• Title/Summary/Keyword: Cement properties

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Evaluation on Sulfate Attack Resistance of Cement Matrix (시멘트 경화체의 황산염침식 저항성 평가)

  • 문한영;김홍삼;이승태
    • Journal of the Korea Concrete Institute
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    • v.12 no.5
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    • pp.141-151
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    • 2000
  • Compressive strength, sulfate deterioration factor(SDF) and length change of 5 types of mortars immersed in sodium sulfate solution were observed. As the results of tests, it was found that the sulfate resistance of blended cement mortars were superior to that of portland cement mortars. Pore volume with diameter larger than 0.1 $\mu\textrm{m}$ of 5 types of pastes indicated that the micro-structures of blended cement pastes were denser, due to pozzolan reaction and latent hydraulic properties, than those of portland cement pastes. The XRD, ESEM, EDS and TG analyses demonstrated that the reactants such as ettringite and gypsum were significantly formed in portland cement pastes. Besides, compared with the $Ca(OH)_2$ content of ordinary portland cement pastes immersed in water and sodium sulfate solution, the $Ca(OH)_2$ contents of fly ash blended cement and ground granulated blast-furnace slag cement paste were about 58% and 28% in water, and 55% and 20% in sodium sulfate solution, respectively.

Properties of fine type cement grouts modified with redispersible polymer powder (재유화형 분말수지 개질 초미립자 시멘트계 균열주입재의 특성)

  • Lee, Chol-Woong;Choi, Nak-Woon;Kim, Byeong-Cheol;Yang, Suk-Woo;Soh, Yang-Seob
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.11a
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    • pp.727-730
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    • 2004
  • The purpose of this study is to evaluate the fundamental properties of fine type cement grouts with redispersible polymer powders. Cement grouts with redispersible polymer powders are prepared with various polymer-cement ratios, and tested. for flow, water absorption, drying shrinkage, flexural and compressive strengths. From the test results, flow of the cement grouts with EVA and Va/VeoVa polymer powers decreased with increasing elapsed time. Regardless of polymer type, the flexural strength of the cement grouts tends to increase with increase in polymer-cement ratio. The maximum compressive strengths of the cement grouts are obtained at a polymer-cement ratio of $5\%$.

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Properties of Polymer-Modified Cement Mortars Using Methylmethacrylate - Butyl Acrylate Latexes (MMA/BA 합성 라텍스 혼입 폴리머 시멘트 모르타르의 성질)

  • 형원길;송해룡;김완기;소양섭
    • Proceedings of the Korea Concrete Institute Conference
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    • 2001.11a
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    • pp.123-128
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    • 2001
  • The Purpose of this study is to clarify the effect of the monomer ratio on properties of the polymer-modified mortars using methyl methacrylate-butyl acrylate latexes, and to obtain basic data necessary to develop appropriate latexes for cement modifiers. This paper deals with the effect of the monomer ratio on the typical properties of polymer-modified mortars with methyl methacrylate-butyl acrylate latexes. The polymer latex-modified mortars are prepared with 5, 10, IS and 20% of polymer cement ratio respectively, and properties of modified mortars such as water absorption, compressive and flexural strengths, chloride-ion penetration depth are tested. The test results indicate that the monomer ratio is very important factors to characterize the strength properties of polymer-modified mortars, but the water absorption and chloride-ion penetration depth are influenced by polymer-cement ratio rather than monomer ratios.

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A Study of Rheological Properties on Cement Paste System Mixed with Mineral Admixtures (광물혼화재가 혼합된 시멘트 페이스트 시스템의 레올로지 특성에 관한 연구)

  • 박대효;노명현;박춘근
    • Proceedings of the Korea Concrete Institute Conference
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    • 2003.11a
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    • pp.505-508
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    • 2003
  • The rheological properties of cement paste system mixed with mineral admixture for the purpose of increasing the strength and improving durability and rheology of concrete were investigated. The results were as follows: The rheological properties of one-ingredient paste system were improved with increasing the dosage of superplasticizer. For two-ingredients paste system, increasing the replacement rate of BFS(blast furnace slag) and FA(fly ash), the yield value and plastic viscosity were decreased compared with non-replacement. In the OPC(ordinary portland cement)-SF(silica fume) system, increasing the replacement rate of SF, the plastic viscosity and yield value increased linearly. In three-ingredients paste system, both OPC-BFS-SF and OPC-FA-SF system, the rheological properties were improved compared with the only replacement of SF. Both two- and three- ingredients paste system, the rheological properties using BFS were improved more than FA.

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Thermal effects on the mechanical properties of cement mortars reinforced with aramid, glass, basalt and polypropylene fibers

  • Mazloom, Moosa;Mirzamohammadi, Sajjad
    • Advances in materials Research
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    • v.8 no.2
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    • pp.137-154
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    • 2019
  • In this study, thermal effects on the mechanical properties of cement mortars with some types of fibers is investigated. The replaced fibers were made of polypropylene (PP), aramid, glass and basalt. In other words, the main goal of this paper is to study the effects of different fibers on the mechanical properties of cement mortars after subjecting to normal and sub-elevated temperatures. The experimental tests used for investigating these effects were compressive, splitting tensile, and four-point bending tests at 20, 100 and $300^{\circ}C$, respectively. Moreover, the microstructures of the specimens in different temperatures were investigated using scanning electron microscope (SEM). Based on the experimental results, the negative effects of sub-elevated temperatures on four-point bending tests were much more than the others. Moreover, using the fibers with higher melting points could not improve the qualities of the samples in sub-elevated temperatures.

Surface and Chemical Properties of Surface-Modified UHMWPE Powder and Mechanical and Thermal Properties of Its Impregnated PMMA Bone Cement V. Effect of Silane Coupling Agent on the Surface Modification of UHMWPE Powder

  • Yang Dae Hyeok;Yoon Goan Hee;Shin Gyun Jeong;Kim Soon Hee;Rhee John M.;Khang Gilson;Lee Hai Bang
    • Macromolecular Research
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    • v.13 no.2
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    • pp.120-127
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    • 2005
  • Conventional poly(methyl methacrylate) (PMMA) bone cement has been widely used as an useful biopolymeric material to fix bone using artificial prostheses. However, many patients had to be reoperated, due to the poor mechanical and thermal properties of conventional PMMA bone cement, which are derived from the presence of unreacted MMA liquid, the shrinkage and bubble formation that occur during the curing process of the bone cement, and the high curing temperature ($above 100^{\circ}C$) which has to be used. In the present study, a composite PMMA bone cement was prepared by impregnating conventional PMMA bone cement with ultra high molecular weight polyethylene (UHMWPE) powder, in order to improve its mechanical and thermal properties. The UHMWPE powder has poor adhesion with other biopolymeric materials due to the inertness of the powder surface. Therefore, the surface of the UHMWPE powder was modified with two kinds of silane coupling agent containing amino groups (3-amino propyltriethoxysilane ($TSL 8331^{R}$) and N-(2-aminoethyl)-3-(amino propyltrimethoxysilane) ($TSL 8340^{R}$)), in order to improve its bonding strength with the conventional PMMA bone cement. The tensile strengths of the composite PMMA bone cements containing $3 wt\%$ of the UHMWPE powder surface-modified with various ratios of $TSL 8331^{R}$ and $TSL 8340^{R}$ were similar or a little higher than that of the conventional PMMA bone cement. However, no significant difference in the tensile strengths between the conventional PMMA bone cement and the composite PMMA bone cements could be found. However, the curing temperatures of the composite PMMA bone cements were significantly decreased.

Mineral Admixture Factors Affecting Rheological Properties of Cement Paste (시멘트 페이스트의 레올로지 특성에 미치는 혼화재 변수의 영향)

  • Heo Young-Sun;Hwang Yin-Sung;Shin Hyun-Sup;Yoon Seob;Lee Gun-Cheol;Han Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2005.11a
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    • pp.57-61
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    • 2005
  • Cement paste is originally the basic material and crucial factor consisting concrete. This study investigates the relationship between flow apparatuses, which are ring flow(R-F), flow cone(F-C) and mini slump(M-S), in order to estimate the fluidity of cement Paste. For quantitatively evaluating the measured data this study also investigated the calibration of the rheology consistent, such as yield value and plastic viscosity, of cement paste using viscometer For this purpose the present work discussed the influence of 3 type of ordinary portland cement with different companies, affecting the fluidity of cement paste. and it also demonstrated the influence of the various kinds of mineral admixtures, such as fly ash(FA), blast furnace slag(BS) and silica fume(SF) and that of incorporating ratio. The author concluded that using R-F apparatus is the most effective flow test method of cement paste and it is exactly proportional to other apparatus' rheological properties.

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Laboratory analysis of loose sand mixed with construction waste material in deep soil mixing

  • Alnunu, Mahdi Z.;Nalbantoglu, Zalihe
    • Geomechanics and Engineering
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    • v.28 no.6
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    • pp.559-571
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    • 2022
  • Deep soil mixing, DSM technique has been widely used to improve the engineering properties of problematic soils. Due to growing urbanization and the industrial developments, disposal of brick dust poses a big problem and causes environmental problems. This study aims to use brick dust in DSM application in order to minimize the waste in brick industry and to evaluate its effect on the improvement of the geotechnical properties. Three different percentages of cement content: (10, 15 and 20%) were used in the formation of soil-cement mixture. Unlike the other studies in the literature, various percentages of waste brick dust: (10, 20 and 30%) were used as partial replacement of cement in soil-cement mixture. The results indicated that addition of waste brick dust into soil-cement mixture had positive effect on the inherent strength and stiffness of loose sand. Cement replaced by 20% of brick dust gave the best results and reduced the final setting time of cement and resulted in an increase in unconfined compressive strength, modulus of elasticity and resilient modulus of sand mixed with cement and brick dust. The findings were also supported by the microscopic images of the specimens with different percentages of waste brick dust and it was observed that waste brick dust caused an increase in the interlocking between the particles and resulted in an increase in soil strength. Using waste brick dust as a replacement material seems to be promising for improving the geotechnical properties of loose sand.

Calcium release and physical properties of modified carbonate apatite cement as pulp capping agent in dental application

  • Zakaria, Myrna Nurlatifah;Cahyanto, Arief;El-Ghannam, Ahmed
    • Biomaterials Research
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    • v.22 no.4
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    • pp.346-351
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    • 2018
  • Background: Carbonate apatite ($CO_3Ap$) and silica-calcium phosphate composite (SCPC) are bone substitutes with good prospect for dental application. SCPC creates a hydroxyapatite surface layer and stimulate bone cell function while, $CO_3Ap$ induce apatite crystal formation with good adaptation providing good seal between cement and the bone. Together, these materials will add favorable properties as a pulp capping material to stimulate mineral barrier and maintain pulp vitality. The aim of this study is to investigate modification of $CO_3Ap$ cement combined with SCPC, later term as $CO_3Ap-SCPC$ cement (CAS) in means of its chemical (Calcium release) and physical properties (setting time, DTS and pH value). Methods: The study consist of three groups; group 1 (100% calcium hydroxide, group 2 $CO_3Ap$ (60% DCPA: 40% vaterite, and group 3 CAS (60% DCPA: 20% vaterite: 20% SCPC. Distilled water was employed as a solution for group 1, and $0.2mol/L\;Na_3PO_4$ used for group 2 and group 3. Samples were evaluated with respect to important properties for pulp capping application such as pH, setting time, mechanical strength and calcium release evaluation. Results: The fastest setting time was in $CO_3Ap$ cement group without SCPC, while the addition of 20% SCPC slightly increase the pH value but did not improved the cement mechanical strength, however, the mechanical strength of both $CO_3Ap$ groups were significantly higher than calcium hydroxide. All three groups released calcium ions and had alkaline pH. Highest pH level, as well as calcium released level, was in the control group. Conclusion: The CAS cement had good mechanical and acceptable chemical properties for pulp capping application compared to calcium hydroxide as a gold standard. However, improvements and in vivo studies are to be carried out with the further development of this material.

Effects of Portland Cement Characters and Working Temperature on the Physical Properties of Cement Mortars (시멘트의 특성과 사용 온도가 모르터의 물성에 미치는 영향)

  • 김원기;김창은
    • Journal of the Korean Ceramic Society
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    • v.37 no.5
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    • pp.410-417
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    • 2000
  • In this study the effects of specifics surface area of cement, addition amount of gypsum and substitution ratio of gypsum anhydrite ont he physical properties of cement mortars were investigated by measruements of setting time, flow, compressive strength and hydration heat evolution rate. The results showed that fluidity of mortars was increased by 40 wt.% of maximum flow change with the decreasing specific surface area of cement from 3,500$\textrm{cm}^2$/g to 3,300${\pm}$50$\textrm{cm}^2$/g and affected by the relationship between the cement and balancing between the chemical activityof cement and solubility of calcium sulfate are desirable to prevent the fluidity of concrete from decreasing by high temperature in summer season.

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