• Macromolecular Research
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• v.13 no.2
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• pp.120-127
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• 2005

Conventional poly(methyl methacrylate) (PMMA) bone cement has been widely used as an useful biopolymeric material to fix bone using artificial prostheses. However, many patients had to be reoperated, due to the poor mechanical and thermal properties of conventional PMMA bone cement, which are derived from the presence of unreacted MMA liquid, the shrinkage and bubble formation that occur during the curing process of the bone cement, and the high curing temperature ($above 100^{\circ}C$) which has to be used. In the present study, a composite PMMA bone cement was prepared by impregnating conventional PMMA bone cement with ultra high molecular weight polyethylene (UHMWPE) powder, in order to improve its mechanical and thermal properties. The UHMWPE powder has poor adhesion with other biopolymeric materials due to the inertness of the powder surface. Therefore, the surface of the UHMWPE powder was modified with two kinds of silane coupling agent containing amino groups (3-amino propyltriethoxysilane ($TSL 8331^{R}$) and N-(2-aminoethyl)-3-(amino propyltrimethoxysilane) ($TSL 8340^{R}$)), in order to improve its bonding strength with the conventional PMMA bone cement. The tensile strengths of the composite PMMA bone cements containing $3 wt\%$ of the UHMWPE powder surface-modified with various ratios of $TSL 8331^{R}$ and $TSL 8340^{R}$ were similar or a little higher than that of the conventional PMMA bone cement. However, no significant difference in the tensile strengths between the conventional PMMA bone cement and the composite PMMA bone cements could be found. However, the curing temperatures of the composite PMMA bone cements were significantly decreased.

• Restorative Dentistry and Endodontics
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• v.38 no.4
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• pp.215-221
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• 2013

Objectives: To determine the retentive strength and failure mode of undercut composite post, glass fiber post and polyethylene fiber post luted with flowable composite resin and resin-cement. Materials and Methods: Coronal parts of 120 primary canine teeth were sectioned and specimens were treated endodontically. The teeth were randomly divided into 6 groups (n = 20). Prepared root canals received intracanal retainers with a short composite post, undercut composite post, glass fiber post luted with flowable resin or resin-cement, and polyethylene fiber post luted with flowable resin or resin-cement. After crown reconstruction, samples were tested for retentive strength and failure mode. Statistical analysis was done with one-way ANOVA and Tukey tests (p < 0.05). Results: There were statistically significant differences between groups (p = 0.001). Mean bond strength in the undercut group was significantly greater than in the short composite post (p = 0.030), and the glass fiber post (p = 0.001) and the polyethylene fiber post group luted with resin-cement (p = 0.008). However, the differences between the undercut group and the groups with flowable composite as the luting agent were not significant (p = 0.068, p = 0.557). Adhesive failure was more frequent in the fiber post groups. Conclusions: Although the composite post with undercutting showed the greatest resistance to dislodgement, fiber posts cemented with flowable composite resin provided acceptable results in terms of retentive strength and fracture mode.

• Advances in concrete construction
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• v.3 no.1
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• pp.71-90
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• 2015

In order to investigate the feasibility and advantage of tuff used as pozzolan in cement-based composite, the representative specimens of tuff were collected, and their chemical compositions, proportion of vitreous phase, mineral species, and rock structure were measured by chemical composition analysis, petrographic analysis, and XRD. Pozzolanic activity strength index of tuff was tested by the ratio of the compression strength of the tuff/cement mortar to that of a control cement mortar. Pozzolanic reaction degree, and the contents of CH and bond water in the tuff/cement paste were determined by selective hydrochloric acid dissolution, and DSC-TG, respectively. The tuffs were demonstrated to be qualified supplementary binding material in cement-based composite according to relevant standards. The tuffs possessed abundant $SiO_2+Al_2O_3$ on chemical composition and plentiful content of amorphous phase on rock texture. The pozzolanic reaction degrees of the tuffs in the tuff/cement pastes were gradually increased with prolongation of curing time. The consistency of CH consumption and pozzolanic reaction degree was revealed. Variation of the pozzolanic reaction degree was enhanced with the bond water content and relationship between them appeared to satisfy an approximating linear law. The fitting linear regression equation can be applied to mutual conversion between pozzolanic reaction degree and bond water content.

• Proceedings of the Korea Concrete Institute Conference
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• 1998.10c
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• pp.105-110
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• 1998

The purpose of this was to examine the used of fly ash as a type of construction material. In this paper the results from a recent study on development of a cement composite utilizing relatively large amount of fly ash are presented. The flowable fly ash-cement sand composite was investigated for strength and flowability characteristics. The independent variable considered were: fly-ash content, sand content, and ratio of water to cementitious materials. Results of this study show that high volume fly-ash composite can be proportioned to obtain 10~15kg/$\textrm{cm}^2$ compressive strength at 28 days. For applications requiring strength between 10kg/$\textrm{cm}^2$ and 15kg/$\textrm{cm}^2$, the mixture with fly ash-cement ratio of 5.6 and sand-cement ratio of 28 with relatively high water content may be used. Slump was held at 25$\pm$1cm for all mixtures produced compressive strength at 28 days were found to range from 5kg/$\textrm{cm}^2$ to 13.7kg/$\textrm{cm}^2$.

• The Journal of Korean Academy of Prosthodontics
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• v.30 no.1
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• pp.93-101
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• 1992

The purpose of this study was to evaluate the effectiveness of core materials and luting agents on the retention of full veneer gold crown. The core materials used in this study was dental amalgam, and composite resin, and the luting agents were zinc phosphate cement, polycarboxylate cement, and glass ionomer cement. The obtained results were as follows. 1. In full veneer gold crown supported by composite resin core, the crown retention with zinc phosphate cement was the highest of all. 2. In full veneer gold crown supported by amalgam core, the crown retention was shown no statistical difference by luting agent. 3. There was no statistical difference in the crown retention between the full veneer gold crown supported by composite resin core and dental amalgam core.

• Journal of the Korean Ceramic Society
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• v.36 no.5
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• pp.539-546
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• 1999

Absorbent polymer-cement composites were fabricated by the semi-powder mixing OPC(ordinary Portland cement) with an absorbent polymer. The effects of absorbent polymer on the mechanical properties and the hydration characteristics were observed and the polymer-cement interaction also discussed. Absorbent polymer-cement composites showed the value of total porosity of 8vol% the value of 28 days flexural strength was up to 280 Kgf/cm2 in the case of absorbent polymer-cement composite at 1 wt% absorbent polymer content and microstructure of absorbent polymer-cement composite has been observed more dense than that of OPC paste. Accordingly the permeability of compositewas improved and so the moisture resistance was also increased. Adding polymer did not retard the hydration of OPC. It was considered from the results of IR(infrared) analysis that the functional group of absorbent polymer would be changed from unidentate to bidentate during by the hydration of cement minerals.

• Geomechanics and Engineering
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• v.23 no.6
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• pp.513-521
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• 2020

In this paper, due to the need for cutting cement-soil group pile composite foundation under the 7-story masonry structure of Zhenghe District and the shield tunnel of Zhengzhou Metro Line 5, a field test was conducted to directly cut cement-soil single pile composite foundation with diameter Ф=500 mm. Research results showed that the load transfer mechanism of composite foundation was not changed before and after shield tunnel cut the pile, and pile body and the soil between piles was still responsible for overburden load. The construction disturbance of shield cutting pile is a complicated mechanical process. The load carried by the original pile body was affected by the disturbance effect of pile cutting construction. Also, the fraction of the load carried by the original pile body was transferred to the soil between the piles and therefore, the bearing capacity of composite foundation was not decreased. Only the fractions of the load carried by pile and the soil between piles were distributed. On-site monitoring results showed that the settlement of pressure-bearing plates produced during shield cutting stage accounted for about 7% of total settlement. After the completion of pile cutting, the settlements of bearing plates generated by shield machine during residual pile composite foundation stage and shield machine tail were far away from residual pile composite foundation stage which accounted for about 15% and 74% of total settlement, respectively. In order to reduce the impact of shield cutting pile construction on the settlement of upper composite foundation, it was recommended to take measures such as optimization of shield construction parameters, radial grouting reinforcement and "clay shock" grouting within the disturbance range of shield cutting pile construction. Before pile cutting, the pile-soil stress ratio n of composite foundation was 2.437. After the shield cut pile is completed, the soil around the lining structure is gradually consolidated and reshaped, and residual pile composite foundation reaches a new state of force balance. This was because the condensation of grouting layer could increase the resistance of remaining pile end and friction resistance of the side of the pile.

• Steel and Composite Structures
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• v.17 no.6
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• pp.907-927
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• 2014

Ultra-lightweight cement composite (ULCC) with a compressive strength of 60 MPa and density of $1450kg/m^3$ has been developed and used in the steel-concrete-steel (SCS) sandwich structures. ULCC was adopted as the core material in the SCS sandwich composite beams to reduce the overall structural weight. Headed shear studs working in pairs with overlapped lengths were used to achieve composite action between the core material and steel face plates. Nine quasi-static tests on this type of SCS sandwich composite beams were carried out to evaluate their ultimate strength performances. Different parameters influencing the ultimate strength of the SCS sandwich composite beams were studied and discussed. Design equations were developed to predict the ultimate resistance of the cross section due to pure bending, pure shear and combined action between shear and moment. Effective stiffness of the sandwich composite beam section is also derived to predict the elastic deflection under service load. Finally, the design equations were validated by the test results.

• Steel and Composite Structures
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• v.21 no.3
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• pp.461-477
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• 2016

Steel-concrete-steel (SCS) sandwich composite wall has been proposed for building and offshore constructions. An ultra-lightweight cement composite with density1380 kg/m3 and compressive strength up to 60 MPa is used as core material and inter-locking J-hook connectors are welded on the steel face plates to achieve the composite action. This paper presents the numerical models using nonlinear finite element analysis to investigate the load displacement behavior of SCS sandwich walls subjected to axial compression. The results obtained from finite element analysis are verified against the test results to establish its accuracy in predicting load-displacement curves, maximum resistance and failure modes of the sandwich walls. The studies show that the inter-locking J-hook connectors are subjected to tension force due to the lateral expansion of cement composite core under compression. This signifies the important role of the interlocking effect of J-hook connectors in preventing tensile separation of the steel face plates so that the local buckling of steel face plates is prevented.

• Journal of the Korean Institute of Educational Facilities
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• v.20 no.4
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• pp.35-43
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• 2013

Some results of experimental investigation conducted to assess the effect of cement composite strength and ductility on the shear behavior and crack-damage mitigation of stud connections between existing reinforced concrete frame in school buildings and seismic strengthening elements from cyclically direct shear tests are described. The cement composite strengths include 50 for medium strength and 70 MPa for high strength. Two types of cement composites, strain-hardening cement composite (SHCC) and non-shrinkage mortar, are used for stud shear connection specimens. The special SHCCs are reinforced with hybrid 0.2% polyethylene (PE) and 1.3% polyvinyl alcohol (PVA) fibers at the volume fraction and exhibits tensile strain capacity ranging from 0.2 to 0.5%. Test result indicates that SHCC improves the seismic performance and crack-damage mitigation of stud shear connections compared with stud connections with non-shrinkage mortar. However, the performance enhancement in SHCC stud connections with transverse and longitudinal reinforcements is less notable for those without additional reinforcement.