• Title/Summary/Keyword: Ceramic recycling

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Study on the Recovery of Tin Oxide and Metallurgical Tin from the Waste Steel Ball for Barrel Plating (바렐도금용 폐Steel Ball로부터 산화주석 및 금속주석 회수에 관한 연구)

  • Kim, Dae Weon;Jang, Seong Tae
    • Journal of the Korean Ceramic Society
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    • v.49 no.6
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    • pp.505-510
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    • 2012
  • A study of the recovery of tin and nickel from steel ball scraps for barrel plating was carried out through a physical treatment, a leaching treatment, hydrogen reduction and an electrolysis experiment. The recovery of the iron component was over 95% by the physical treatment. We obtained tin oxide in the form of metastannic acid ($SnO_2{\cdot}xH_2O$) with impurities of less than 5% from the leaching treatment. We also recovered the high-purity metallurgical tin at a rate that exceeded 99.9% by the electrolysis of crude tin obtained from the hydrogen reduction of metastannic acid.

Overview and Future Concerns for Red Mud Recycling Technology and Industry (알루미나 제조 공정 산출물 레드머드의 재활용 현황과 기술개발 동향 분석)

  • Hong, Hyun-Seon;Kim, Ye-lin;Cho, Hyun-Jung;Kim, Dae-Weon;Kim, Dae-woong;Kim, Hyeong-Jun;Kim, Yong;Kim, Sung-pyo
    • Resources Recycling
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    • v.26 no.5
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    • pp.12-21
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    • 2017
  • Red mud generated in the alumina manufacturing process contains various valuable resources, but it is not comprehensively recycled yet causing severe environmental problems. In Korea, red mud is producing about 200,000 tons annually and most of them are landfilled or disposed. Red mud's recycling technology is also being developed in many countries, but red mud's recycling technologies are still lacking compared to the production rate. In this study, we analyzed the characteristics and the amount of red mud, and the current status and technology development trend. Red mud has shown that recycling studies are being carried out in fields such as construction, recycling, metal recovery, adsorbent, and pollution stabilization. In particular, technologies for recovering rare earths have been developed as worldwide because of their high economic value. The data analyzed in this study will be used as basic data for the further development of technologies in the future.

A Study on the Recycling of Red Mud as the Raw Materials for the Manufacture of Clay Brick (점토벽돌 제조용 원료로서 레드머드 재활용에 관한 연구)

  • Kang, Hye-Ju;Lee, Yeong-Hun;Lee, Hee-Ra;Kang, Suk-Pyo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2019.05a
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    • pp.21-22
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    • 2019
  • This study is designed to apply natural clay replaceable redmud as ceramic material by mixing redmud with the materials used in existing brickmaking in laboratory environment. Therefore, through this study, the redmud is recycled as a raw material for clay bricks and presented as a basic material for the use of redmud in clay bricks.

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The adsorption efficiency of ceramic filter media prepared with the steel-making slag for the removal of VOCs (휘발성 유기화합물 제거를 위한 제강슬래그로 제조된 세라믹 여재의 흡착효율)

  • Sin, Jun-Ho;Kim, Tae-Heui;Park, Kyung-Bong
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.20 no.3
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    • pp.153-157
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    • 2010
  • We studied the adsorption efficiency of steelmaking slag in removing volatile organic compounds (VOCs) for increasing the recycling rate of steel-making slag. Ceramic filter was prepared by mixing the steel-making slag and the diatomite which is used as adsorbents due to the advantage of the high specific surface area and regular mesopores. The adsorption efficiency for VOCs removal was about 80%, 96% and 85% in acetaldehyde, formaldehyde and ammonia, respectively. The adsorption efficiency over 80% for all The gases showed the practical possibility as the adsorption filter.

Decomposition Mechanism of Waste Hard Metals using by ZDP (Zinc Decomposition Process) (ZDP(Zinc Decomposition Process)를 이용한 폐 초경합금의 분해기구)

  • Pee, Jae-Hwan;Kim, Yoo-Jin;Sung, Nam-Eui;Hwang, Kwang-Taek;Cho, Woo-Seok;Kim, Kyeong-Ja
    • Journal of the Korean Ceramic Society
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    • v.48 no.2
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    • pp.173-177
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    • 2011
  • Decomposition promoting factors and decomposition mechanism in the zinc decomposition process of waste hard metals which are composed mostly of tungsten carbide and cobalt were evaluated. Zinc volatility amount was suppressed and zinc valatilization pressure was produced in the reaction graphite crucible inside an electric furnace for ZDP. Reaction was done for 2 h at $650^{\circ}C$, which 100 % decomposed the waste hard metals that were over 30 mm thick. As for the separation-decomposition of waste hard metals, zinc melted alloy formed a liquid composed of a mixture of ${\gamma}-{\beta}1$ phase from the cobalt binder layer (reaction interface). The volume of reacted zone was expanded and the waste hard metal layer was decomposed-separated horizontally from the hard metal. Zinc used in the ZDP process was almost completely removed-collected by decantation and volatilization-collection process at $1000^{\circ}C$.

Waste to shield: Tailoring cordierite/mullite/zircon composites for radiation protection through controlled sintering and Y2O3 addition

  • Celal Avcioglu;Recep Artir
    • Nuclear Engineering and Technology
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    • v.56 no.7
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    • pp.2767-2774
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    • 2024
  • In this study, investment casting shell waste successfully utilized to produce cordierite/mullite/zircon composites. Green pellets, consisting of investment casting shell waste, alumina, and magnesia, were prepared and sintered at temperatures between 1250 and 1350 ℃. The influence of the sintering temperature on the crystalline phase composition, densification behavior, flexural strength, microstructure, and radiation shielding properties of the cordierite/mullite/zircon composites is investigated. Phase analysis showed that characteristic cordierite peaks appear at 1250 ℃, but the complete conversation of silica from investment casting shell waste into cordierite requires a sintering temperature of at least 1300 ℃. Notably, the cordierite/mullite/zircon composite sintered at 1350 ℃ exhibited a sixfold increase in flexural strength compared to the ceramic composite directly fabricated from investment casting shell waste at the same sintering temperature. Furthermore, the effect of Y2O3 addition on composites' radiation shielding properties is investigated. The results show that the Y2O3 addition improves densification behavior, enhancing the shielding capabilities of the composites against fast neutron and gamma radiation. Our findings suggest that the developed ceramic composites show significant potential for gamma-ray and neutron shielding applications.

A Review on Ceramic Based Membranes for Textile Wastewater Treatment (염색폐수의 처리를 위한 세라믹 분리막에 대한 고찰)

  • Kwak, Yeonsoo;Rajkumar, Patel
    • Membrane Journal
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    • v.32 no.2
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    • pp.100-108
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    • 2022
  • Among various industries, the textile industry uses the largest amount of water for coloring textiles which leads to a large amount of wastewater containing various kinds of dye. There are various methods for the removal of dye such as flocculation, ozone treatment, adsorption, etc. But these processes are not much successful due to the issue of recycling which enhances the cost. Alternatively, the membrane separation process for the treatment of dye in wastewater is already documented as the best available technique. Polymeric membrane and ceramic membrane are two separate groups of separation membranes. Advantages of ceramic membranes include the ease of cleaning, long lifetime, good chemical and thermal resistance, and mechanical stability. Ceramic membranes can be prepared from various sources and natural materials like clay, zeolite, and fly ash are very cheap and easily available. In this review separation of wastewater is classified into mainly three groups: ultrafiltration (UF), microfiltration (MF), and nanofiltration (NF) process.

Effect of $N_2$-back-flushing in Multi Channels Ceramic Microfiltration System for Paper Wastewater Treatment (제지폐수 처리를 위한 다채널 세라믹 정밀여과 시스템에서 질소 역세척 효과)

  • Park Jin-Yong;Choi Sung-Jin;Park Bo-Reum
    • Membrane Journal
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    • v.16 no.1
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    • pp.31-38
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    • 2006
  • The ceramic microfiltration system with periodic $N_2$-back-flushing was operated for treating paper wastewater discharged from a company making toilet papers by recycling milk or juice cartons. Two kinds of alumina membranes with 7 channels used here for recycling paper wastewater. The optimal filtration time interval for HC04 membrane with $0.4{\mu}m$ pore size was lower value of 4 min than 16 min for HC10 with $1.0{\mu}m$ pore size at fixed back-flushing time 40 sec, trans-membrane pressure $1.0kg_f/cm^2$ and back-flushing pressure $5.0kg_f/cm^2$. From the results of TMP effect at fixed filtration time interval and back-flushing time, the lower TMP was better on membrane fouling because high TMP could make easily membrane cake and fouling inside membrane structure. However, we could acquire the highest volume of total permeate at the highest TMP for the reason that TMP was driving force in our filtration system to treat paper wastewater. Then the permeate water of low turbidity was acquired in our microfiltration system using multi channels ceramic membranes, and the treated water could be reused in paper process.

Analysis for Water Vapour Adsorption and Desorption Performance of Waste Paper-Mulberry according to Particle Size Control (폐닥나무의 입도제어에 따른 흡·방습 특성 분석)

  • Jo, Ki-Sic;Kim, Tae-Yeon;Seo, Sung-Kwan;Lee, Oh-Kyu;Chu, Yong-Sik
    • Resources Recycling
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    • v.29 no.2
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    • pp.8-17
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    • 2020
  • In this study, adsorption and desorption characteristics of pulverized waste paper-mulberry pellet and bast fiber were measured to confirm the applicability to humidity control products. Paper-mulberry powder was classified by 710-355㎛, 355-100㎛, 100-45㎛ and less than 45㎛ and used in experiment. Specific surface area increased from 1.02㎡/g to 1.35㎡/g as the particle size decreased from 710㎛ to under 45㎛. Adsorption and desorption performance decreased in the order of 355-100㎛, 710-355㎛, 100-45㎛, less than 45㎛ and bast fiber, adsorption content on each particle sizes were 141.1g/㎡, 147.1g/㎡, 135.7g/㎡, 129.0g/㎡ and desorption content were 117.2g/㎡, 123.6g/㎡, 110.2g/㎡, 93.3g/㎡. As a result, adsorption and desorption performance of paper-mulberry powder were superior to those of the bast fiber and these phenomenon can be considered that it caused by pore distribution in pellet and damage of fiber.

Preparation of Porous Ceramic Bead using Mine Tailings and Its Applications to Catalytic Converter (광미(鑛尾)를 활용(活用)한 다공성 세라믹 비드 제조(製造) 및 촉매(觸媒) 변환기(變換機)로의 응용(應用))

  • Seo, Junhyung;Kim, Seongmin;Han, Yosep;Kim, Yodeuk;Lee, Junhan;Park, Jaikoo
    • Resources Recycling
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    • v.22 no.4
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    • pp.38-45
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    • 2013
  • The porous ceramic beads using mine tailing were prepared and applied to catalytic converter for NOx/SOx removal. Catalytic support was used synthesized mesoporous silica (SBA-15) which coated on surface. Internal structure for porous ceramic beads was composed of three-dimensional network structure and porosity was about 80%. In addition, the specific surface area for mesoporous silica(SBA-15) coated on converter was significantly increased 55 $m^2/g$ compared with 0.8 $m^2/g$ before coating. NOx/SOx removal experiment was performed using $V_2O_5$ and $V_2O_5$/CuO converter. NOx conversion ratio for $V_2O_5$/CuO converter was approximately increased 10% compared to $V_2O_5$ converter. In addition, catalytic converter of $V_2O_5$/CuO was shown to remove 95% of NOx and 90% of SOx at reaction temperature of $350^{\circ}C$, space velocity of 10000 $h^{-1}$ and $O_2$ concentrations of 5%, respectively.