• Journal of the Korean Ceramic Society
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• v.45 no.12
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• pp.755-759
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• 2008

New cathode materials $LaNi_{1-x}{Cu_x}{O_3}$ (typically $LaNi_{0.8}Cu_{0.2}O_3$) were synthesized using a co-precipitation method. The structure and morphology of the powders were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The composite material [$Ce_{0.8}Sm_{0.2}O_{2-\ddot{a}}$(SDC) and carbonate (${Na_2}{CO_3},{Li_2}{CO_3}$)], NiO and $LaNi_{1-x}{Cu_x}{O_3}$ were used as the electrolyte, anode and cathode, respectively. The electrochemical performance of La-Ni-Cu-O perovskite oxide at low temperatures ($400{\sim}550^{\circ}C$) was studied. The results showed that $LaNi_{0.8}Cu_{0.2}O_3$ precursor powder prepared through a co-precipitation method and calcined at $860^{\circ}C$ for 2 h formed uniform grains with diameters in the range of $400{\sim}500\;nm$. The maximum power density and the short circuit current density of the single cell unit at $550^{\circ}C$ were found to be $390\;mW/cm^2$ and $968\;mA/cm^2$, respectively.

• Korean Chemical Engineering Research
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• v.54 no.4
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• pp.459-464
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• 2016

In this study, the electrochemical characteristics of porous silicon/carbon composite anode were investigated to improve the cycle stability and rate performance in lithium ion batteries. In this study, the effect of TEOS and $NH_3$ concentration, mixing speed and temperature on particle size of nano silica was investigated using $St{\ddot{o}}ber$ method. Nano porous Si/C composites were prepared by the fabrication processes including the synthesis of nano $SiO_2$, magnesiothermic reduction of nano $SiO_2$ to obtain nano porous Si by HCl etching, and carbonization of phenolic resin. Also the electrochemical performances of nano porous Si/C composites as the anode were performed by constant current charge/discharge test, cyclic voltammetry and impedance tests in the electrolyte of $LiPF_6$ dissolved inorganic solvents (EC:DMC:EMC=1:1:1vol%). It is found that the coin cell using nano porous Si/C composite has the capacity of 2,006 mAh/g and the capacity retention ratio was 55.4% after 40 cycle.

• Korean Chemical Engineering Research
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• v.49 no.1
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• pp.10-14
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• 2011

The electrode material performances of electric double layer capacitor(EDLC) were investigated using mesopous active carbon fiber(ACF), which was prepared by the iron exchange method. The mesoporous ACF had pore characteristics of specific surface area around 1249, 664 $m^2$/g, mesoporous fraction around 70.6-81.3% and meanpore size around 2.78-4.14 nm. The results showed that as HNO3 treatment time decreased, the specific surface area increased and mesoporous fraction decreased. To investigate electrochemical performance of EDLC, unit cell was manufactured using mesoporus ACF, conducting material and binder; organic elctrolyte was used on this experiment. The specific capacitance of ACF treated with HNO3 for 2 hours turned out to be 0.47 $F/cm^2$and the results of the cyclic charge-discharge tests were stable. Thus, the electrochemical performance of EDLC was mainly dependent on specific surface area of ACF electrode and the diffusion resistance of charge decreased as the mesopore increased.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.38B no.4
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• pp.229-239
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• 2013

Recently, device-to-device (D2D) communications have been highlighted to improve the spectral efficiency and offer various user experiences in cellular networks. In this paper, we survey standards and literatures related to the D2D technology and address various advantages of D2D technology, and the problems to be resolved before practically implemented. Especially, by considering an important interference issue between cellular and D2D links, five resource allocation and interference management scenarios are provided and their performances are evaluated through the system level simulations. The simulation results show that the use of D2D significantly improve the cell capacity and the D2D user rate due to the effects of frequency reuse and data off-loading. Notably, it is also shown that an optimal D2D communication range exists to maximize the system performance.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.24 no.12A
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• pp.1852-1861
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• 1999

In this paper, CDMA Reservation ALOHA scheme which can reduce multiple access interference and packet collision is proposed to support multi-traffic such as voice and random data with and without priority. In this scheme, the time slot is divided into two stage, access and transmission stage. Only packets with spreading codes assigned from base station in access stage can transmit their packets in transmission stage, so MAI can be reduced. To reduce packer collision in access stage, the code reservation and access permission probability are used. Code reservation is allowed for voice traffic and continuous traffic with priority using piggyback and access permission probability based on the estimation of the number of contending users in the steady-state is adaptively applied to each traffic terminal. Also, we analyzed and simulated the numerical performances required for each traffic using Markov chain modeling in a single cell environment.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.23 no.6
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• pp.1514-1525
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• 1998

Two main characteristics of VBR MPEG video traffic are different statistics according to different picture types and the periodic traffic pattern due to GOP structure. Especially, the I-pictures at the beginning of each GOP generate $$\mu$h more traffic than other pictures. When several VBR Mpeg video sources are superposed, the I-picture starting times of these sources may significantly affect the cell loss characteristics of ATM $$\mu$tiplexers. In this paper, we propse a performance model for ATM $$\mu$tiplexers with VBR MPEG video sources whose starting times are arbitrary given. For analysis, both single and superposed source traffic are modeled as NDPPs (non-deterministic periodic processes), and the ATM $$\mu$tiplexer is modeled as a U-state NDPPD/D/1/B queueing system. It is hown that the numerical results are very close to the si$$\mu$ation results. From the relationships between the starting tiem distributions and the corresponding $$\mu$tiplexer performances, some considerations for designing a scheduling policy in order to obtain the maxi$$\mu$ $$\mu$tiplexing gain are presented.

• Membrane Journal
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• v.26 no.2
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• pp.141-145
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• 2016

Polymer electrolyte membranes (PEMs) are key components to determine electrochemical fuel cell performances, in addition to electrode materials. The PEMs need to satisfy selective transport behaviors to small molecules including gases and protons; the PEMs have to transport protons as fast as possible, while they should act as hydrogen barriers, since the permeated gas induces the thermal degradation of cathode catalyst, resulting in rapid electrochemical reduction. To date, limited tools have been used to measure how fast hydrogen gas permeates through PEMs (e.g., Constant volume/variable Pressure (time-lag) method). However, most of the measurements are conducted under vacuum where PEMs are fully dried. Otherwise, the obtained hydrogen permeance is easily changeable, which causes the measurement errors to be large. In this study, hydrogen permeation properties through Nafion212 used as a standard PEM are evaluated using an in-situ measurement system in which both temperature and humidity are controlled at the same time.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.38B no.5
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• pp.355-367
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• 2013

In the Policy and Charging Control(PCC) architecture of the 3GPP and WiMAX forum, the Policy and Charging Rule Function(PCRF) controls and configures the policies of quality of services(QoS) and accounting to a Policy and Charging Rule Enforcement Function(PCEF). In this paper, we categorize the errors into three types that include a disconnection with peer entity, a delayed or no response and a response with failure result, and propose a scheme to automatically synchronize the data between the PCRF and the PCEF for each type of error. Also, we conduct a quantitative analysis to see how much it can help to maintain the cell capacity of the mobile VoIP service in a WiBro network, which is implemented in Korea according to the standards of WiMAX. We can see that our proposed scheme improves the performances of PCC by preventing the waste of radio resources, the overload of systems, the memory leakage of servers, the system shutdown, and so on. We have validated the scheme by implementation, and reflected it in WiMAX standard documents.

• Journal of the Korean Electrochemical Society
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• v.7 no.4
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• pp.189-193
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• 2004

Lithium secondary battery with gel polymer electrolyte, which was composed of POAGA and TEGDMA, was prepared and its cell performances were evaluated. Collation time decreased with increasing the contents of the monomer in the POAGA-based gel polymer electrolyte. The polymer electrolyte was stable up to 4.5V electro-chemically and its ionic conductivity was $5.2\times10^{-3}Scm^{-1}$ at room temperature. The lithium-ion polymer battery with $3.0wt\%$ curable monomer and $1.0wt\%$ monomer showed rate-capability, low-temperature performance and cycleability.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.34 no.10
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• pp.885-891
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• 2010

Thermal management is important for enhancing the performance and durability of polymer electrolyte membrane fuel cells (PEMFCs) and is taken into account in the design of PEMFCs. In general, cooling pates with circulating liquid coolant (water) are inserted between several unit cells to exhaust the reaction heat from PEMFCs. In this study, computational fluid dynamics (CFD) simulations were performed to characterize the uniform cooling performance of parallel multipass serpentine flow fields (MPSFFs) that were used as coolant flow channels in PEMFCs. The cooling performances of conventional serpentine and parallel flow fields were also evaluated for the purpose of comparison. The CFD results showed that the use of parallel MPSFFs can help reduce the temperature nonuniformity, and thus, can favorably enhance the performance and durability of PEMFCs.