• Title/Summary/Keyword: CeO2

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A Study on the Photofade of Graft Copolymer (Part I) -for variance of whiteness- (Graft 공중합물의 광퇴색에 관한 연구(제1보) -백색도 변화에 대하여-)

  • Cho Kyung Rae
    • Journal of the Korean Society of Clothing and Textiles
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    • v.7 no.1
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    • pp.11-16
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    • 1983
  • Variance of whiteness after graft copolymerization of acrylonitrile, methylmethacrylate and acrylamide onto bleached cellulose using Ce(IV) salt as initiators and the effect of homopolymer on the grafted fibers by photo-irradiation were studied. Also, the development of Yellowing were determined after carbon-arc radiation in a Fade-o-meter. The results were as follows: (1) Variation of whiteness of grafted cellulose fibers were influenced by graft-ratio, Inorganic-Organic Balance (IOB) of functional group in used monomers and adhering homopolymers on the grafed fibers. (2) Yellowing was not affected by the concentration of Ceric Ammonium Nitrate directly during reaction (eg. 0.008>0.006>0.014 M).

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Steam Reforming of Biogas on Nickel Fiber Mat Catalysts (니켈 섬유 매트 촉매를 사용한 바이오가스 수증기개질 반응)

  • Bui, Quynh Thi Phuong;Kim, Yong-Min;Yoon, Chang-Won;Nam, Suk-Woo
    • Journal of Energy Engineering
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    • v.20 no.3
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    • pp.252-258
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    • 2011
  • Nickel fiber mat was investigated as a potential structured catalyst for steam reforming of biogas in the temperature range of $600-700^{\circ}C$. The activity of as-received catalyst was very low owing to the smooth surface of fibers. Pretreatment of the catalyst by oxidation followed by reduction under methane partial oxidation condition significantly improved the catalytic activity, although degradation of the activity was found during the reaction due to oxidation and sintering. This deactivation was retarded by supplying additional hydrogen in the inlet gases or by coating $CeO_2$ over the catalyst surfaces.

Superconductivity and physics (초전도와 물리학)

  • 오범환
    • Electrical & Electronic Materials
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    • v.9 no.3
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    • pp.304-309
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    • 1996
  • 본 고에서는 초전도에 관한 학문적 연구내용의 추이와 그 응용기술의 개발내용을 간략히 살펴보았다. 고온 초전도의 형성원리에 대한 학문적 관심과 응용기술 개발사이의 괴리를 이해하려는 노력의 일환으로 고온 초전도체를 주대상으로 한 각종 연구결과들을 소개하면서 순수학문과 공학기술과의 긴밀한 연관성을 찾았다. 전자와 정공의 도핑 대칭성을 확립한 Nd-Ce-Cu-O의 발견은 물성의 정확한 이해에 기초한 성공이었고, 산화물 고온 초전도체들의 전자쌍 파동함수의 대칭성에 관한 논의들에서 최근 연구의 주종을 이루고 있는 Josephson-coupling과 Photoemission등의 직관적인 결과를 주는 측정 실험들은 고도의 첨단기술과 죠셉슨 접합 등의 새로운 초전도 물성개념의 정확한 이해를 요하는 연구들이었다. 이러한 새로운 초전도 개념들의 토대위에 현 응용분야들의 추세를 대략 살핌으로써 부실하나마 미래의 차원 높은 수요에 대비한 학문적, 기술적 준비를 시도해 보았다.

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The Multi-layer Fabrication and Characteristic Performance for Dark Current Reduction of Amorphous Selenium (비정질 셀레늄의 누설전류 저감을 위한 다층구조 제작 및 특성 평가)

  • Park, J.K.;Kang, S.S.;Suk, D.W.;Lee, H.W.;Nam, S.H.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07b
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    • pp.849-852
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    • 2002
  • Recently, amorphous selenium is used as x-ray conversion material for flat-panel x-ray detector. In this paper, we investigated the effect of breakdown under high voltage and leakage current in PN-type multi-layer structure based on p-type a-Se and n-type conductive thin film. Experimental results show that the multi-layer based detector reduced leakage current because n-type CeO2 conductive layer prevent from hole injection into a-Se layer from collection electrode, Also, the breakdown voltage was improved by dielectric layer between a-Se and top electrode.

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Synthesis of (Y,Sm)BCOpowder and Fabrication of a single crystal using Polymeric Complex Method (착체중합법에 의한 (Y,Sm)BCO 분말합성과 단결정 제조)

  • 안재원;최희락;한영희;한상철;정년호
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07a
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    • pp.482-485
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    • 2002
  • We synthesize a (Y,Sm)BCO(its composition is (Y/Sm123+0.4Y/Sm211)+1wt%CeO$_2$) powders using polymeric complex method. (Y,Sm)BCO powders are prepared as heated at 970$^{\circ}C$. For measurement of this characterization, We measure XRD and SEM. We use TSMG method for fabricatlon of (Y,Sm)BCO single crystal. The manufactured VBCO single crystal is measured by a magnetic distribution device using 0.5 Tesla magnet. As the result of this measurement, we find that a trapped magnet fields are 550 Gauss.

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Surface polishing of Micro channel using Magneto-Rheological fluid (MR유체를 이용한 미세 채널구조물의 표면연마)

  • 이승환;김욱배;민병권;이상조
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2003.06a
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    • pp.1873-1876
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    • 2003
  • Magneto-rheological polishing is a new technology used in precision polishing. It utilizes magneto-rheological fluid. nonmagnetic polishing abrasive, aqueous carrier fluids in magnetic field to remove material from a part surface. Silicon micro channel as work piece is fixed in the slurry which is made of MR fluid and CeO$_2$(10 vol%) abrasive particles. And permanent magnet rotate in the slurry to transfers magnetic force to abrasive particles by increasing yield strength of MR fluid. so, the obtained bottom surface roughness of micro channel by experiment reduced to Ra 0.010 $\mu\textrm{m}$ Rmax 0.103 $\mu\textrm{m}$ and finwall surface roughness of micro channel reduced to Ra 0.018 $\mu\textrm{m}$ Rmax 0.468 $\mu\textrm{m}$. At optimum conditions of variables, the workpiece as silicon micro channel have about 24 times smaller surface roughness than before polishing.

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MCNP-4A와 CASMO-3를 이용한 CE 16$\times$16 핵연료집합체 임계도 및 봉출력 분포 해석

  • 김교윤;김강석;박찬오
    • Proceedings of the Korean Nuclear Society Conference
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    • 1995.10a
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    • pp.79-84
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    • 1995
  • 핵연료집합체 연소도 계산용 전산코드인 CASMO-3를 도입하여 한국고유핵설계체계를 개발하기 위해서는 CE형 핵연료집합체의 핵적특성을 파악하는 것은 필수적이다. 따라서, CASMO-3와 몬테칼로 전산코드인 MCNP-4A를 이용하여 CE형 16$\times$16 핵연료집합체에 대한 $K_{inf}$ 및 봉출력 분포를 비교 분석하였다. $K_{inf}$ 의 경우는 CASMO-3에 의한 계산 결과가 0.5% 이내에서 MCNP-4A의 계산 결과와 일치하였으며, 봉출력분포의 경우도 제어봉 주변이나 Gd$_2$O$_3$ 독봉을 제외하고는 CASMO-3에 의한 계산 결과가 MCNP-4A의 계산 결과와 거의 일치하는 것으로 나타났다.

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Effects of partial pressures of various gases on the qualities of long coated conductors fabricated in vacuum

  • Lee, Byoung-Su;Kim, Ho-Sup;Youm, Do-Jun
    • 한국초전도학회:학술대회논문집
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    • v.10
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    • pp.140-140
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    • 2000
  • The effects of partial pressures of various gases on the qualities of coated conductors are studied, where the long samples were fabricated in a vacuum of a large physical vapour deposition system. The various gases such as $0_25,$H_2$,H_20$,$C_n H_m$, and CO come out from the large heating system and gives somewhat complicated effects on the interfacial chemistry at CeO/Ni which Is Important for the epitaxial growth of the film. The results of XRD measurements on the films fabricated in the controlled partial pressures of thoes gases will be presented.

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Improvement of Oxide-Mechanical Polishing Characteristics According to the Ceria Abrasive Adding (세리아 연마제 첨가량에 따른 산화막 CMP 특성 고찰)

  • Han, Sang-Jun;Park, Sung-Woo;Lee, Woo-Sun;Sea, Yong-Jin
    • Proceedings of the KIEE Conference
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    • 2006.10a
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    • pp.87-88
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    • 2006
  • To investigate the possibility of ceria abrasive-added slurry for the oxide-chemical mechanical polishing (oxide-CMP) application, two kinds of retreated methods were introduced as follows: First, the characteristics of mixed abrasive slurry (MAS) using $CeO_2$ powder as an abrasive added within diluted silica slurry (DSS) were evaluated to achieve the improvement of removal rates and non-uniformity. Second, the control of pH level due to the dilution of slurry was examined. And then, we have discussed the CMP characteristics as a function of abrasive dispersion time.

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Antioxidant activity and comparative analysis of major functional compounds in liqueur using coffee and coffee-ground (커피와 커피박 침출주의 항산화 활성 및 주요 생리활성 물질의 비교 분석)

  • Kang, Jeong Eun;Park, Seon Kyeong;Guo, Tian Jiao;Kang, Jin Yong;Lee, Du Sang;Kim, Jong Min;Kwon, O-Jun;Lee, Uk;Heo, Ho Jin
    • Food Science and Preservation
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    • v.23 no.4
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    • pp.560-567
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    • 2016
  • Sensory evaluation, in vitro antioxidant activities and main compounds of coffee water-extract, coffee liqueur (CL) and coffee-ground liqueur (CGL) were investigated to consider their industrialization. Sensory evaluation showed that all groups of CGL without 25% CGL (3 month) were relatively higher than CL groups. Total phenolic compounds and in vitro antioxidant activities such as 1,1-diphenyl-2picryl-hydrazyl (DPPH) radical scavenging activity and ferric reducing/antioxidant power (FRAP) were also performed. The group of 35% CGL had higher total phenolic compounds than others, and the result of DPPH radical scavenging activity was similar to that of total phenolic compounds. In addition, 35% CGL is comparable to the FRAP of coffee water extract (CE). Qualitative and quantitative analysis using high-performance liquid chromatography (HPLC) were performed, and chlorogenic acid as a ployphenolic compound and caffeine as a nonpolyphenolic compound were detected in all samples. Moreover, the HPLC analysis showed that CGLs contain a larger amounts of chlorogenic acid (difference of 0.3~10.5%) and also greater amounts of caffeine (difference of 10.0~18.2%) more then CE. Consequently, these results suggest that coffee-ground as coffee by-products could be used as commercially available food substances because of its physiological molecules remained.