-Hyun;Um, Ju-Chul
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.191-191
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    • 2008
  • 강유전성 세라믹스 재료로써는 PZT계열의 세라믹재료가 널리 쓰이고 있다. 이는 우수한 유전 및 압전특성을 가지고 있으나, PbO을 다량 함유하고 있어 $1000^{\circ}C$이상에서 PbO가 급격하게 휘발되는 성질 때문에 조성의 변동이 생겨 재현성이 어려우며 이를 방지하기 위하여 PbO를 과잉 첨가시키기 때문에 PbO휘발로 인한 강한 독성이 인체에 유해하고, 비환경 친화적인 물질로 최근에는 환경문제가 대두됨에 따라 대체 또는 보완 할 수 있는 방안에 검토되고 있다. 본 연구는 그 해결책의 한 방안으로 압전특성이 우수한 $(Pb_{0.94}Sr_{0.06})[(Ni_{1/2}W_{1/2})_{0.02}(Mn_{1/3}Nb_{2/3})_{0.07}(Zr_{0.51}Ti_{0.49})_{0.91}]O_3$계 조성을 설계하고 Glass frit(0~1.1 wt%)를 소량 첨가하여 액상 소결 특성을 부여하고 $1000^{\circ}C$ 이하의 저온에서 소결하여 유전 및 압전 특성을 평가하였다. 실험방법은 일반적인 세라믹스 제조공정으로 24시간 ball milling하고 $850^{\circ}C$에서 2시간 하소 후 Glass frit를 소결조제로 소랑 첨가하여 $1000^{\circ}C$ 이하 온도에서 소결을 진행하여 각 소결온도에 따른 유전 및 압전 특성을 평가하였다. 최종 소결된 시편의 밀도와 수축율을 분석하여 최적의 소결온도를 확립하였으며 XRD분석을 통해 perovskite구조를 확인하고 미세구조확인을 위해 SEM으로 관찰하였다. 압전 특성을 평가하였다.

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The Analysis of Acoustic Waves generated by a TA(ThermoAcoustic) Laser Pair (열음향(Thermoacoustic) 레이저의 음향파 특성 분석)

  • Oh, Seung-Jin;Chen, Kuan;Lee, Yoon-Joon;Shin, Sang-Woong;Lim, Sang-Hoon;Chun, Won-Gee
    • Journal of the Korean Solar Energy Society
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    • v.31 no.6
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    • pp.1-7
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    • 2011
  • Sound waves and acoustic energy generated by two identical TA (ThermoAcoustic) lasers were analyzed and studied. One end of the ceramic stack was heated by a thin NiCr wire wound around that end. The other end of the stack was cooled by natural convection of atmospheric air. The wavelength of the sound waves generated by a single TA laser was four times the tube length and the amplitude of the waves increased with the heating rate. SPL (SoundPressure Level) meters and microphones were employed to measure and study the sound waves at different distances from the glass tube opening and at the focusing point of the TA laser pair for different laser position arrangements. The sound waves of the two TA lasers at the focusing point were found to be almost 180 degrees out of phase when the openings of the two lasers were very close to each other and the angle between the laser axes was small. When the two TA lasers were placed far apart, the sound wave amplitudes and the phase difference between the two laser outputs varied periodically with time. The frequencies of the sound waves changed when the openings of the two TA lasers were in close vicinity and the angle between the laser axes exceeded a certain value. In this case, the glass tube opening was no longer a pressure anti-node and the wavelength of the fundamental mode was not equal to four times the tube length.