• Membrane and Water Treatment
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• v.7 no.3
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• pp.175-191
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• 2016

In this work, oil-in-water emulsions (O/W) were prepared successfully by membrane emulsification with $0.5{\mu}m$ pore size membrane. Sunflower oil was emulsified in aqueous Tween80 solution with a simple crossflow apparatus equipped with ceramic tube membrane. In order to increase the shear-stress near the membrane wall, a helical-shaped reducer was installed within the lumen side of the tube membrane. This method allows the reduction of continuous phase flow and the increase of dispersed phase flux, for cost effective production. Results were compared with the conventional cross-flow membrane emulsification method. Monodisperse O/W emulsions were obtained using tubular membrane with droplet size in the range $3.3-4.6{\mu}m$ corresponded to the membrane pore diameter of $0.5{\mu}m$. The final aim of this study is to obtain O/W emulsions by simple membrane emulsification method without reducer and compare the results obtained by membrane equipped with helix shaped reducer. To indicate the results statistical methods, $3^p$ type full factorial experimental designs were evaluated, using software called STATISTICA. For prediction of the flux, droplet size and PDI a mathematical model was set up which can describe well the dependent variables in the studied range, namely the run of the flux and the mean droplet diameter and the effects of operating parameters. The results suggested that polynomial model is adequate for representation of selected responses.

• Membrane Journal
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• v.26 no.3
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• pp.205-211
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• 2016

Performance of pyrophyllite-based ceramic membranes newly developed were investigated. Membrane fouling caused by microbial suspensions taken from a full-scaled MBR system at domestic wastewater treatment plant was observed at different airflow rate and distance between each membrane. For the pyrophyllite support, pore size was about $1.0{\mu}m$, but surface coating with $Al_2O_3$ solution decreased the pore size with the reduction of the pure water permeability. With the MLSS taken from the full-scaled MBR system (6 g/L), the fouling rate was decreased by increasing airflow rate under $20L/m^2{\cdot}hr$ of setpoint flux. However, the effectiveness of the airflow rate on the fouling control depends strongly upon the gap between each membrane. At fixed airflow rate, the fouling rate was decreased by increasing the gap between each pyrophyllite membrane. Nevertheless, further increasing the membrane distance from 3.5 to 5.4 cm resulted in higher fouling rate. Similar result was observed with the $Al_2O_3$ coated-pyrophyllite membrane. Nevertheless, the fouling rate was lower with the coated membrane than that observed with the uncoated pyrophyllite support. Regardless of surface coating, the suspended solids were removed almost completely and the surface coating on the pyrophyllite support improved organic rejection with PEG solution (MW : 8000 kDa) tested.

• Journal of the Korean Ceramic Society
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• v.42 no.12 s.283
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• pp.865-871
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• 2005

Submicron thick solid electrolyte membrane is essential to the implementation of low temperature solid oxide fuel cell, and, therefore, development of new electrode structures is necessary for the submicron thick solid electrolyte deposition while providing functions as current collector and fuel transport channel. In this research, a nickel membrane with multi-stage nano hole array has been produced via modified two step replication process. The obtained membrane has practical size of 12mm diameter and $50{\mu}m$ thickness. The multi-stage nature provides 20nm pores on one side and 200nm on the other side. The 20nm side provides catalyst layer and $30\~40\%$ planar porosity was measured. The successful deposition of submicron thick yttria stabilized zirconia membrane on the substrate shows the possibility of achieving a low temperature solid oxide fuel cell.

• Journal of Korean Society of Environmental Engineers
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• v.35 no.2
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• pp.144-150
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• 2013

Hybrid ceramic membrane (HCM) processes that combined ozonation with a ceramic membrane (CM) or a reactive ceramic membrane (RM), an iron oxide nanoparticles (IONs) incorporated-CM were investigated for membrane fouling control. Alumina disc type microfiltration and ultrafiltration membranes doped with IONs by sintering method were tested under varying mass fraction of IONs. Scanning electron microscope (SEM) images showed that IONs were well-doped on the CM surface and doped IONs were approximately 50 nm in size. Change in the pure water permeability of RM was negligible compared to that of CM. These results indicate that IONs incorporation onto CM had little effect on CM performance in terms of the flux. Natural organic matter (NOM) fouling and fouling recovery patterns during HCM processes confirmed that the RM-ozonation process enhanced the destruction of NOM and reduced the extent of fouling more than the CM-ozonation process by hydroxyl radical formation in the presence of IONs on RM. In addition, analyses of NOM in the feed water and the permeate showed that the efficiency of membrane fouling control results from the NOM degradation during HCM processes; leading to removal and transformation of relatively high contents of aromatic, high molecular weight and hydrophobic NOM fractions.

• Membrane Journal
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• v.33 no.6
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• pp.439-446
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• 2023

Ceramic membranes are generally used for various industrial processes operating under extreme conditions because of its high thermal and chemical stability. However, due to the trade-off phenomenon of permeability and mechanical strength, preparation of high permeability-high strength membrane is necessary. In this study, the change in characteristics and performances of ceramic membranes was analyzed depending on the type of polymer binder and its mixing ratio. Because the solubility between solvent and polymer binder was higher in PSf (polysulfone) than in PES (polyethersulfone), the viscosity and discharge pressure of the PSf-based dope solution were higher than those of PES-based dope solution. When PSf was used as a polymer binder, ceramic membrane showed high mechanical strength and low water permeability due to the dense structure. On the other hand, in case of PES, the mechanical strength was slightly reduced and the water permeability was increased. It was confirmed that the optimum mixing ratio of the PSf and PES with high water permeability and mechanical strength was 9:1.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.26 no.10
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• pp.741-744
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• 2013

In this study, we fabricated anodic aluminum oxide (AAO) membrane by two step anodizing process for pH detection. The structural properties were observed by X-ray diffraction (XRD) and field emission scanning electron microscope (FE-SEM). Electrochemical measurements of the pH sensor have been performed in capacitance-voltage (C-V) and drift rates. The characterization of AAO membrane exhibited high sensitivity (99.1 mV/pH) at second anodizing time of 4 min.

• Membrane Journal
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• v.8 no.4
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• pp.191-202
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• 1998

The emission standards for diesel particulates have been continued to become tighter. This article reviews the pore and how to filtering characteristics and how to design the ceramic honeycomb filter which is generally used for diesel particulate filter. And the properties and fabrication methods of other particulate filters, i.e. ceramic fiber candle filter, ceramic foam filter, ceramic cross-flow filter and metal filter, are presented in this review. The results show that though the various filters have been developed and tested in the field, the more efforts are needed for the commercilaization of the diesel particulate filter.

• Proceedings of the Membrane Society of Korea Conference
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• 2005.11a
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• pp.268-272
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• 2005

• Membrane Journal
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• v.18 no.4
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• pp.325-335
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• 2008

In this study, we used multi-channels ceramic membrane having larger permeate volume per unit time rather than tubular membrane. The hybrid process for advanced drinking water treatment was composed of granular activated carbons (GAC) packing between module inside and outside of multi-channels microfiltration membrane. Instead of natural organic matters (NOM) and fine inorganic particles in natural water source, modified solution was prepared with humic acid and kaolin. Kaolin concentration was fixed at 30mg/L and humic acid was changed as $2{\sim}10\;mg/L$ to inspect effect of organic matters. As a result, both resistance of membrane fouling ($R_f$) and permeate flux (J) were highly influenced by concentration of humic acid. Also, in result of water-back-flushing period (FT) effect, the shorter FT was the more effective to reduce membrane fouling and to enhance permeate flux because of frequent water-back-flushing. However, the optimal FT condition was 8 min when operating costs were considered. Then, the hybrid process using multi-channels ceramic membrane and GAC was applied to lake water treatment. As a result, average treatment efficiencies in our experiment using the hybrid process were 98.02% for turbidity, 75.64% for $UV_{254}$ absorbance, 7.18% for TDS and 84.73% for $COD_{Mn}$.

• Journal of the Korean Ceramic Society
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• v.30 no.7
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• pp.589-597
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• 1993

The optimum sol solution for making alumina membrane was synthesized by using sol-gel method with aluminium isopropoxide. Two types of supports were made from the $\alpha$-Al2O3 powder. The porosities of supports could be controlled by the forming methods and the heat treatment conditions. After the support was coated with optimum sol solution and heat-treated at 50$0^{\circ}C$ for 1hour, the thickness of crack-free membrane could be controlled reproductively with dipping time.