• Title/Summary/Keyword: Cathodic protection method

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Optimum Cathodic Protection for Stainless Steel Shaft of Small-Size Boat (소형선박용 스테인리스강 축의 음극방식 응용)

  • Bae, I.Y.;Park, J.D.;Kang, D.S.;Lee, M.H.;Kim, K.J.
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2005.11a
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    • pp.232-233
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    • 2005
  • Stainless steel has been stably used closed by passivity oxidation films($Cr_2O_3$) is made by neutral atmospheric environment. However, passivity oxidation films of the surface of stainless steel occasionally comes to be destroyed in seawater which is influenced by an environment having halogen ion like $Cl^-$, then, localization corrosion comes to occur. Stainless steel 304 for shaft system material of the small-size FRP fishing boat on seawater environments made an experiment on simulation of sacrifical anode(Al, Zn). Through these experiment and study, following results have been obtained ; According to the field inspection and corrosion simulation, the corrosion on the 2nd class stainless steel shaft(STS 304) in FRP fishing boat has been verified to occur by crevice corrosion and galvanic corrosion etc.. According to the comparison and analysis of Stainless steel 304 shaft materials after simulation leaving unprotected and applying cathodic protection, unprotected shaft specimen of stainless steel 304 was severely corroded, but, protected shaft specimen was not totally corroded. This result is assumed to be made by the facts that anodic reaction, $Fe{\rightarrow}Fe^{2+}$ + $2e^-$, has been restricted by the cathodic protection current of sacrificial anode material.

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Fundamental Study on Cathodic Protection and Material Development as Erosion-Control Methods of Oceanic Centrifugal Pump(1) (해상용 원심펌프 임펠러의 침식억제법으로 음극방식 및 재료개발에 관한 기초연구 1)

  • 이진열;임우조
    • Journal of Advanced Marine Engineering and Technology
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    • v.19 no.2
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    • pp.56-66
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    • 1995
  • Recently, with theraped advancement in th oceanology such an ocean-going vessel and oceanic structures, there is a need to study the cavitation erosion-corrosion control of pump impeller, the partial element of ocean machinery, for more effective operation. Especially, the cathodic protection (impressed current method & Al-sacrificial anode method) was applied to sea water, and Cu-alloy material mixed Zn & Al was used as a control method of cavitation erosion-corrosion. In this study, used the piezoelectric vibrator with 20KHz, 24.mu.m to cavity generation apparatus, and investigated the weight loss, weight loss rate, electrode potential & current density etc. under this condition. According to test result, thos describes how to indentify an influence of the cathodic protection and Al & Zn addition in material development for the control of cavitation erosion-corrosion, and those will serve as fundamental data on the cavitation erosion-corrosion control of oceanic centrifugal pump.

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Properties Analysis of Environment Friendly Coating Films Formed by Using Electrodeposition Principle on Seawater (해수환경중 전착원리에 의해 형성시킨 환경친화적인 코팅막의 특성 분석)

  • Baek, S.M.;Lee, C.S.;Kim, K.J.;Moon, K.M.;Lee, M.H.
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2005.11a
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    • pp.196-197
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    • 2005
  • Cathodic protection is one of the successful ways to prevent corrosion of steel structures in marine environments. The unique feature of cathodic protection in seawater is the formation of calcareous deposits on cathodic metal surface. The formation principles of calcareous deposit seawater had been known for a long time. That is, cathodic reduction reactions associated with cathodic protection in seawater generate $OH^-$ at the metal surface in accordance with the formular ; 1/2 $O_2$ + $H_2O$ + $2e^-$ $2OH^-$ and $2H_2O$ + $2e^-$ ${\rightarrow}$ $H_2$ + $2OH^-$. These reactions increase the pH at the metal / seawater interface. The high pH causes precipitation of $Mg(OH)_2$ and $CaCO_3$ in accordance with the formular ; $Mg^{2+}$ + $2(OH)^-$ ${\rightarrow}$ $Mg(OH)_2$ and $Ca^{2+}$ + $HCO_3^-$ + $OH^-$ ${\rightarrow}$ $H_2O$ + $CaCO_3$. These are typically the main compounds in calcareous deposits. It obviously has several advantages compared to the conventional coatings, since the environment-friendly calcareous deposit coating is formed by the elements($Mg^{2+}$, $Ca^{2+}$) naturally present in seawater. In this study, environmental friendly calcareous deposit films were prepared on steel plates by electro plating technic in natural seawater. The influence of current density on composition ratio, structure and morphology of the coated films were investigated by scanning electron microscopy formation process of calcareous deposits films in natural seawater. And we confirmed the properties of all the films can be improved greatly by controlling the material structure and morphology with effective use of the electroplating method in natural seawater.

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A Case Study(1) of Mitigation Methode of DC Stray Current for Underground Metallic Structures in KOREA (국가기간시설물의 전식대책(안) 및 그 적용 사례(1))

  • Bae, Jeong-Hyo;Ha, Yoon-Cheol;Ha, Tae-Hyun;Lee, Hyun-Goo;Kim, Dae-Kyeong
    • Proceedings of the KIEE Conference
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    • 2007.07a
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    • pp.1612-1614
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    • 2007
  • The owner of underground metallic structures (gas pipeline, oil pipeline, water pipeline, etc) has a burden of responsibility for the corrosion protection in order to prevent big accidents like gas explosion, soil pollution, leakage and so on. So far, Cathodic Protection(CP) technology have been implemented for protection of underground systems. The stray current from DC subway system in Korea has affected the cathodic protection (CP) design of the buried pipelines adjacent to the railroads. In this aspect, KERI has developed a various mitigation method, drainage system through steel bar under the rail, a stray current gathering mesh system, insulation method between yard and main line, distributed ICCP(Impressed Current Cathodic System), High speed response rectifier, restrictive drainage system. We installed the mitigation system at the real field and test of its efficiency in Busan and Seoul, Korea. In this paper, the results of field test, especially, distributed ICCP system is described.

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A Study on the Standardization for Cathodic Protection System and its Testing Method in Korea (국내 전기방식 시스템 및 시험 방법에 대한 표준화 연구)

  • Bae, Jeong-Hyo;Ha, Tae-Hyun;Lee, Hyun-Goo;Kim, Dae-Kyeong
    • Proceedings of the KIEE Conference
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    • 2001.07b
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    • pp.663-665
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    • 2001
  • Generally, the owners of the facilities adopt CP(Cathodic Protection) Systems to protect the corrosion accidents previously. The developed countries have secured the standard of CP systems and its test methods through the various researches and consolidation of the rules. So, we have been studying the international standards; JSEC, NACE Standard, ASTM, DNV, Australian Standard etc. and standardizing the systems and its test methods to apply in Korea.

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A Study on Monitoring of Mitigation of Rail Corrosion using Sacrificial Anode Cathodic Protection Method (희생양극법을 적용한 철도 레일의 방식효과 모니터링 연구)

  • Choi, Jung-Youl;Park, Jong-Yoon;Lee, Kyu-Yong;Chung, Jee-Seung
    • The Journal of the Convergence on Culture Technology
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    • v.5 no.4
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    • pp.367-371
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    • 2019
  • In this study, we proposed the sacrificial anode cathodic protection method as a countermeasure to reduce the corrosion of railway rails under oceanic climatic conditions and proved the anticorrosive effect experimentally. In addition, the proposed sacrificial anode cathodic protection method were tested on site to examine long-term rail corrosion monitoring and field applicability for more than 26 months and to prove the effectiveness of rail corrosion. As a result of monitoring the corrosion state using the cellophane tape method, the appearance of the applied sections with sacrificial anode cathodic protection method was good at the present time about 26 months after the field test laying, and no abnormalities and other abnormalities of the rail welded section and the rail web were found. Hence, in places where no sacrificial anodes were installed, rust progressed rapidly. In addition, the proper spacing of sacrificial anodes was found to form the most stable corrosion coating at 1.0 ~ 1.5m. After about 26 months of monitoring, the installation of sacrificial anodes could help stabilize the overall rail corrosion level, even if the spacing was somewhat wider.

Evaluation of Scc Susceptibility of Welded HAZ in Structual Steel(II) -Frcature Behavior in Cathodic Protection- (강 용접부의 응력부식크랙 감수성 평가에 관한 연구 II -음극방식에서의 파괴거동-)

  • 임재규;조정운;나의균
    • Journal of Welding and Joining
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    • v.11 no.3
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    • pp.61-74
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    • 1993
  • The cause of corrosion failure found in structures or various components operating in severe corrosive environment has been attributed to stress corrosion cracking(SCC) which is resulting from the combined effects of corrosive environments and static tensile stress. Cathodic protection is an electrochemical method of corrosion control that is widely used in marine environment and primarily on carbon steel. A number of criteria are used to determine whether or not a structure is cathodically protected. In practice, -0.8V versus Ag/AgCl is the most commonly used for marine structures. This paper showed the combined effects of cathodic potential and slow, monotonic straining on the tensile ductility and fracture morphology of parents and friction welded joints for SM45C, SCM440 and SM20C steels in syntheic sea water(S.S.W.,pH:8.2). For the parent materials in cathodic potentials, the higher tensile strength is, the more susceptible SCC is. And the welded HAZ is more susceptible than the parent materials.

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Properties analysis of environment friendly calcareous deposit films electrodeposited at various temperature conditions in natural seawater (천연해수 중 온도 변화에 따라 전착한 환경친화적인 석회질 피막의 특성 분석)

  • Lee, Chan-Sik;Kang, Jun;Lee, Myeong-Hoon
    • Journal of Advanced Marine Engineering and Technology
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    • v.39 no.7
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    • pp.779-785
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    • 2015
  • Cathodic protection is recognized as the most cost-effective and technically appropriate corrosion prevention method for the submerged zone of offshore structures, ships, and deep-sea facilities. When cathodic protection is applied, the cathodic currents cause dissolved oxygen reduction, generating hydroxyl ions near the polarized surface that increase the interfacial pH and result in enhanced carbonate ion concentration and precipitation of an inorganic layer whose principal component is calcium carbonate. Depending on the potential, magnesium hydroxide can also precipitate. This mixed deposit is generally called "calcareous deposit." This layer functions as a barrier against the corrosive environment, leading to a decrease in current demand. Hence, the importance of calcareous deposits for the effective, efficient operation of marine cathodic protection systems is recognized by engineers and scientists concerned with cathodic protection in submerged marine environments. Calcareous deposit formation on a marine structure depends on the potential, current, pH, temperature, pressure, sea-water chemistry, flow, and time; deposit quality is significantly influenced by these factors. This study determines how calcareous deposits form in sea water, and assesses the interrelationship of formation conditions (such as the sea water temperature and surface condition of steel), deposited structure, and properties and the effectiveness of the cathodic protection.

Cathodic Protection of Buried Gas Pipelines Using Common Anode Beds (공용양극을 이용한 가스배관의 전기방식)

  • Ha, Y.C.;Kim, D.K.;Bae, J.H.;Ha, T.H.;Lee, H.G.
    • Journal of the Korean Institute of Gas
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    • v.12 no.1
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    • pp.19-24
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    • 2008
  • Due to industrialization and urbanization, underground metallic utilities with different owners have been rapidly increased and cathodic protection (CP) methods, especially impressed current CP systems, have been widely adopted to protect their utilities from corrosion with expanded recognition of this method. The stray current interference problem as well as the difficulty in spatial security for system installation, however, came to a ramification of which each owner couldn't resolve for himself. In this respect, this paper illustrates a field-diagnosed example for mutual interference due to separately operated CP systems and suggests an alternative method to overcome the interference situation by design and field-assessment of a common anode bed cathodic protection system.

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