• 제목/요약/키워드: Cell temperature

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저온 고체산화물 연료전지용 공기극 미세구조 제어 및 성능개선 (Cathode Microstructure Control and Performance Improvement for Low Temperature Solid Oxide Fuel Cells)

  • 강중구;김진수;윤성필
    • 한국세라믹학회지
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    • 제44권12호
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    • pp.727-732
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    • 2007
  • In order to fabricate a highly performing cathode for low-temperature type solid oxide fuel cells working at below $700^{\circ}C$, electrode microstructure control and electrode polarization measurement were performed with an electronic conductor, $La_{0.8}Sr_{0.2}MnO_3$ (LSM) and a mixed conductor, $La_{0.6}Sr_{0.4}Co_{0.2}Fe_{0.8}O_3$(LSCF). For both cathode materials, when $Sm_{0.2}Ce_{0.8}O_2$ (SDC) buffer layer was formed between the cathode and yttria-stabilized zirconia (YSZ) electrolyte, interfacial reaction products were effectively prevented at the high temperature of cathode sintering and the electrode polarization was also reduced. Moreover, cathode polarization was greatly reduced by applying the SDC sol-gel coating on the cathode pore surface, which can increase triple phase boundary from the electrolyte interface to the electrode surface. For the LSCF cathode with the SDC buffer layer and modified by the SDC sol-gel coating on the cathode pore surface, the cathode resistance was as low as 0.11 ${\Omega}{\cdot}cm^2$ measured at $700^{\circ}C$ in air atmosphere.

알루미늄 발포소재의 성형 공정 인자가 기공제어에 미치는 영향 (Effects of Process Parameters on Cell Control of Aluminum Foal Material)

  • 전용필;강충길
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 1997년도 추계학술대회 논문집
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    • pp.163-166
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    • 1997
  • Aluminium foam material is a highly porous material having complicated cellular structure defined by randomly distributed air pores in metallic matrix. this structure gives the aluminium a set of properties which cannot be achieved by any of conventional treatments. The properties of aluminium foam material significantly depend on its porosity, so that a desired profile of properties can be tailored by changing the foam density. Melting method is the one of foaming processes, which the production has long been considered difficult to realize becaues of such problems as the low foamability of molten metal, the varying size of. cellular structures, solidification shrinkage and so on. These problems, however, have gradually been solved by researchers and some manufacturers are now producing foamed aluminum by their own methods. Most of all, the parameters of solving problem in electric furnace were stirring temperature, stirring velocity, foaming temper:iture, and so on. But it has not considered about those in induction heating, foaming velocity and foaming temperature in semi-solid state yet. Therefore, this paper presents the effects on these parameter to control cell size, quantity and distribution.

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Enhancement of Dimensional Stability of Compressed Open Cell Rigid Polyurethane Foams by Thermo-Mechanical Treatment

  • Ahn, WonSool
    • Elastomers and Composites
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    • 제50권1호
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    • pp.30-34
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    • 2015
  • Thermo-mechanical treatment process of a compressed open-cell rigid polyurethane foam (OC-RPUF), which was fabricated for the vacuum insulation panel (VIP), was studied to obtain an optimum condition for the dimensional stability by the relaxation of compressive stress. Thermo-mechanical deformation of the sample OC-RPUF was shown to occur from about $120^{\circ}C$. Yield stress of 0.36 MPa was shown at about 10% yield strain. And, densification of the foam started to occur from 75% compressive strain and could be continued up to max. 90%. Compression set of the sample restored after initial compression to 90% at room temperature was ca. 82%. Though the expansion occurred to about twice of the originally compressed thickness in case of temperature rise to $130^{\circ}C$, it could be overcome and the dimensional stability could be maintained if the constant load of 0.3 MPa was applied. As the result, a thermo-mechanical treatment process, i.e, annealing process at temperature of $130{\sim}140^{\circ}C$ for about 20 min as is the maximum compressed state at room temperature, should be required for dimensional stability as an optimum condition for the use of VIP core material.

고온형 고분자전해질 연료전지의 준3차원 모델링을 통한 국부적 동특성 해석에 관한 연구 (A Study on the Local Dynamic Characteristics of High Temperature Proton Exchange Membrane Fuel Cell by Quasi-three-dimensional Model)

  • 박재만;민경덕;강상규
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2011년도 추계학술대회 초록집
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    • pp.81.1-81.1
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    • 2011
  • High temperature proton exchange membrane fuel cell (HT-PEMFC) has been regarded as a promising clean energy sources. In this study, a quasi-three-dimensional dynamic model of HT-PEMFC has been developed and the local dynamic characteristics are investigated. The model has the geometrical simplification of 2+1D reduction (quasi-3D). The one-dimensional model consists of nine control volumes in cross-sectional direction to solve the energy conservation and the species conservation equations. Then, the one-dimensional model is discretized into 25 local sections along the gas flow direction to account for gas and thermal transport in channels. With this discretization, the local characteristics of HT-PEMFC such as species conservation, temperature, and current density can be captured. In order to study the basic characteristics of HT-PEMFC, it is important to investigate the local dynamic characteristics. Thus, the model is simulated at various operating conditions and the local dynamic characteristics related to them are observed. The model is useful to investigate the distribution of HT-PEMFC characteristics and the physical phenomena in HT-PEMFC.

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EVA(Ethylene Vinyl Acetate) 수지가 태양전지의 장기적인 수명에 미치는 영향에 관한 실험적 연구 (Experimental study on the effects of EVA(Ethylene Vinyl Acetate) for solar cell's long-term life)

  • 김선용
    • 대한안전경영과학회지
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    • 제17권4호
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    • pp.397-401
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    • 2015
  • In this study, analysed the characteristics of power drop and surface damage in solar cell through high temperature and humidity test in the 3 case of EVA(ethylene vinyl acetate) and 2 case ribbon thickness. The solar cells were tested during the 500hr in $85^{\circ}C$ temperature and 85% relative humidity conditions, that excerpted standard of PV Module(KS C IEC-61215). Through the EL(Electroluminescence) shots, specimen's surface have partialy damaged. Before and after high humidity and high temperature test, ribbon thickness $200{\mu}m$ EVA1 case power drop rate was 8.463%, EVA2 case was 6.667%, EVA3 case was 6.373%. In the ribbon thickness $250{\mu}m$ EVA1 case power drop rate was 6.521%, EVA2 case was 8.517%, EVA3 case was 6.019%. EVA3 case was the lowest power and FF(fill factor) drop rate at the 2 case of ribbon thickness, because EVA3 is laerger than EVA1 and EVA2 in thickness, elongation and tensile strength.

Al Doped ZnO 박막의 열처리에 따른 태양전지용 투명전도막 특성 (Properties of TCO Fabricated with Annealing Temperature of Al Doped ZnO Film for Solar Cell Application)

  • 김봉석;김응권;김용성
    • 한국세라믹학회지
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    • 제43권9호
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    • pp.532-536
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    • 2006
  • The annealing temperature effect of transparent conducting oxide film grown on glass substrate for solar cell application was studied in this paper. Using pulsed DC magnetron sputtering with 1 at% Al-doped ZnO target, TCO films were deposited on coming 7059 glass at room temperature. Al:ZnO thin films were annealed at 200, 400, Al $600^{\circ}C$ for 10 min and annealing resulted in lower biaxial compressive stress of about 1GPa and increased average crystallite size in all films. The as-grown film shows the resistivity of $1{\times}10^{-2}{\Omega}{\cdot}cm$ and transmittance under 80%, whereas the electrical and optical properties of film annealed at $400^{\circ}C$ are enhanced up to $5{\times}10^{-4}{\Omega}{\cdot}cm$ and 85%, respectively.

5 kW급 고온형 연료전지 촉매 연소기 유동 균일화 장치가 연소 특성에 미치는 영향 (Effect of Flow Uniformity Device on the Catalytic Combustor for 5 kW High Temperature Fuel Cell System)

  • 이상민;우현탁;안국영
    • 한국수소및신에너지학회논문집
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    • 제22권6호
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    • pp.878-883
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    • 2011
  • Effect of flow uniformity on the reaction characteristics of a catalytic combustor for high temperature fuel cell system has been experimentally investigated in the present study. One of the most important factor in designing catalytic combustion is to avoid hot spot in catalysts. In this regard, it is very important to secure flow uniformity of combustor inlet. A couple of perforated plates were applied at the front of catalyst region as flow uniformity device with minimal pressure drop. Results show that the velocity and temperature profile became more uniform when applying the flow uniformity device. CO and $CH_4$ emissions at the combustor exit were decreased and the average exit temperature was slightly increased with the flow uniformity device.

Anode-supported Type SOFCs based on Novel Low Temperature Ceramic Coating Process

  • Choi, Jong-Jin;Ahn, Cheol-Woo;Kim, Jong-Woo;Ryu, Jungho;Hahn, Byung-Dong;Yoon, Woon-Ha;Park, Dong-Soo
    • 한국세라믹학회지
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    • 제52권5호
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    • pp.338-343
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    • 2015
  • To prevent an interfacial reaction between the anode and the electrolyte layer during the conventional high-temperature co-firing process, an anode-supported type cell with a thin-film electrolyte was fabricated by low-temperature ceramic thick film coating process. Ni-GDC cermet composite was used as the anode material and YSZ was used as the electrolyte material. Open circuit voltage and maximum power density were found to strongly depend on the surface uniformity of the anode functional layer. By optimizing the microstructure of the anode functional layer, the open circuit voltage and maximum powder density of the cell increased to 1.11 V and $1.35W/cm^2$, respectively, at $750^{\circ}C$. When a GDC barrier layer was applied between the YSZ electrolyte and the LSCF cathode, the cell showed good stability, with almost no degradation up to 100 h. Anode-supported type SOFCs with high performance and good stability were fabricated using a coating process.

Triple junction 태양전지의 a-SiGe middle cell에 관한 연구 (Study of hydrogenated a-SiGe cell for middle cell of Triple junction solar cell)

  • 박태진;백승조;김범준
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2010년도 춘계학술대회 초록집
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    • pp.83.1-83.1
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    • 2010
  • Hydrogenated a-SiGe middle cell for triple junction solar cell was investigated with various process parameters. a-SiGe I-layer was deposited at substrate temperature $245^{\circ}C$ and hydrogen content(R) was up to 26.7. Low optical bandgap(1.45eV) of a-SiGe cell was applied for middle cell although a-SiGe single cell efficiency with low Ge content was higher. And this cell was applied to the middle cell of a glass superstrate type a-Si/a-SiGe/uc-Si triple junction solar cell. The triple junction solar cell was resulted in the initial efficiency of about 9%, area $0.25cm^2$, under global AM 1.5 illumination.

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발포금속 제조를 위한 석고주형의 특성 (Properties of Plaster Mold for Open Cell Aluminum Foam)

  • 김기영;백남익
    • 한국주조공학회지
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    • 제21권4호
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    • pp.253-259
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    • 2001
  • There are many methods to produce metal foams, which can be classified into three groups according to the state of the starting metal i.e. liquid or powder or solid. Three types of defects such as cell closing, cell deformation or breakdown and cell misrun are thought to be occurred when we make the open cell aluminum foams by precision casting. Filling ability of the mold slurry between preform is related with cell closing, mold collapsibility is related with cell deformation or breakdown, mold temperature and pouring pressure are related with cell misrun. These factors can be evaluated by measuring slurry fluidity, burnout strength and permeability of the mold. Properties of the plaster mold were evaluated to find optimum mold conditions for high quality open cell aluminum foam in this study. Permeability was almost zero independent of burnout conditions, however, crack initiation was found on the surface of all specimens one or two minutes after taking out from the furnace. Crack has grown and disappeared with time. This crack may facilitate the mold filling when molten metal is poured, because of the improved mold permeability. It was considered that crack initiation and disappearance was closely related with temperature difference between the surface and inner part. Knocking-out the mold is a difficult problem due to the small cell size, because continuous mesh structure of the metal foam is not strong. It is not easy to remove molding material after pouring. We can expect that water quenching can facilitate the knocking-out the mold after solidification without damaging cell structures. Collapsed particles after water quenching became bigger with the increase in time.

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