• Title/Summary/Keyword: Cell temperature

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Performance Analysis of Methane Fueled Marine Solid Oxide Fuel Cell and Steam Turbine Hybrid Power System (선박동력용 SOFC/ST 하이브리드시스템의 성능 평가)

  • Lee, Kyung-Jin;Oh, Jin-Suk;Kim, Sun-Hee;Oh, Sae-Gin;Lim, Tae-Woo;Kim, Jong-Su;Park, Sang-Kyun;Kim, Mann-Eung;Kim, Myoung-Hwan
    • Journal of Advanced Marine Engineering and Technology
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    • v.35 no.5
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    • pp.590-599
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    • 2011
  • The electrification of the waste heat of fuel cell is necessary to enhance the efficiency of fuel cell system. For this purpose, the SOFC/ST(Solid oxide fuel cell/Steam turbine) hybrid system is suitable. The purpose of this work is to predict the performance of methane fueled SOFC/ST hybrid power system and to analyze the influence of operating temperature of stack, current density of stack, combustor outlet gas temperature, and boiler outlet gas temperature. According to the analysis, it is proved that making the best use of the waste heat of stack and minimizing the fuel consumption of combustor are essential for the high-efficiency of SOFC/ST hybrid system.

Investigation of a Thermal Stress for the Unit Cell of a Solid Oxide Fuel Cell (고체산화물 연료전지 단위셀의 열응력에 관한 연구)

  • Kim, Young-Jin;Park, Sang-Kyun;Roh, Gill-Tae;Kim, Mann-Eung
    • Journal of Advanced Marine Engineering and Technology
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    • v.35 no.4
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    • pp.414-420
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    • 2011
  • Thermal stress analysis of a planar anode-supported SOFC considering electrochemical reactions has been performed under operating conditions where average current density varies from 0 to 2000 $A/m^2$. For the case of the 2000 $A/m^2$ operating condition, Structural stress analysis based on the temperature distributions obtained from the CFD analysis of the unit cell has also been done. From this one way Fluid-Structure Interaction(FSI) analysis, Maximum Von-Mises stress under negligible temperature gradient fields occurs when cell components are perfectly bonded. The maximum stress of the electrolyte, cathode and anode in a unit cell SOFC is 262.58MPa, 28.55MPa and 15.1MPa respectively. The maximum thermal stress is critically dependent on static friction coefficient.

Effect of Garlic Extracts with Extraction Conditions on Antioxidant and Anticancer Activity (추출조건에 따른 마늘 추출물의 항산화 및 항암활성 효과)

  • Kim, Hae-Ja;Han, Choong-Ho;Kim, Nan-Young;Lee, Eun-Kyoung;Lee, Ki-Nam;Cho, Hwa-Eun;Choi, Yun-Hee;Chong, Myong-Soo
    • Journal of Physiology & Pathology in Korean Medicine
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    • v.24 no.1
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    • pp.111-117
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    • 2010
  • The purpose of this study was to investigate the effect of garlic(Allium sativum L.) extracts with extraction conditions on antioxidant and anticancer activity. The extracts prepared for garlic by hot temperature extraction (HG), low temperature extraction (LG), UMPM extraction (UG), fermentation (FG) and black garlic hot temperature (BG) method. Content of total polyphenol compound was the BG higher than other extracts. The EDA (electron donating ability) and SOD-like activity was increased in dose-dependent manners, and the activity of BG and UM was significantly higher than LG and FG. We examined cytotoxicity, nitric oxide production of Raw 264.7 cell and inhibition of HT 1080 cell by MTT assay. All extracts does not have any toxic effects in macrophages(Raw 264.7). And UG inhibited the production of nitrite in Raw 264.7 cells activated with LPS. The antitumor effects of LG and UG on HT 1080 cell was indicated a significantly inhibition activity. These results suggested that UG (UMPM extraction of garlic) have activities of antioxidant, anticancer effects.

STUDY ON THERMOSENSITIVITY OF CHITOSAN SCAFFOLD AND ON ITS EFFECTS ON FIBROBLAST PROLIFERATION IN CELL THERAPY FOR SOFT TISSUE AUGMENTATION (연조직 증강을 위한 세포치료 시 비계로서 키토산의 온도 감응성 및 섬유모세포의 증식에 미치는 영향에 관한 연구)

  • Kim, Jung-Ho;Choi, Jin-Young
    • Journal of the Korean Association of Oral and Maxillofacial Surgeons
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    • v.35 no.3
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    • pp.146-152
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    • 2009
  • Traditional surgical method or injection using filler is performed for soft tissue augmentation. Surgical methods have disadvantage of surgical morbidity. Commercially available injectable materials have the disadvantages such as resorption, short-term effect. repeated application and hypersensitivity. Significant shortcoming of cell therapy using autologous fibroblasts is delay of treatment effect. Chitosan/${\beta}$-glycerol phosphate (GP) solution has thermosensitive property and allows sol-gel transition at physiologic pH and temperature. These properties may resolve the delay of treatment effect. The purposes of this study are to evaluate the viscosity and pH changes of chitosan/${\beta}$-GP solutions and to evaluate the effect of chitosan/${\beta}$-GP solution on fibroblast proliferation and production of collagen. We measured the viscosity and pH as function of temperature, of the solution containing 1:0.7, 1:0.75, 1:0.8 chitosan (1, 10, 100, 700 kDa) /${\beta}$-GP. Fibroblasts from ears of 5 rats were cultured in chitosan/${\beta}$-GP solutions for 3 weeks. Cell proliferation and collagen contents were measured every week with WST (water-soluble tetrazolium salt) assay and Collagen assay respectively. The Results are 1) Chitosan(100 kDa<)/${\beta}$-GP solution (1:0.75) showed sol-gel transition at physiologic pH and body temperature and injectable properties. It will enable to resolve the delay in treatment effect 2) Cell proliferation and total collagen contents of the control group were increased with time. However, these decreased after the 1st week in experimental group 3) Collagen contents in the experimental group are higher than that of control group. Chitosan/${\beta}$-GP solution may provide favorable conditions for cell function

Properties of Silicon Nitride Deposited by RF-PECVD for C-Si solar cell (결정질 실리콘 태양전지를 위한 실리콘 질화막의 특성)

  • Park, Je-Jun;Kim, Jin-Kuk;Song, Hee-Eun;Kang, Min-Gu;Kang, Gi-Hwan;Lee, Hi-Deok
    • Journal of the Korean Solar Energy Society
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    • v.33 no.2
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    • pp.11-17
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    • 2013
  • Silicon nitride($SiN_x:H$) deposited by radio frequency plasma enhanced chemical vapor deposition(RF-PECVD) is commonly used for anti-reflection coating and passivation in crystalline silicon solar cell fabrication. In this paper, characteristics of the deposited silicon nitride was studied with change of working pressure, deposition temperature, gas ratio of $NH_3$ and $SiH_4$, and RF power during deposition. The deposition rate, refractive index and effective lifetime were analyzed. The (100) p-type silicon wafers with one-side polished, $660-690{\mu}m$, and resistivity $1-10{\Omega}{\cdot}cm$ were used. As a result, when the working pressure increased, the deposition rate of SiNx was increased while the effective life time for the $SiN_x$-deposited wafer was decreased. The result regarding deposition temperature, gas ratio and RF power changes would be explained in detail below. In this paper, the optimized condition in silicon nitride deposition for silicon solar cell was obtained as 1.0 Torr for the working pressure, $400^{\circ}C$ for deposition temperature, 500 W for RF power and 0.88 for $NH_3/SiH_4$ gas ratio. The silicon nitride layer deposited in this condition showed the effective life time of > $1400{\mu}s$ and the surface recombination rate of 25 cm/s. The crystalline silicon solar cell fabricated with this SiNx coating showed 18.1% conversion efficiency.

Optimization of Drive-in Process with Various Times and Temperatures in Crystalline Silicon Solar Cell Fabrication (결정질 실리콘 태양전지 도핑 확산 공정에서 시간과 온도 변화에 의한 Drive-in 공정 연구)

  • Lee, Hee-Jun;Choi, Sung-Jin;Myoung, Jae-Min;Song, Hee-Eun;Yu, Gwon-Jong
    • 한국태양에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.51-55
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    • 2011
  • In this paper, the optimized doping condition of crystalline silicon solar cells with 156 ${\times}$ 156 mm2 area was studied. To optimize the drive-in condition in the doping process, the other conditions except drive-in temperature and time were fixed. After etching 7 ${\mu}m$ of the surface to form the pyramidal structure, the silicon nitride deposited by the PECVD had 75~80 nm thickness and 2 to 2.1 for a refractive index. The silver and aluminium electrodes for front and back sheet, respectively, were formed by screen-printing method, followed by firing in $400-425-450-550-850^{\circ}C$ five-zone temperature conditions to make the ohmic contact. Drive-in temperature was changed in range of $828^{\circ}C$ to $860^{\circ}C$ and time was from 3 min to 40 min. The sheet resistance of wafer was fixed to avoid its effect on solar cell. The solar cell fabricated with various conditions showed the similar conversion efficiency of 17.4%. This experimental result showed the drive-in temperatures and times little influence on solar cell characteristics.

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Operation Characteristics and Analysis of Temperature Gradients in a 5-kW Molten Carbonate Fuel Cell Stack (5 kW 용융탄산염 연료전지 스택내 운전특성 및 온도 변화 해석)

  • Lim, Hee-Chun;Koh, Joon-Ho;Ryu, Jeong In
    • Transactions of the Korean hydrogen and new energy society
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    • v.10 no.2
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    • pp.107-118
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    • 1999
  • A 5-kW MCFC stack with $3,000cm^2$ electrode area was tested to investigate cell performance and operation characteristics. The stack performance was evaluated based on electrical output and I-V change. The stack showed high cell performance (7.6 kW) than the design performance and operated for more than 5,760 hours, but a significant temperature gradient inside the stack was observed. A 3-dimensional mathematical model for molten carbonate fuel cell (MCFC) was developed for the purpose of simulation of stack performance during the operation. The model was solved using PHOENICS, a computational fluid dynamics (CFD) code. The simulation result demonstrated a close prediction of the temperature gradient and stack performance.

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Preliminary Performance Assessment of a Fuel-Cell Powered Hypersonic Airbreathing Magjet

  • Bernard Parent;Jeung, In-Seuck
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2004.03a
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    • pp.703-712
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    • 2004
  • A variant of the magnetoplasma jet engine (magjet) is here proposed for airbreathing flight in the hypersonic regime. As shown in Figure 1, the engine consists of two distinct ducts: the high-speed duct, in which power is added electromagnetically to the incoming air by a momentum addition device, and the fuel cell duct in which the flow stagnation temperature is reduced by extracting energy through the use of a magnetoplas-madynamic (MPD) generator. The power generated is then used to accelerate the flow exiting the fuel cells with a fraction bypassed to the high-speed duct. The analysis is performed using a quasi one-dimensional model neglecting the Hall and ion slip effects, and fix-ing the fuel cell efficiency to 0.6. Results obtained show that the specific impulse of the magjet is at least equal to and up to 3 times the one of a turbojet, ram-jet, or scramjet in their respective flight Mach number range. Should the air stagnation temperature in the fuel cell compartment not exceed 5 times the incoming air static temperature, the maximal flight Mach number possible would vary between 6.5 and 15 for a magnitude of the ratio between the Joule heating and the work interaction in the MPD generator varied between 0.25 and 0.01, respectively. Increasing the mass flow rate ratio between the high speed and fuel cell ducts from 0.2 to 20 increases the engine efficiency by as much as 3 times in the lower supersonic range, while resulting in a less than 10% increase for a flight Mach number exceeding 8.

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Study on Possibility of PrBaMn2O5+δ as Fuel Electrode Material of Solid Oxide Electrolysis Cell (이중 페로브스카이트 촉매 PrBaMn2O5+δ의 고온전기분해조(Solid Oxide Electrolysis Cell) 연료극 촉매로 적용 가능성에 대한 연구)

  • Kwon, Youngjin;Kim, Dongyeon;Bae, Joongmyeon
    • Journal of the Korea Institute of Military Science and Technology
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    • v.20 no.4
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    • pp.491-496
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    • 2017
  • The hydrogen($H_2$) is promising energy carrier of renewable energy in the microgrid system such as small village and military base due to its high energy density, pure emission and convenient transportation. $H_2$ can be generated by photocatalytic water splitting, gasification of biomass and water electrolysis driven by solar cell or wind turbine. Solid oxide electrolysis cells(SOECs) are the most efficient way to mass production due to high operating temperature improving the electrode kinetics and reducing the electrolyte resistance. The SOECs are consist of nickel-yttria stabilized zirconia(NiO-YSZ) fuel electrode / YSZ electrolyte / lanthanum strontium manganite-YSZ(LSM-YSZ) air electrode due to similarity to Solid Oxide Fuel Cells(SOFCs). The Ni-YSZ most widely used fuel electrode shows several problems at SOEC mode such as degradation of the fuel electrode because of Ni particle's redox reaction and agglomeration. Therefore Ni-YSZ need to be replaced to an alternative fuel electrode material. In this study, We studied on the Double perovskite $PrBrMnO_{5+{\delta}}$(PBMO) due to its high electric conductivity, catalytic activity and electrochemical stability. PBMO was impregnated into the scaffold electrolyte $La_{0.8}Sr_{0.2}Ga_{0.85}Mg_{0.15}O_{3-{\delta}}$(LSGM) to be synthesized at low temperature for avoiding secondary phase generated when it exposed to high temperature. The Half cell test was conducted at SOECs and SOFCs modes.

Performance Analysis of Ammonia-Fed Solid Oxide Fuel Cell Using Alternating Flow (교류 흐름 방식을 적용한 암모니아 공급 고체산화물 연료전지의 성능 분석)

  • QUACH, THAI-QUYEN;GIAP, VAN-TIEN;LEE, DONG KEUN;LEE, SUNYOUP;BAE, YONGGYUN;AHN, KOOK YOUNG;KIM, YOUNG SANG
    • Transactions of the Korean hydrogen and new energy society
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    • v.33 no.5
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    • pp.557-565
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    • 2022
  • The effect of flow configuration in ammonia-fed solid oxide fuel cell are investigated by using a three-dimensional numerical model. Typical flow configurations including co-flow and counter-flow are considered. The ammonia is directly fed into the stack without any external reforming process, resulting in an internal decomposition of NH3 in the anode electrode of the stack. The result showed that temperature profile in the case of counter-flow is more uniform than the co-flow configuration. The counter-flow cell, the temperature is highest at the middle of the channel while in the case of co-flow, the temperature is continuously increased and reached maximum value at the outlet area. This leads to a higher averaged current density in counter-flow compared to that of co-flow, about 5%.