• Title/Summary/Keyword: Cation exchange capacity (CEC)

Search Result 184, Processing Time 0.027 seconds

Evaluation of the Removal Characteristics of Pollutants in Storm Runoff Depending on the Media Properties (여재 특성에 따른 강우 유출수 내 오염물질 제거특성 평가)

  • Kim, Tae-Gyun;Cho, Kang-Woo;Song, Kyung-Guen;Yoon, Min-Hyuk;Ahn, Kyu-Hong;Hong, Sung-Kwan
    • Journal of Korean Society of Environmental Engineers
    • /
    • v.31 no.7
    • /
    • pp.483-490
    • /
    • 2009
  • The aims of this study were to evaluate the removal efficiency for various pollutants in urban storm runoff by a filtration device, and to determine design parameters depending on filter media properties. Appropriate selection of filter media will affect the size and life time of the filtration device. Sets of column tests were performed in order to evaluate the removal efficiency by perlite and a synthetic resin. An investigation of surface properties including CEC (cation exchange capacity) and zeta-potential suggested that the perlite had a superior adsorption capability for cationic pollutants. TCODcr and turbidity were analyzed to investigate the removal characteristic of particulate pollutant. In both columns, the particles in the collected storm runoff was almost completely capture with a small EBCT (empty bed contact time) of 2.5 minutes. Complete clogging at the EBCT of 2.5 minutes occurred after 630 minutes in the perlite column and 810 minutes in the resin column. The removal efficiency of TCODcr and turbidity at the EBCT of 2.5 minutes decreased to below 70% due to an wall effect. The removal efficiency for dissolved pollutant (SCODcr) was negligible due to the insufficient contact time for adsorption. The removal of heavy metals (Cu, Zn, Pb) was mostly ascribed to the filtration of particles containing metals, since the relationship between CEC and the removal efficiency was not apparent. The result of this study would be valuable for the application of filtration device to control of urban storm runoff.

Growing Environment Characteristics and Vegetational Structure of Sageretia thea, Medicinal Plant (약용식물 상동나무 자생지 생육환경 특성과 식생구조)

  • Son, Yonghwan;Son, Ho Jun;Park, Gwang Hun;Lee, Dong Hwan;Cho, Hyejung;Lee, Sun-Young;Kim, Hyun-Jun
    • Korean Journal of Plant Resources
    • /
    • v.35 no.5
    • /
    • pp.594-606
    • /
    • 2022
  • This study was conducted to figure out the environment factors including vegetation structure and soil characteristics in natural habitats of Sageretia thea, and offers the basic information for habitats conservation and proliferation. The natural habitats of Sageretia thea were located at altitudes between 0~370 m with inclinations ranged as 3~35°. Through the vegetation research, the dominant species of tree layers were found to be divided into four communities. Cornus macrophylla (Com. I), Pinus thunbergii - Cinnamomum camphora (Com. II), Machilus thunbergii (Com. III), and Pinus thunbergii (Com. IV). The Species diversity (H') was 1.397~1.455, evenness (J') was 0.972~0.986, and dominance (D) was found to be 0.014~0.028. As a result of the physicochemical characteristics of soils, habitats soil mainly consisted of sandy soil and sandy loam soil. The average soil pH was 5.28~5.98, electronic conductivity was 0.22~63 ds/m, soil organic matter was 13.33~19.33 cmol+/kg, Exchange cations were appeared in the order of Ca2+, Mg2+, K+, and Na+. The Ordination result showed that Correlation coefficient between communities and environmental factors were significantly correlated with 4 main factors altitude, electronic conductivity, cation exchange capacity, exchangeable Na+. As expected, The result of this study will be helpful information on the preservation and mass production for use.

Characterization of Natural Zeolite for Removal of Radioactive Nuclides (방사성 핵종 제거를 위한 천연 제올라이트 특성 연구)

  • Kim, Hu Sik;Park, Won Kwang;Lee, Ha Young;Park, Jong Sam;Lim, Woo Taik
    • Journal of the Mineralogical Society of Korea
    • /
    • v.27 no.1
    • /
    • pp.41-51
    • /
    • 2014
  • The four natural zeolites collected in Pohang and Gyeongju area, Kyungsangbuk-do, Korea, were characterized by XRD, XRF, DTA, TGA, and CEC analysis. The primary species of these zeolite are heulandite, modenite, illite, and illite in Kuryongpo (Ku), Pohang (Po), Yangbuk-A (Ya-A), and Yangbuk-B (Ya-B) samples. The XRF analysis showed that the four zeolites contain Si, Al, Na, K, Mg, Ca, and Fe. Cation exchange capacity of Kuryongpo (Ku) zeolite was the highest compared to other zeolites. The adsorption capacities of Cs and Sr in the four natural zeolites were compared at $25^{\circ}C$. On the basis of adsorption data Langmuir and Freundlich adsorption isotherm model were confirmed. The equilibrium process was descried well by Langmuir isotherm model. This study shows that Ya-A zeolite is the most efficient for the $Cs^+$ and $Sr^{2+}$ ion adsorption compared to the other natural zeolites.

Impact of Environmentally-friendly Organic Agro-Materials on Chemical Properties of Remediated Soils (친환경 유기농자재 처리에 따른 정화토양의 개선 효과)

  • Kim, Dong-Jin;Ahn, Byung-Koo;Lee, Jin-Ho
    • Korean Journal of Organic Agriculture
    • /
    • v.21 no.4
    • /
    • pp.753-767
    • /
    • 2013
  • Soil contamination has continuously increased worldwide, thus the remediation for the contaminated soils has risen steadily. However, the consideration of ecological safety for the remediated soils and their agricultural uses has been very limited. Therefore, this study was to investigate the influences of selected environmentally-friendly agricultural materials, organic by-product fertilizer (OF), charcoal (CC), and biochar (BC), as soil conditioners for improving poor chemical properties of fuel-oil removed soil by land farming technique. Two different remediated soils, remediated soil A (RSA) and remediated soil B (RSB), were selected. Soil texture of both RSA and RSB was sandy loam. The chemical properties of RSA and RSB were as follows: soil pHs of 8.5 and 8.7, soil organic matter contents of 7.4 and 5.5g $kg^{-1}$, total nitrogen contents of 0.26 and 0.10g $kg^{-1}$, available phosphorus concentrations of 7.2 and 4.4mg $kg^{-1}$, and exchangeable calcium concentrations of 14.8 and $11.7cmol_c$ $kg^{-1}$, respectively. Results of the properties were not reached for the optimal values for cultivating crops that were recommended by National Academy of Agricultural Science at Rural Development Administration in Korea. However, after applying OF, CC, and BC, the chemical properties of soils were selectively improved, which were that soil organic matter content and available phosphorus concentration increased, whereas the soil pH were not changed. In particular, the chemical properties were positively changed more with the application of 5.0% biochar. Thus, continuous management of the remediated soils with applying the eco-friendly agricultural materials can improve the quality of reme-diated soils.

A Study on the Characteristics of Bentonites Produced in Korea (한국산 Bentonite의 특성(特性)에 관(關)한 조사연구(調査硏究))

  • Lee, Jae-Suk;Jung, Pil-Gyun;Choi, Dae-Ung
    • Korean Journal of Soil Science and Fertilizer
    • /
    • v.10 no.1
    • /
    • pp.69-74
    • /
    • 1977
  • This study has been conducted to identify physico-chemical and clay mineralogical characteristics of bentonites produced in Korea for the purpose of finding good quality bentonite for agricultural ure. The results are summarized as follows: 1. Bentonites are mainly composed of montmorillonite developed from tuffs in a lava flow. 2. Chemical properties of bentonites are: pH in $H_2O$(1:1), 7:cation exchange capacity, 60-96me/100g; content of $SiO_2$, 54-72%; ratio of $SiO_2$ to $Al_2O_3$, 4.1-10.0;oven dry loss of $H_2O$ is higher than the ingnition loss of $H_2O$. 3. The x-ray diffrection patterns of powder bentonites show peaks at $14-15{\AA}$, $4.4{\AA}$, and $2.5{\AA}$, and that of swellen one show $17{\AA}$ when treated with ethylene glycol. 4. Distribution areas of the good quality bentonites were (1) Dogu-Dong, Donghae-Myeon, Yeonil-Gun, Gyeongsangbug-Do (2) Hamyeon-Ri, Yangnam-Myeon, Weolseong-Gun, Gyeongsanbug-Do. (3) Joam-Ri, Gangdong-Myeon, Weolseong-Gun, Gyeongsangbug-Do. (4) Sanha-Ri, Gangdong-Myeon, Ulju-Gun, Gyeongsangnam-Do. (5) Sinhyeon-Ri, Gangdong-Myeon, Ulju-Gun, Gyeongsangnam-Do. (6) Yonghang-Ri, Pyeongchang-Myeon, Pyeongchang-Gun, Gangweon-Do.

  • PDF

Improvement of Verification Method for Remedial Works through the Suggestion of Indicative Parameters and Sampling Method (정화 보조지표와 시료 채취 방법 제안을 통한 토양정화검증 제도 개선 연구)

  • Kwon, Ji Cheol;Lee, Goontaek;Kim, Tae Seung;Yoon, Jeong-Ki;Kim, Ji-in;Kim, Yonghoon;Kim, Joonyoung;Choi, Jeongmin
    • Journal of Soil and Groundwater Environment
    • /
    • v.21 no.6
    • /
    • pp.179-191
    • /
    • 2016
  • In addition to the measurement of the concentration of soil contaminants, the new idea of indicative parameters was proposed to validate the remedial works through the monitoring for the changes of soil characteristics after applying the clean up technologies. The parameters like CFU (colony forming unit), pH and soil texture were recommended as indicative parameters for land farming. In case of soil washing, water content and the particle size distribution of the sludge were recommended as indicative parameters. The sludge is produced through the particle separation process in soil washing and it is usually treated as a waste. The parameters like water content, organic matter content, CEC (cation exchange capacity) and CFU were recommended as indicative parameters for the low temperature thermal desorption method. Besides the indicative parameter, sampling methods in stock pile and the optimal minimum amount of composite soil sample were proposed. The rates of sampling error in regular grid, zigzag, four bearing, random grid methods were 17.3%, 17.6%, 17.2% and 16.5% respectively. The random grid method showed the minimum sampling error among the 4 kinds of sampling methods although the differences in sampling errors were very little. Therefore the random grid method was recommended as an appropriate sampling method in stock pile. It was not possible to propose a value of optimal minimum amount of composite soil sample based on the real analytical data due to the dynamic variation of $CV_{fund{\cdot}error}$. Instead of this, 355 g of soil was recommended for the optimal minimum amount of composite soil sample under the assumption of ISO 10381-8.

Research Trends of Forest Liming and the Effects of Liming on Forest Ecosystems (산림 대상 석회 시용의 연구 경향과 산림생태계에 미치는 영향)

  • Kim, Jusub;Chang, Hanna;Roh, Yujin;Han, Seung Hyun;Son, Yowhan
    • Korean Journal of Environmental Biology
    • /
    • v.36 no.1
    • /
    • pp.50-61
    • /
    • 2018
  • The current study aimed to review the research trends on forest liming by age, country, and research topics, and seeks to summarize the effects of forest liming on soil, vegetation and water system in forest ecosystems. The recent goals of forest liming have been changed in response to changes in the acid deposition, and related studies have been mainly carried out in Europe and North America, where there is noted a massive forest decline, which was subsequently caused by acid rain. Most forest liming studies are noted to have focused on soil responses, however, the number of studies on the responses of vegetation and water system according to a literature review on the subject were relatively small. Meanwhile, forest liming influenced whole forest ecosystems through interaction between the soil, vegetation and water system as associated with the relevant regions. The changes in soil pH, base saturation, and cation exchange capacity by forest liming were noted as different depending on the soil layer and elapsed time after liming. The responses of vegetation to forest liming were shown in above- and below-ground plant growth and plant nutrient concentration, and also were noted to have varied depending on the available regional plant species and noted specific soil conditions. The chemical properties of the water system were changed similarly to those in the soil, leading to notable changes as seen in the planktons and available fish species in the region. Finally, these results could be used to plan further studies on forest liming, which would significantly benefit regional studies to promote the preservation of the species noted for protection in the region.

Treatment of Food Wastes by Vermicomposting (Vermicomposting에 의한 음식물 쓰레기의 처리)

  • Lee, Ju Sam;Kim, Man Joong;Kim, Nam Chun
    • Journal of the Korea Organic Resources Recycling Association
    • /
    • v.13 no.3
    • /
    • pp.51-62
    • /
    • 2005
  • The effects of the processing mixture of food wastes and various organic wastes when vermicomposted on earthworm(Eisenia foefida) growth, the cast production amounts and the chemical properties of casts were evaluated. The substrates used in this experiments were cow manure, pig manure sludge, fermented pig manure with sawdust, nightsoil sludge, and sewage sludge and were respectively mixed with food wastes at a ratios of 50:50(v/v). The control consisted of food wastes alone without other wastes. All of earthworm died in the food wastes 100%, therefore the process of food wastes alone by vermicomposting was impossible in this experiment. Worm cast produced sufficiently contained quantities of available phosphorus, exchangeable potassium, exchangeable magnesium, and cation exchange capacity. The increase of earthworm's biomass occured on the mixtures of food wastes and cow manure, fermented pig manure with sawdust. Dry weight of worm cast was the highest on the mixtures of food wastes and fermented pig manure with sawdust and the proportion of cast weight after vermicomposting was significantly the highest on the mixtures of food wastes and cow manure($p{\leq}0.05$). Also, the mixtures of food wastes and cow manure, and fermented pig manure with sawdust showed a positive values of conversion rate and conversion efficiency rate of organic matter to earthworm tissue than that of other treatments. These results suggested that cow manure and fermented pig manure with sawdust are adequate to process with food wastes by vermicomposting.

  • PDF

Effects of a Biological Amendment on Chemical and Biological Properties and Microbial Diversity in Soils Receiving Different Organic Amendments (각기 다른 유기물이 투여된 토양에서 토양의 화학적, 미생물학적 특성과 미생물의 다양성에 미치는 생물비료의 효과)

  • Park, Kee-Choon;Kremer, Robert J.
    • Korean Journal of Soil Science and Fertilizer
    • /
    • v.40 no.4
    • /
    • pp.234-241
    • /
    • 2007
  • Biological amendments consisting of suspensions of selected microorganisms are often used in conjunction with various organic materials for amending soils to improve soil quality and plant growth. The effects of the biological amendment on chemical and biological properties of soil were investigated for a biological amendmentalone and when combined with different organic materials includingmunicipal compost (MC), poultry litter (PL), and cover crops (red clover (RC) and spring oats). A liquid preparation of a biological amendment called Effective Microorganisms was sprayed on the tested plots three times over a two-year period. Effective Microorganisms alone did not influence pH, K, or organic matter content in soil. However, increases in P in PL-treated soils in fall of both years andCa in MC-treated soil in fall 2001, and decreases in Ca, Mg, and cation exchange capacity (CEC) in RC-planted soil were associated with EM. Increased dehydrogenase(DH) activitiesassociated with Effective Microorganismswere only detected in July (P=0.0222) and October (P=0.0834) for RC-planted soils in the first year. Fluorescein diacetate (FDA) hydrolysisappeared to be enhanced by Effective Microorganisms in soils untreated or treated with MC and oatsbut only sporadically during the sampling period. FDA hydrolysis in both PL- and RC-treated soils as well as DH activity in PL-treated soils decreased with Effective Microorganisms treatment. Effective Microorganisms did not influence substrate utilization patterns expressed by the BIOLOG assay. We conclude that Effective Microorganisms effects on soil chemical and biological properties varied depending on the added organic materials. Effective Microorganisms periodically increased soil DH activity and FDA hydrolysis with RC and with MC plus oats, respectively.

Habitat Environment of Epimedium koreanum Nakai (삼지구엽초(三枝九葉草) 자생지(生地生) 환경(環境) 특성(特性))

  • Park, Kyeong-Yeol;Choi, Byoung-Ryourl;Yi, Eun-Sub;Kim, Sun-Jae;Park, Cheol-Ho
    • Korean Journal of Medicinal Crop Science
    • /
    • v.6 no.1
    • /
    • pp.51-56
    • /
    • 1998
  • This study was carried out to evaluate environmental and ecological characteristics of natural habitat for cultivation of Epimedium koreanum. Habitat of E. koreanum was the slope foot of mountain descending gradually toward mostly northwest from top of mountain with slope of $2{\sim}20%$ and the altitude ranged from 60 to 400m above the sea level. Some physiochemical characteristics of habitat soil were as follows: pH, $4.1{\sim}5.8$, organic matters content, $4.9{\sim}6.6%$ and cation exchange capacity, $14.8{\sim}34.3\;me/100g$ soil, respectively. Habitats were shaded by deciduous broad-leaved tree mainly, and compared with those of naked area, relative photon flux density was $3.5{\sim}13.1%$ and relative luminance was $3.3{\sim}11.9%$ due to shading. Air temperature of habitat under shade was $4.3{\sim}6.5^{\circ}C$ lower than that of naked area. Habitat soil temperature was lower than that of naked area but temperature range was smaller than that of naked area. E. koreanum plants were growing with semishading plants under shade of tree leaf. From investigation of natural characteristics of habitat, it was concluded that E. koreanum plant would grow at place with a little change in temperature and moisture of soil which was caused by shading and mulching with litterfall of broad-leaved tree.

  • PDF