• Title/Summary/Keyword: Cell surface properties

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Effects of pH of Reaction Solution on the Structural and Optical Properties of CdS Thin Films for Solar Cell Applications (태양전지용 CdS 박막의 구조적 및 광학적 특성에 미치는 반응용액의 pH 영향)

  • Lee, Jae-Hyeong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.24 no.8
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    • pp.616-621
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    • 2011
  • In this paper, CdS thin films, which were widely used window layer of the CdTe and the Cu(In,Ga)$Se_2$ thin film solar cell, were grown by chemical bath deposition, and effects of pH of reaction solution on the structural and optical properties were investigated. For pH<10.5, as the pH of reaction solution was higher, the deposition rate of CdS films was increased by improving ion-by-ion reaction in the substrate surface and the crystallinity of the films was improved. However, when the pH was higher than 10.5, the deposition rate was decreased because of smaller $Cd^{2+}$ ion concentration in the reaction solution. Also, the crystallinity of the films were deteriorated. The CdS films deposited at lower pH showed poor optical transmittance due to adsorbed colloidal particles, while the transmittance was improved for higher pH.

Study on the Change of Physical and Anatomical Properties in the Pine Wood by Accelerated Weathering Test (촉진열화실험에 의한 소나무의 물성 및 조직 변화에 대한 연구)

  • Kim, Gwang-Chul
    • Journal of the Korea Furniture Society
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    • v.23 no.3
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    • pp.324-331
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    • 2012
  • The domestic pine was used to investigate the change of specific gravity, moisture contents, color and anatomical structure by accelerated weathering test (AWT). According to visual inspection, a few knot separation and looseness as well as considerable surface discoloration was found out. However, the crack and split of surface texture have been never occurred till the last step of AWT. On the whole, as the time of accelerated weathering test has increased, the specific gravity has decreased. Finally, after the 9th week of AWT, the specific gravity was 0.38 that reached to 82% compared to the control specimen. In case of moisture content (MC), it showed rising trend in its early stages, however, after 3th week of AWT it have displayed steady state. A deterioration of cell-wall components was not remarkably observed by scanning electron microscope (SEM), however the ray fractures of AWT specimen were observed more than those of control specimen. The full fracture of epithelial cell around resin canal was observed by optical microscope. The fracture of ray of 2th cycle AWT specimen was first, followed by 1th week and control group. A distortion of tracheid for early spring wood and fracture of epithelial cell were generally observed by a similar level, regardless of duration time of AWT. Therefore, it is obvious that increasing duration time of AWT does not affect the deterioration of micro-structure for wood members from this study. Although a considerable change of anatomical properties was not found, there is a need of further research to understand how will the changes of specific gravity and MC on the physical properties of wood member.

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Mechanical Properties of EPDM Gasket after Long-Term Operations (EPDM 가스켓의 장시간 운전에 따른 기계적 성능변화)

  • Wu, Lan;Kim, Seon-Hak;Cheon, Seung-Ho;Kim, Jin-Su;Hyun, Deok-Su;Kim, Byeong-Heon;Lee, Sung-Kun;Jeong, Jae-Hoon;Ji, Duk-Jin;Oh, Byeong-Soo
    • Transactions of the Korean hydrogen and new energy society
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    • v.22 no.4
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    • pp.488-494
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    • 2011
  • Gasket plays an important role on sealing of the polymer electrolyte membrane fuel cell (PEMFC) stack. Stack requires gaskets in each cell to keep the hydrogen and air/oxygen within their respective regions. The failure of the gasket creates the problems of fuel leakage, mixing, damage on parts and can be a direct reason for the degrading the efficiency of fuel cell. The purpose of this paper researches on how mechanical properties of EPDM gasket in PEMFC are changed after long-term operations. The EPDM (ethylenepropylene-diene monomer) gaskets are obtained from the stack after long-term operations. DMA (dynamic mechanical analysis) is conducted to access the change of mechanical properties of the EPDM gasket. SEM/EDS (scanning electron microscope/energy dispersive spectroscopy) was used to show the surface topography and chemical characterization on the sample surface.

High Concentration of Red Clay as an Alternative for Antibiotics in Aquaculture

  • Jung, Jaejoon;Jee, Seung Cheol;Sung, Jung-Suk;Park, Woojun
    • Journal of Microbiology and Biotechnology
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    • v.26 no.1
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    • pp.130-138
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    • 2016
  • The use of antibiotics in aquaculture raises environmental and food safety concerns because chronic exposure of an aquatic ecosystem to antibiotics can result in the spread of antibiotic resistance, bioaccumulation of antibiotics in the organisms, and transfer of antibiotics to humans. In an attempt to overcome these problems, high-concentration red clay was applied as an alternative antibiotic against the following common fish pathogens: Aeromonas salmonicida, Vibrio alginolyticus, and Streptococcus equinus. The growth of A. salmonicida and V. alginolyticus was retarded by red clay, whereas that of S. equinus was promoted. Phase contrast and scanning electron microscopy analyses confirmed the attachment of red clay on cell surfaces, resulting in rapid gravitational removal and cell surface damage in both A. salmonicida and V. alginolyticus, but not in S. equinus. Different cell wall properties of grampositive species may explain the unharmed cell surface of S. equinus. Significant levels of oxidative stress were generated in only the former two species, whereas significant changes in membrane permeability were found only in S. equinus, probably because of its physiological adaptation. The bacterial communities in water samples from Oncorhynchus mykiss aquacultures supplemented with red clay showed similar structure and diversity as those from oxytetracycline-treated water. Taken together, the antibiotic effects of high concentrations of red clay in aquaculture can be attributed to gravitational removal, cell surface damage, and oxidative stress production, and suggest that red clay may be used as an alternative for antibiotics in aquaculture.

The Effect of Heat Sterilization on the Surface Topography and the Tensile Properties in Various Nickel Titanium Wires Including a Korean Product (열멸균과정이 nickel titanium호선의 기계적 성질과 표면상태에 미치는 영향)

  • Kim, Byoung-Ho;Nahm, Dong-Seok;Yang, Won-Sik
    • The korean journal of orthodontics
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    • v.28 no.6 s.71
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    • pp.927-935
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    • 1998
  • The purpose of this study is to investigate the changes of mechanical properties and surface topography of various nickel titanium wires after heat sterilization for recycling with quantitative method. The materials used were four kinds of nickel titanium orthodontic wires including a Korean product. Experimental specimens were treated with two kinds of heat sterilization methods ; dry heat ($180^{\circ}C$, 60min) and autoclave ($121^{\circ}C$, 15-20psi, 30min). Mechanical properties were evaluated by tensile test with Instron 4466 (load cell capacity:.1000 kg, cross head speed:5mm/min, grip distince:40mm in room temperature). Surface topography of various wires was compared with each other qualitatively by using scanning electron microscopy and quantitatively by using profilometer. The findings were analyzed statistically with student t-tests. The results were as follows; 1. Neither method of heat sterilization had any effects on tensile properties of the nickel-titanium wires used in this experiment. 2. Before heat sterilization, the surface smoothness was highest in Optimalloy, followed by Align and Sentalloy, with NiTi showing the lowest smoothness value. 3. In surface topography, Align and Optimalloy were not influenced by heat sterilization. NiTi, on the other hand, had increased roughness after dry heat sterilization and Sentalloy showed the same tendency after each of the two heat sterilization procedures.

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Effects of Oxygen Plasma Treatment on the Electrical Properties of Organic Photovoltaic Cells (유기 광기전 소자의 전기적 특성에 미치는 산소 플라즈마 처리의 영향)

  • Oh, Dong-Hoon;Lee, Young-Sang;Park, Hee-Doo;Shin, Jong-Yeol;Kim, Tae-Wan;Hong, Jin-Woong
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.60 no.12
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    • pp.2276-2280
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    • 2011
  • An indium-tin-oxide (ITO) is normally used as a substrate in organic photovoltaic cells. We examined the effects of an oxygen ($O_2$) plasma treatment on the electrical properties of an organic photovoltaic cell. Experiments with four-point probe method and atomic force microscope revealed the lowest surface resistance of 17.64 ${\Omega}$/sq and the lowest average surface roughness of 1.39 nm at the plasma treatment power of 250 W. A device structure of ITO/CuPc/$C_{60}$/BCP/$Cs_2CO_3$/Al was fabricated by thermal evaporation with and without the plasma treated ITO substrate. It was found that the power conversion efficiency of the cell with the plasma treated ITO is 65 % higher than the one without the plasma treated ITO.

Effects of $O_2$ Plasma Treatment on the Electrical Properties of Organic Photovoltaic Cell (유기 광기전 소자의 전기적 특성에 미치는 산소 플라즈마 처리의 영향)

  • Oh, Dong-Hoon;Lee, Young-Sang;Park, Hee-Doo;Shin, Jong-Yeol;Kim, Tae-Wan;Hong, Jin-Woong
    • Proceedings of the KIEE Conference
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    • 2011.07a
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    • pp.1463-1464
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    • 2011
  • An indium thin oxide(ITO) is used as a substrate material for organic light-emitting diodes(OLEDs) and organic photovoltaic cells. This study examined the effects of an $O_2$ plasma treatment on the electrical properties of an organic photovoltaic cell. The four probe method and Atomic force microscope(AFM) revealed the lowest surface resistance at the plasma treatment intensity of 250 [W] and the lowest average surface roughness of 2.0 [nm] at 250 [W]. The lowest average resistance of 17 [${\Omega}$/sq] was also observed at 250 [W] 40 [sec]. The $O_2$ plasma treatment device and a basic device in a structure of CuPc/C60/BCP/Al on ITO glass were fabricated by thermal evaporation, respectively. When the $O_2$ plasma treatment was used to the ITO, The experimental results revealed that the power conversion efficiency(PCE) indicated 65 [%] higher in the PCE than that without the plasma treatment.

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Corrosion Behavior of Anode Current Collectors in Molten Carbonate Fuel Cells (용융탄산염 연료전지 Anode부 집전판의 부식특성)

  • Han, Won-Kyu;Ju, Jeong-Woon;Shin, Jung-Cheol;Kang, Sung-Goon;Jun, Joong-Hwan;Lim, Hee-Chun
    • Korean Journal of Materials Research
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    • v.18 no.5
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    • pp.259-265
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    • 2008
  • The corrosion and degradation factors of a current collector in a molten carbonate fuel cell (MCFC) were investigated to determine the optimized coating thickness of nickel on STS316L. The results show that the surface morphology and electrical properties depended on the nickel coating thickness. The surface morphology gradually changed from a flat to a porous structure along as the nickel coating thickness decreased, and the electrical resistance of the nickel-coated STS316L increased as the nickel coating thickness decreased. This can be attributed to the diffusion of elements of Fe and Cr from the substrate through the nickel grain boundaries. Additionally, carburization in the metal grains or grain boundaries in an anodic environment was found to influence the electrical properties due to matrix distortion. The resistance of Cr-oxide layers formed in an anodic environment causes a drop in the potential, resulting in a decrease in the system efficiency.

Bioproduction and Anticancer Activity of Biosurfactant Produced by the Dematiaceous Fungus Exophiala dermatitidis SK80

  • Chiewpattanakul, Paramaporn;Phonnok, Sirinet;Durand, Alain;Marie, Emmanuelle;Thanomsub, Benjamas Wongsatayanon
    • Journal of Microbiology and Biotechnology
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    • v.20 no.12
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    • pp.1664-1671
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    • 2010
  • A new biosurfactant producer was isolated from palm-oil-contaminated soil and later identified through morphology and DNA sequencing as the yeast-like fungus Exophiala dermatitidis. Biosurfactant production was catalyzed by vegetable oil, supplemented with a basal medium. The culture conditions that provided the biosurfactant with the highest surface activity were found to be 5% palm oil with 0.08% $NH_4NO_3$, at a pH of 5.3, with shaking at 200 rpm, and a temperature of $30^{\circ}C$ for a 14-day period of incubation. The biosurfactant was purified, in accordance with surfactant properties, by solvent fractionation using silica gel column chromatography. The chemical structure of the strongest surface-active compound was elucidated through the use of NMR and mass spectroscopy, and noted to be monoolein, which then went on to demonstrate antiproliferative activity against cervical cancer (HeLa) and leukemia (U937) cell lines in a dose-dependent manner. Interestingly, no cytotoxicity was observed with normal cells even when high concentrations were used. Cell and DNA morphological changes, in both cancer cell lines, were observed to be cell shrinkage, membrane blebbling, and DNA fragmentation.

EO performance of TN cell on the inorganic films surface using DuoPIGatron ion source on NDLC thin film (무기박막표면에 DuoPIGatron 이온소스를 이용한 TN-LCD 셀의 전기광학 특성)

  • Kim, Byoung-Yong;Hwang, Jeoung-Yeon;Kim, Sang-Hun;Han, Jung-Min;Seo, Dae-Shik
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.432-433
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    • 2006
  • Electro-optical (EO) characteristics of twisted nematic (TN) - liquid crystal display (LCD) on the NDLC thin film using obliquely ion beam (IB) exposure as new ion beam (IB) type system (DuoPIGatrion ion source). A good uniform alignment of the nematic liquid crystal (NLC) alignment with the ion beam exposure on the NDLC thin film was observed. In addition, it can be achieved the good EO properties of the ion-beam-aligned TN-cell on polyimide surface ; the stable VT curve in the ion-beam-aligned TN cell on the NDLC thin film with ion beam exposure using new type IB equipment was obtained. and the fast response time in the ion-beam-aligned TN cell on the NDLC thin film with ion beam exposure using new type IB equipment was obtained.

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