• Title/Summary/Keyword: Cellulose acetate

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Optimization of Simultaneous Saccharification and Fermentation of Rice Straw to Produce Butanol (Butanol 생산을 위한 동시 당화 발효법의 최적화)

  • Jun, Young-Sook;Kwon, Gi-Seok;Kim, Byung-Hong
    • Microbiology and Biotechnology Letters
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    • v.16 no.3
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    • pp.213-218
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    • 1988
  • Studies were made to optimize the simultaneous saccharification and fermentation (SSF) of rice straw to produce butanol using Clostridium acetobutylicum KCTC 1037 and a cellulolytic enzyme preparation from Trichoderma viride. The fermentation was inhibited when the liquid enzyme preparation from Novo was used, whilst a successful fermentation was achieved in the SSF using the enzyme manufactured by Pacific Chemical Co. The minimum cellulase concentration for the successful fermentation of pure cellulose was found to be 4 IU/g of substrate used. Alkaline treatment was better method for the fermentation of rice straw by the system. SSF using 25% alkaline treated rice straw produced 150 mM butanol, 90 mM acetone. On the other hand, fermentation of ball milled rice straw was mainly acidogenic producing 98 mM acetate and 64 mM butyrate with less than 20 mM butanol. These results show that rice straw contains (a) specific inhibitor(s) for solventogenesis which is destroyed or soluble in alkali.

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A Study on the Extractives of Domestic Major Softwood Needles (II) - Antioxidant Activity of the Extractives from the Needles of Chamaecyparis pisifera (Sieb. et Zucc.) Endlicher - (국내산 주요 침엽수 잎의 추출성분 (II) - 화백나무 (Chamaecyparis pisifera (Sieb. et Zucc.) Endlicher)잎 추출성분 및 항산화 활성 -)

  • Lee, Sang-Keug;Bae, Young-Soo
    • Journal of the Korean Wood Science and Technology
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    • v.34 no.4
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    • pp.76-82
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    • 2006
  • The dried ground needles (2.0 kg) of Chamaecyparis pisifera (Sieb. et Zucc.) Endlicher were extracted with acetone-$H_2O$ (7:3, v/v), concentrated, and fractionated with a series of n-hexane, methylene chloride, ethyl acetate and water on a separation funnel. Each fraction was freeze dried, then a portion of ethyl acetate soluble powder was chromatographed on a Sephadex LH-20 column using a series of aqueous methanol and ethanol-n-hexane mixture as eluents. The isolated compounds were identified by cellulose TLC, $^1H$-, $^{13}C$-NMR, COSY, HETCOR, FAB and EI-MS. (+)-catechin, taxifolin-3-O-${\beta}$-D-xylopyrano-side, quercetin-3-O-${\alpha}$-L-rhamnopyranoside were isolated from the ethyl acetate soluble fraction of Chamaecypairs pisifera needle. Antioxidative tests on the isolated compounds indicated that all of the compounds showed similar values to ${\alpha}$-tocopherol and BHT as controls.

Hydrogen Production from Barley Straw and Miscanthus by the Hyperthermophilic Bacterium, Cadicellulosirupter bescii

  • Minseok Cha;Jun-Ha Kim;Hyo-Jin Choi;Soo Bin Nho;Soo-Yeon Kim;Young-Lok Cha;Hyoungwoon Song;Won-Heong Lee;Sun-Ki Kim;Soo-Jung Kim
    • Journal of Microbiology and Biotechnology
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    • v.33 no.10
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    • pp.1384-1389
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    • 2023
  • This work aimed to evaluate the feasibility of biohydrogen production from Barley Straw and Miscanthus. The primary obstacle in plant biomass decomposition is the recalcitrance of the biomass itself. Plant cell walls consist of cellulose, hemicellulose, and lignin, which make the plant robust to decomposition. However, the hyperthermophilic bacterium, Caldicellulosiruptor bescii, can efficiently utilize lignocellulosic feedstocks (Barley Straw and Miscanthus) for energy production, and C. bescii can now be metabolically engineered or isolated to produce more hydrogen and other biochemicals. In the present study, two strains, C. bescii JWCB001 (wild-type) and JWCB018 (ΔpyrFA Δldh ΔcbeI), were tested for their ability to increase hydrogen production from Barley Straw and Miscanthus. The JWCB018 resulted in a redirection of carbon and electron (carried by NADH) flow from lactate production to acetate and hydrogen production. JWCB018 produced ~54% and 63% more acetate and hydrogen from Barley Straw, respectively than its wild-type counterpart, JWCB001. Also, 25% more hydrogen from Miscanthus was obtained by the JWCB018 strain with 33% more acetate relative to JWCB001. It was supported that the engineered C. bescii, such as the JWCB018, can be a parental strain to get more hydrogen and other biochemicals from various biomass.

Evaluation of the membrane filtration and elution for detection of Giardia lamblia cysts in water (수중 Giardia lamblia cysts 검출을 위한 멤브레인 여과 및 용출에 대한 연구)

  • Hong, Uk-Seon;Kim, Gyeong-Ju;Lee, Gi-Se
    • 한국생물공학회:학술대회논문집
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    • 2000.04a
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    • pp.422-423
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    • 2000
  • The protozoan parasite Giardia lamblia has been implicated as the causative agents of many outbreaks of waterborne intestinal illness. Accurate evaluation of Giardia lamblia removal in water treatment process requires a reliable method for measuring the concentrations of these pathogens in water. The relative recovery of Giardia cysts was assessed for seeded samples of distilled water. Cysts preparation was done by encystment in vitro. Membrane filtration was evaulated with cellulose acetate, polycarbonate, polypropylene, polyethersulfone, nylon membranes. Elution conditions were varied to improve cyst recovery.

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Electrophoretic Study of Serum Protein Changes in Pregnancy (정상임부(正常姙婦)의 혈청단백분획량(血淸蛋白分劃量)의 변동(變動)에 관(關)한 연구(硏究))

  • Tchai, B.S.;Park, J.B.;Cho, K.H.;Kim, H.C.
    • Journal of Nutrition and Health
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    • v.7 no.4
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    • pp.33-37
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    • 1974
  • Changes in the concentration of total protein, albumin, ${\alpha}_1-,{\alpha}_2-,{\beta}-,$ and ${\gamma}-globulin$ in Serum from 138 healthy, normal pregnant woman were studied by the method of cellulose-acetate electrophoresis. 1. The concentration of total serum protein decreased gradually during the first 7 month, and showed a tendency to increase thereafter. 2. The concentration of serum albumin showed a steady continuous fall untill term. 3. During pregnancy,${\alpha}_1$ and ${\beta}-globulin$ value rose, ${\gamma}-globulin$ value fell and ${\alpha}_2-globulin$ value showed no significant change.

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Remediation Groundwater contaminated with Nitrate and Phosphate using Micellar-enhanced ultrafiltration

  • 백기태;양지원
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2002.04a
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    • pp.334-337
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    • 2002
  • The drinking water industry faces a growing number of difficultiesin the treatment of groundwater for drinking water production. Groundwater sources are frequently contaminated with nitrates and phosphates due to usage of chemical fertilizer In this study, feasibility of micellar enhanced ultrafiltation (MEUF) was investigated to remediate groundwater contaminated with nitrate and phosphate. Ultrafiltration membrane was cellulose acetate with molecular weight cut off (MWCO) 10,000 and celtyl pyridinium chloride (CPC) was used to form pollutant-micelle complex with nitrate and phosphate. The results show that nitrate and phosphate rejections are satisfactory. The removal efficiency of nitrate and phosphate show 80% and 84% in single pollutant system, respectively with 3 molar ratio of CPC to pollutants. In the multi-pollutant systems, the removalefficiency increased to 90 % and 89 % for nitrate and phosphate, respectively, The presence of nitrate in the solutions did not affect the removal of phosphate and that of phosphate did not affect the removal of nitrate. The concentration of CPC in the permeate and removal efficiency of CPC was a function of the concentration of CPC in the feed solutions.

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The Identification & Separation of Phenolic fraction in Cigarette Smoke Condensate (담배연기 응축물중 phenolic fraction의 분리와 확인)

  • Rhee, Mun-Su;Lim, Heung-Bin;Jang, Ki-Cheol
    • Journal of the Korean Society of Tobacco Science
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    • v.10 no.1
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    • pp.49-57
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    • 1988
  • The phenolic compounds were isolated from the cigarette smoke condensate using two immiscible organic solvents by a partition coefficient. Of them, 20 phenolic compounds were identified by GC and GC/MS. The amount of the phenolic compounds was phenol, p-crestol, hydroxybensoic acid in order. And there was no difference in composition of these compound dependent on leaf tobacco . About 70% amount of these compounds were absorbed to cellulose acetate filter used. The contents and composition of these compounds were various in the commercial cigarette.

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Interfacial Polymerization Formation and Thickness of Thin Film (계면중합 반응과정 고찰 및 박막의 두께 측정)

  • 박종원;민병렬
    • Proceedings of the Membrane Society of Korea Conference
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    • 1997.10a
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    • pp.87-89
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    • 1997
  • 1. 서론 : 막을 이용한 분리기술의 실용화의 최대 과제는 선택성이 높고 용매의 투과용매의 투과속도가 높은 막재질 및 처리 면적이 큰 막의 개발이 필요하게 되었다. 이러한 성능 개발은 1960년대 cellulose acetate 계통의 막개발 이후 1980년대 지지층 고분자위에 다른 고분자 물질을 도포한 복합막(thin film composite layer)이 개발되어 막의 성능을 급격히 발전시켰다. 그 중에서 초박막화(ultrathin membrane)는 분리막에 의한 분리공정의 최대 결점인 낮은 투과량의 개선을 꾀할 수 있다는 장점 때문에 다양한 시도가 이루어지고 있다. 이러한 박막 제조 방법에는 박층분산법, 침지코팅법, 기상증착법, 계면중합법이 있으나, 섞이지 않는 두 계면 사이에서 고분자를 형성시키는 계면중합법은 수용상에 함침된 지지막위에 유기상을 계변에서 중합시켜 박막을 얻는 기술이다. 중합과정에서 일어나는 계면의 형성과정에 대한 연구는 미흡하기에 이에 본 연구는 시간에 따른 계면중합 반응 형성과정을 고찰하는 방법을 소개하고, 형성된 박막의 아론적, 실험적 두께 측정을 비교하였다.

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Dyeing Properties of Bi-functional Reactive Dyes on a Novel Regenerated Cellulosic Fiber

  • Koh, Joonseok;Kim, Ik Soo;Kim, Sung Soo;Shim, Woo Sub;Kim, Jae Pil
    • Fibers and Polymers
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    • v.5 no.1
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    • pp.44-51
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    • 2004
  • Three bi-functional reactive dyes such as Bis(vinylsulphone) type, Bis(monochlorotriazine) type and Bis(mononicotinotriazine) type were applied to regular viscose rayon and new regenerated cellulosic fiber ($enVix^ⓡ$) which was prepared from cellulose acetate fiber by the hydrolysis of acetyl groups, and their dyeing properties and fastness properties were compared. enVix exhibited better dyeability and fastness than regular viscose rayon and these results were also explained by the differences in the supramolecular structure of these two fibers.

Printing Properties of Novel Regenerated Cellulosic Fibers

  • Kim, Ik-Soo;Koh, Joon-Seok;Han, Nam-Keun;Kim, Jae-Pil
    • Fibers and Polymers
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    • v.5 no.3
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    • pp.219-224
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    • 2004
  • The reactive printing properties of regular viscose rayon and a new regenerated cellulosic fiber (en Vix^{\textregistered}$) which was prepared from cellulose acetate fiber was investigated in a comparative manner. From the results, it was found that en Vix exhibited better printing properties than regular viscose rayon. It showed stable final color yields, irrespective of the amount of thickener, hence reproducibility of printing of en Vix is expected to be excellent. In addition, urea requirements were less for the printings on en Vix than for the corresponding printing on viscose rayon. Therefore, en Vix is also expected to reduce the amount of the urea which causes environmental problems in dyehouse effluent.