• Title/Summary/Keyword: Cell surface properties

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석탄 물성에 따른 직접탄소 연료전지의 전기화학 반응 특성 연구 (A Study on the Effect of Coal Properties on the Electrochemical Reactions in the Direct Carbon Fuel Cell System)

  • 안성율;엄성용;이영훈;문철언;성연모;최경민;김덕줄
    • 대한기계학회논문집B
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    • 제36권10호
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    • pp.1033-1041
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    • 2012
  • 본 논문에서는 석탄의 물리적 화학적 구조에 의한 직접탄소 연료전지 내부의 전기화학 반응 특성의 변화에 대하여 연구하였다. 석탄의 구조, 표면적 및 기공체적, 작용기의 분포 등을 분석하기 위하여 다양한 분석 기법(TGA, XRD, BET, XPS)을 사용하였다. 석탄 내부에 존재하는 탄소의 강력한 결정구조는 연료의 비표면적 및 기공크기를 축소시켜 고 전류밀도 영역에서 급격한 포텐셜의 감소를 초래한다. 표면에 분포하는 작용기는 저전류 밀도 영역에서의 전기화학 반응에 영향을 미치며, 제한 전류밀도 및 최대 전력밀도는 전체 탄소의 양과 밀접한 상관관계를 가지고 있다는 것을 확인할 수 있었다. 전해질의 물질전달 향상 및 작동온도에 의한 영향도 논하였다.

Effects of Serial Passage on the Characteristics and Chondrogenic Differentiation of Canine Umbilical Cord Matrix Derived Mesenchymal Stem Cells

  • Lee, K.S.;Cha, S.H.;Kang, H.W.;Song, J.Y.;Lee, K.W.;Ko, K.B.;Lee, H.T.
    • Asian-Australasian Journal of Animal Sciences
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    • 제26권4호
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    • pp.588-595
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    • 2013
  • Mesenchymal stem cells (MSCs) are often known to have a therapeutic potential in the cell-mediated repair for fatal or incurable diseases. In this study, canine umbilical cord MSCs (cUC-MSCs) were isolated from umbilical cord matrix (n = 3) and subjected to proliferative culture for 5 consecutive passages. The cells at each passage were characterized for multipotent MSC properties such as proliferation kinetics, expression patterns of MSC surface markers and self-renewal associated markers, and chondrogenic differentiation. In results, the proliferation of the cells as determined by the cumulative population doubling level was observed at its peak on passage 3 and stopped after passage 5, whereas cell doubling time dramatically increased after passage 4. Expression of MSC surface markers (CD44, CD54, CD61, CD80, CD90 and Flk-1), molecule (HMGA2) and pluripotent markers (sox2, nanog) associated with self-renewal was negatively correlated with the number of passages. However, MSC surface marker (CD105) and pluripotent marker (Oct3/4) decreased with increasing the number of subpassage. cUC-MSCs at passage 1 to 5 underwent chondrogenesis under specific culture conditions, but percentage of chondrogenic differentiation decreased with increasing the number of subpassage. Collectively, the present study suggested that sequential subpassage could affect multipotent properties of cUC-MSCs and needs to be addressed before clinical applications.

수종의 탈단백 우골 이식재의 특성 비교 분석 (A comparative analysis of basic characteristics of several deproteinized bovine bone substitutes)

  • 여신일;박성환;노우창;박진우;이재목;서조영
    • Journal of Periodontal and Implant Science
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    • 제39권2호
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    • pp.149-156
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    • 2009
  • Purpose: Deproteinized bovine bone substitutes are commonly used in dental regenerative surgery for treatment of alveolar defects. In this study, three different bovine bone minerals - OCS-B (NIBEC, Seoul, Korea), Bio-Oss (Geistlich - Pharma, Switzerland), Osteograft/N - 300 (OGN, Dentsply Friadent Ceramed. TN, USA) - were investigated to analyze the basic characteristics of commercially available bone substitutes. Methods: Their physicochemical properties were evaluated by scanning electron microscopy, energy dispersive X-ray spectrometer (EDS), surface area analysis, and Kjeldahl protein analysis. Cell proliferation and alkaline phosphatase (ALP) activity of human osteosarcoma cells on different bovine bone minerals were evaluated. Results: Three kinds of bone substitutes displayed different surface properties. Ca/P ratio of OCS - B shown to be lower than other two bovine bone minerals in EDS analysis. Bio-Oss had wider surface area and lower amount of residual protein than OCS - B and OGN. In addition Bio - Oss was proved to have lower cell proliferation and ALP activity due to lots of residual micro particles, compared with OCS - B and OGN. Conclusions: Based on the results of this study, three bovine bone minerals that produced by similar methods appear to have different property and characteristics. It is suggested that detailed studies and quality management is needed in operations for dental use and its biological effects on new bone formation.

전기 이중층 커패시터 적용을 목적으로 한 공용매상 전해액과 전기화학적 특성 (Enhance Potential Stability of Organic Electrolyte in EDLC by Using Co-solvent and Its electrochemical properties.)

  • 이현석;육영재;김한주;박수길
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2014년도 추계학술대회 논문집
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    • pp.164-164
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    • 2014
  • Characteristics of electrolyte are those; electrical stability, ion conductivity, viscosity, high temperature work, cell application. Theoretically, GBL has high oxidation voltage. Also, boiling point of GBL is $206^{\circ}C$ and flash point is over $280^{\circ}C$.

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도금액 관리에 관한 조사연구 (Studies on Control of Gilding Liquid)

  • 신종철;박광자;이성주;이종용
    • 한국표면공학회지
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    • 제10권1호
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    • pp.1-18
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    • 1977
  • To support the domestic plating industry concerning localized products, survey was conducted in with chemicals and properties of plating solution. Collected samples from 55 factories throughout the country were investigated by spectigated by spectrograph, Hull cell test chemical analysis method to find major chemical components of the plating solution.

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고분자전해질 연료전지용 분리판의 적용을 위한 그라핀이 코팅된 알루미늄 합금의 전기화학적 특성 (Electrochemical properties of graphene coated aluminium alloy for PEM fell cell separator)

  • 남대근;김정수;조형호
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2011년도 춘계학술대회 및 Fine pattern PCB 표면 처리 기술 워크샵
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    • pp.36-36
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    • 2011
  • 고분자 전해질 연료전지용 분리판은 가격비와 중량비가 높아 부품 가격 및 중량을 낮출 경우 파급 효과가 높을 것으로 예상된다. 일반적인 금속판들은 연료전지 스택 내의 산성 분위기에서 존재하므로 표면 부식이 쉽게 발행한다. 본 연구에서는 연료전지의 사용환경을 고려하여 금속판의 부식방지 및 표면특성 향상을 위해 그라핀을 코팅하였으며, 연료전지 스택 내부와 유사한 산화성 분위기를 모사하여 전기화학적 특성을 분석하였다.

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The $Al_2O_3$ Passivation Mechanism for c-Si Surface Deposited by ALD Using $O_3$ Oxidant

  • 조영준;장효식
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제45회 하계 정기학술대회 초록집
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    • pp.320.1-320.1
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    • 2013
  • We have investigated the effect of surface passivation for crystalline silicon solar cell using ozone-based atomic layer deposited (ALD) $Al_2O_3$. We examined passivation properties such as uniformity, carrier lifetime, thickness, negative fixed charge density at AlOx/Si interface, and reflectance. The influences of process temperature and heat treatment were investigated using microwave photoconductance decay (PCD). Ozone-based ALD $Al_2O_3$ film shows the best carrier lifetime at lower deposition temperature than $H_2O$-based ALD.

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Evaluation of ENEPIG Surface Treatment for High-reliability PCB in Mobile Module

  • Lee, Joon-Kyun;Yim, Young-Min;Seo, Jun-Ho
    • 한국표면공학회지
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    • 제43권3호
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    • pp.142-147
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    • 2010
  • We evaluated characteristics of ENEPIG (Electroless Nickel Electroless Palladium Immersion Gold) surface treatment for mobile equipment that requires high reliability, in addition to investigating surface treatment processes for semiconductor boards that require high reliability such as regular PCB-package systems, board-on-chip, chip-scaled package (CSP), etc and application for semiconductor package board of SIP, BOC. As a result, it appeared that ENEPIG has superior properties compared to ENIG surface treatment in corrosion resistance, solder junction, wetting, etc. We anticipate that these results will be able to lend credibility to ENEPIG as a low-cost alternative for producing mobile devices such as the cell phones, especially when applied to mass production.

염료감응형 태양전지의 상대전극 재료로서 탄소나노튜브의 전기화학적 특성 (Electrochemical Properties of Carbon Nano-tube as the Counter Electrode of Dye-sensitized solar cell)

  • 김현주;이동윤;구보근;이원재;송재성;이대열
    • 한국전기전자재료학회논문지
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    • 제17권10호
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    • pp.1090-1094
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    • 2004
  • Studies on porous oxide electrode, dye and electrolyte for dye-sensitized solar cells have been intensively carried out until now. However, counter electrode have not been much studied so far. Accordingly, it is needed to investigate new counter electrode materials with superior catalyst property and to substitute for Pt electrode. In this case, carbon nano-tubes (CNTs) are one of alternatives for counter electrodes as following merits: low resistivity, excellent electron emission property, large surface area and low cost due to development of mass production technique. Such advantages gave us to select multiwalled CNTs (MWCNT) as counter electrode for dye-sensitized solar cell. Also, cyclic voltammetry and impedance spectroscopy were used to investigate electrochemical properties of both CNT electrode and Pt electrode. It was found that sheet resistance of CNT electrode was similar to that of Pt electrode, also, electrochemical properties of CNT electrode was superior to that of Pt electrode on the basis on the measurement of CV and impedance spectrum. It was found that CNT is likely to be a very promising electrode material for dye solar cells.