• Title/Summary/Keyword: Cation

Search Result 2,611, Processing Time 0.03 seconds

Natural Zeolities (제오라이트 광물(鑛物))

  • Sang, Ki Nam
    • Economic and Environmental Geology
    • /
    • v.9 no.3
    • /
    • pp.165-168
    • /
    • 1976
  • Zeolites are aluminosilicates with a three dimensional framework structure enclosing pores occupied by cation and water molecules, both of which have considerable freedom of movement within certain limits. The ability of zeolites to exchange cation is one of the mere useful of their characteristics. The ion exchange condition of zeolites strongly affects absorption as well as other properties. The application, techniques of identification and evaluation of clinoptilolite, chabazite, mordenite and phillipsite are reviewed.

  • PDF

Preparation and Physical Characterizations of Superparamagnetic Maghemite Nanoparticles

  • Yoon, Sunghyun
    • Journal of Magnetics
    • /
    • v.19 no.4
    • /
    • pp.323-326
    • /
    • 2014
  • Superparamagnetic maghemite nanoparticles were prepared by chemical co-precipitation, followed by a temperate oxidation stage, and investigated using FE-SEM, XRD, TGA, VSM, and M$\ddot{o}$ssbauer spectroscopy. Through SEM image and XRD analysis, its average particle size was found to be 13.9 nm. While VSM magnetic measurement showed typical superparamagnetic behavior at room temperature, M$\ddot{o}$ssbauer spectroscopic investigation revealed that non-vanishing magnetic hyperfine structure were retained. Cation distribution estimated from M$\ddot{o}$ssbauer spectroscopy confirmed the formation of maghemite nanophase in the sample.

Determination of Cation Charge Density in Mica-type Layered Aluminosilicates by N-alkylammonium Method (N-alkylammonium법에 의한 Mica형 층상 규산 알루미늄의 양이온 전하 밀도의 측정)

  • 최진호;박중철;김창은;이창교
    • Journal of the Korean Ceramic Society
    • /
    • v.22 no.4
    • /
    • pp.3-8
    • /
    • 1985
  • The layer charge densities and interlayer C. E. C(cation exchange capacity) of ten mica-type aluminosilicates from Yong-il Pohang-prefacture were determined by n-alkylammonium method which is based on the mo-nolayer-doubelelayer structural transition of ni-alkylammonium ion in interlayer space of the layered silcates. The upper and lower limits of layer charge and interlyer C, E, C estimated were about 0.25~0.36 eq/(Si, $Al)_4$ O10 and 69~99meq/100g, respectively.

  • PDF

Intercalation of Ca-montmorillonite with Decylammonium Ion and n-Alcanol (Decylammonium 이온과 n-Alcanol 분자에 의한 Ca-montmorillonite의 Intercalation)

  • 최진호;김창은;형경우
    • Journal of the Korean Ceramic Society
    • /
    • v.20 no.3
    • /
    • pp.205-210
    • /
    • 1983
  • The determination of charge density and charge distribution in montmorillonite are discussed. The method is based on cation exchange of the inorganic interlayer cations against decylammonium ion and molecular intercalation of n-alcanol. The results obtained from Yougil-bentonite show that charge density of 0.37 per unit formula and cation exchange capacity of 102.5 meq/100g.

  • PDF

Synthesis of Analcime by Treating of Domestic Feldspar (국산 장석으로부터의 Analcime합성)

  • 김면섭
    • Journal of the Korean Ceramic Society
    • /
    • v.14 no.1
    • /
    • pp.7-11
    • /
    • 1977
  • Domestic Anyang feldspar was treated in autoclave with 1N sodium hydroxide solution for 1-6 hrs at 100-20$0^{\circ}C$ By X-ray diffraction patterns and cation exchange capacity, the products were examined. The following concecutive reaction was valid. AlbitelongrightarrowAmorphous aluminosilicatelongrightarrowAnalcime The reaction rate constants, k1 and k2, were 0.20 and 0.15(1/hr) at 20$0^{\circ}C$ respectively. The activiation energy from albite to amorphous aluminosilicate was 10 kcal/mol, and from amorphous aluminosilicate to analcine 13 kcal/mol. The analcime obtained was excellent in cation exchange capacity, amounting to 210meq./100g.

  • PDF

Biophysical Characteristics of $Mg^{2+}$ Blockades in Ion Channels and Their Physiological Roles

  • Park, Chul-Seung
    • Proceedings of the Korean Biophysical Society Conference
    • /
    • 1999.06a
    • /
    • pp.26-27
    • /
    • 1999
  • Ionic currents through many different cation channels are specifically reduced by internal and/or external $Mg^{2+}$ within a concentration range of physiological relevance. Although there are many ways for a divalent cation to reduce channel currents, the current blockade by directly binding to a conduction pore has been most well studied.(omitted)

  • PDF

Medium effects on the H-Atom Abstraction and Silyl-Transfer Photoreactions of Silylalkyl Ketones

  • Oh, Sun-Wha
    • Journal of Photoscience
    • /
    • v.12 no.1
    • /
    • pp.47-50
    • /
    • 2005
  • Mediumeffects have been explored on the competitive H-atom abstraction and SET-promoted, silyl-transfer reactions of excited states of silylalkyl-substituted phenyl ketones. The chemical selectivities of photochemical reactions of silylalkyl phenyl ketones appear to depend on medium polarity, medium silophilicity, added metal cation and alkyl length. Irradiations of silylalkylketones in aqueous solvent system and in presence of metal cation such as $Li^+$ and $Mg^{+2} $lead to formation of acetophenone predominantly by the sequential SET-silyl transfer route.

  • PDF

Direct Observation of an Antihomoaromatic Bicyclooctadienyl Cation

  • Shin Jung-Hyu
    • Bulletin of the Korean Chemical Society
    • /
    • v.3 no.2
    • /
    • pp.66-70
    • /
    • 1982
  • The question of the bicyclohomoaromatic stabilization and destabilization is examined. The chemistry of bicyclo(3.2.1)octa-3,6-dienide anion has been studied on order to test these concepts. The bicyclooctadienide anion is shown to be stable delocalized ion which undergoes a facile proton-deuterium exchange reaction. The solvolysis of bicyclo(3.2.1)octa-3,6-dienyl p-nitrobenzoate is much slower than the monoene analog. We have made direct observation of the bicyclooctadienyl and octenyl cations by $^{19}F$-nmr spectroscopy, and were able to demonstrate that the bicyclooctadienyl cation was bishomoantiaromatic.