• Journal of Electrochemical Science and Technology
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• v.6 no.1
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• pp.26-33
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• 2015

In this study, cell performance and thermal stability of lithium-ion cells with a polyimide (PI) separator are investigated. In comparison to conventional polyethylene (PE) separator, the PI separator exhibits distinct advantage in microporous structure, leading to superior reliability of the cell. The cells with PI separator exhibit good cell performances as same as the cells with PE separator, but their reliability was superior to the cell with PE separator. Especially in the hot-box test at 150 and 180℃, PI separator showed a contraction percentage close to 0% at 150℃, while the PE separator showed a contraction percentage greater than 10% in both width and length. Therefore, the PI separator can be the promising candidate for separators of the next generation of lithium-ion battery.

• Journal of the Korean institute of surface engineering
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• v.40 no.3
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• pp.149-158
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• 2007

Of all components of MCFC(molten carbonate fuel cell), corrosion of separator is one of the most decisive factor for commercializing of MCFC. In order to provide better understanding of corrosion behavior and morphology for gas channel of separator plate, post-analysis after cell operation for 1200 hours at $650^{\circ}C$ was performed by optical microscope, SEM and EPMA. Intergranular corrosion was observed on gas channel of separator plate. Corrosion product layer was identified as Fe-oxide, Cr-oxide and Ni-oxide by EPMA, and oxide thickness was measured with a $60{\mu}m-150{\mu}m$. Also, gas channel of separator was damaged by severe intergrannular attack with post analysis in consistent with immersion test. Moreover, pitting on the channel plate was observed with a depth of $18{\sim}24{\mu}m$. The results of immersion method are well agreement with post analysis measurements.

• Journal of the Korean institute of surface engineering
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• v.48 no.5
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• pp.199-204
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• 2015

Recently, fuel cell is a good alternative for energy source. Separator is a important component for fuel cell. In this study, The surface of separator was modified for corrosion resistance and electric conductivity. Reduced graphene oxide (rGO) was made by Staudenmaier's method. Nickel, phosphorus and rGO were coated on 6061 aluminum alloy as a separator of proton exchange membrane fuel cell by composite electroless plating. Scanning electron microscope, energy-dispersive X-ray spectroscopy and X-ray photoelectron spectroscopy were used to examine the morphology of Ni-P-rGO. Surface images were shown that the rGO was dispersed on the surface of Ni-P electroless plating, and nickel was combined with the un-reduced oxygen functional group of rGO.

• 제어로봇시스템학회:학술대회논문집
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• 2004.08a
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• pp.68-71
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• 2004

Recently, a great deal of research and development of a fuel cell have been carried out to solve problems on the drain of fossil fuel, air pollution and global warning. In order to improve the efficiency of a fuel cell, it is necessary to clarify the flow in separator. In this study, distributions of velocity flow rate and pressure, and streamlines are examined in detail from numerical analysis with CFD code. In the experiment the distribution of flow rate is measured and flow in the each grooves of the separator is visualized by dye method changing Reynolds number. Furthermore, effects of size of the inlet and outlet manifolds and shape of ribs near the inlet outlet on the distributions of flow and pressure are examined.

• 한국신재생에너지학회:학술대회논문집
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• 2007.06a
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• pp.97-100
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• 2007

Fuel Cell Stack performance, which is influenced by the maintenance of a constant internal environment, requires high levels of air tightness. Used for analysis, gasket for fuel cell is made of elastic rubber materials and placed over separator, and shape of deformation of a gasket affects the transformation separator and airtightness while fastening structure. Separator as made of steel sheet isn't broken under pressure but can affect gas and cool water flow by the plastic deformation process. Therefore， it is understood that assembly process is well developed in case distribution of stress and shape of deformation is shown uniformly. This study is conducted on the assumption that a fuel cell maintenance is advantageous in that conditions. In this paper, analyses of unit cell and partial model were performed and distribution of stress and shape of deformation of Gasket and separator were analyzed to evaluate the airtightness while fastening structure.

• Transactions of the Korean hydrogen and new energy society
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• v.29 no.5
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• pp.442-449
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• 2018

Research on High temperature polymer electrolyte fuel cell (HT-PEMFC) has actively been conducted all over the world. Since the HT-PEMFC can be operated at a high temperature of $120-180^{\circ}C$ using phosphoric acid-doped polybenzimidazole (PBI) electrolyte membrane, it has considerable advantages over conventional PEMFC in terms of operating conditions and system efficiency. However, If the thermal distribution is not uniform in the stack unit, degradation due to local reaction and deterioration of lifetime are difficult to prevent. The thin plate separator reduces the volume of the fuel cell stack and improves heat transfer, consequently, enhancing the cooling effect. In this paper, a large area flow field of thin plate separator for HT-PEMFC is designed and sub-stack is fabricated. We have studied stack performance evaluation under various operating conditions and it has been verified that the proposed design can achieve acceptable stack performance at a wide operating range.

• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 2007.10a
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• pp.296-299
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• 2007

The focus of this study is to estimate the stiffness factor of the separator plate of MCFC (Molten Carbonate Fuel Cell) at the elevated temperature. The process factors affecting the stiffness of the separator plate were chosen to determine the most important factor using the finite element analysis with the Taguchi method. The most influential factor, picked out by the ANOYA, turned out the pitch in the separator plate.

• Journal of Advanced Marine Engineering and Technology
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• v.30 no.2
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• pp.231-238
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• 2006

The performance of free-breathing polymer electrolyte membrane fuel cell (PEMFC) was studied experimentally and the effect of cathode separator structure on the cell performance was investigated. Cathode separators were used for the cell with $18cm^2$ active area. In channel type, the contact resistance is low, and the nature convection. which is strongly affected by the cross-sectional shape of cathode separator channel, is dominant in a cell performance. The maximum power density with $18cm^2$ active area is $105mW/cm^2$ using the 10mm depth and 2mm width channel. A computational analysis was optimum structure of free-breathing channel type PEMFC for robotic application.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.20 no.11
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• pp.1000-1003
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• 2007

The molten carbonate fuel cell has conspicuous feature and high potential in being used as an energy converter of various fuel to electricity and heat. However, the molten carbonate fuel cell which use strongly corrosive molten carbonate at $650^{\circ}C$ have many problem. One of the material problems is the severe corrosion of the metallic components, such as the separator. The effect of coating and annealing treatment on the corrosion for SUS 304 and SUS 430 which are the candidate materials for molten carbonate fuel cell hardware has been investigated in molten carbonate at $650^{\circ}C$ by using steady state polarization and electrochemical impedance spectroscopy method. It was found that the corrosion current of these SUS 304 and SUS 430 decreased with coating and annealing treatment.

• Journal of the Korean Electrochemical Society
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• v.14 no.3
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• pp.171-175
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• 2011

Lithium secondary batteries using lithium metal count electrode are easy to use and to analyze the specific characteristics of working electrode. Nevertheless, during the charge operation internal electrical short circuit could be caused by the dendritic growth of lithium. The cell failure by the short circuit depends on the condition of separator such as constitutive material and thickness. To prevent the cell failure caused by the dendritic growth of lithium, the electrochemical properties of the cell of lithium metal count electrode were evaluated for four different kinds of separator. Among the tested separators, GMF (glass micro-fiber filter, $300{\mu}m$) was the most promising one because it could effectively prevent the cell failure during the charge. The cell using GMF separator had relatively low impedance. Generally the cell using thicker separator than $50{\mu}m$ could effectively avoid the cell failure by internal short circuit and had the good cycleability. The highest rate capability by the signature method was acquired in the case of GMF separator.