• Title/Summary/Keyword: Cathodic Potential

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Study on the Cathodic Protection Characteristics of Hot Water Boiler by Mg-Alloy Galvanic Anode(1) (Mg 합금 유전양극에 의한 온수Boiler의 음극방식특성에 관한 연구(1))

  • 임우조;윤병두
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.37 no.2
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    • pp.147-152
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    • 2001
  • Corrosion damage of boiler, factory equipment and so forth occur quickly due to using of the polluted water, resulting in increasing leak accident. Especially, working life of hot water boiler using the polluted water becomes more short, and energy loss increases. The cathodic protection method is the most economical and reliable one to prevent corrosion damage of steel structures. Mg-base alloys galvanic anode protection of cathodic protection methode is suitable for the application of hot water boiler using water with high specific resistance such as tap water. This paper is studied on the cathodic protection characteristics of hot water boiler. In tap water solution, the measurement of cathodic protection potential according to the time elapsed is carried out, and behavior of cathodic polarization with current change is investigated. The main results obtained are as follows. In hot water boiler shell, the open circuit potential of base metal become less noble than that of weld Bone, and the current density of base metal becomes low than that of weld zone. The further distance from Mg-alloy galvanic anode, the higher cathodic protection potential of hot water boiler appears. And protective potential becomes high according to pass cathodic protection time and after 6∼10 days become stable.

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The Effects of cathodic protection on fracture toughness of buried gas pipeline (매설가스배관의 음극방식이 배관의 파괴인성에 미치는 영향)

  • Kim, Cheol-Man;Kim, Woo-Sik
    • Proceedings of the KSME Conference
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    • 2001.06a
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    • pp.573-578
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    • 2001
  • For the corrosion protect ion of the natural gas transmission pipelines, two methods are used, cathodic protection and coating technique. In the case of cathodic protection, defects are embrittled by occurring hydrogen at the crack tip or material surface. It is however very important to evaluate whether cracks in the embrittled area can grow or not, especially in weld metal. In this work, on the basis of elastic plastic fracture mechanics, we performed CTOD test ing with varying test conditions, such as the potential and current density. The CTOD of the base steel and weld metal showed a strong dependence of the test conditions. The CTOD decreased with increasing cathodic potential and current density. The morphology of the fracture surface showed quasi-cleavage. Hydrogen introduced fractures, caused by cathodic overprotection.

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Fracture Toughness Evaluation of Natural Gas Pipeline under the Cathodic Protection

  • Kim, Cheol-Man;Baek, Jong-Hyun;Kim, Young-Pyo;Kim, Woo-Sik
    • Corrosion Science and Technology
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    • v.8 no.4
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    • pp.133-138
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    • 2009
  • For the corrosion protection of the natural gas transmission pipelines, two methods are used, cathodic protection and coating technique. In the case of cathodic protection, defects are embrittled by occurring hydrogen at the crack tip or material surface. It is however very important to evaluate whether cracks in the embrittled area can grow or not, especially in weld metal. In this work, on the basis of elastic plastic fracture mechanics, we performed the CTOD testing with various test conditions, such as testing rate and potential. The CTOD of the base metal and the weld metal showed a strong dependence of the test conditions. The CTOD decreased with decreasing testing rate and with increasing cathodic potential. The morphology of the fracture surface showed the quasi-cleavage at low testing rate and cathodic overprotection. The low CTOD was caused by hydrogen embrittlement at crack tip.

Determination of optimum protection potential for cathodic protection of offshore wind-turbine-tower steel substructure by using potentiostatic method (정전위법에 의한 해상풍력 타워 구조물용 강재의 음극방식을 위한 최적방식전위 결정)

  • Lee, Jung-Hyung;Jung, Kwang-hu;Park, Jae-Cheul;Kim, Seong-Jong
    • Journal of Advanced Marine Engineering and Technology
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    • v.41 no.3
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    • pp.230-237
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    • 2017
  • In this study, electrochemical methods were used to determine the optimum protection potential of S355ML steel for the cathodic protection of offshore wind-turbine-tower substructures. The results of potentiodynamic polarization experiments indicated that the anodic polarization curve did not represent a passivation behavior, while under the cathodic polarization concentration, polarization was observed due to the reduction of dissolved oxygen, followed by activation polarization by hydrogen evolution as the potential shifted towards the active direction. The concentration polarization region was found to be located between approximately -0.72 V and -1.0 V, and this potential range is considered to be the potential range for cathodic protection using the impressed current cathodic protection method. The results of the potentiostatic experiments at various potentials revealed that varying current density tended to become stable with time. Surface characterization after the potentiostatic experiment for 1200 s, by using a scanning electron microscope and a 3D analysis microscope confirmed that corrosion damage occurred as a result of anodic dissolution under an anodic polarization potential range of 0 to -0.50 V, which corresponds to anodic polarization. Under potentials corresponding to cathodic polarization, however, a relatively intact surface was observed with the formation of calcareous deposits. As a result, the potential range between -0.8 V and -1.0 V, which corresponds to the concentration polarization region, was determined to be the optimum potential region for impressed current cathodic protection of S355ML steel.

Regional Cathodic Protection Design of a Natural Gas Distribution Station

  • Yabo, Hu;Feng, Zhang;Jun, Zhao
    • Corrosion Science and Technology
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    • v.16 no.5
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    • pp.235-240
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    • 2017
  • Regional cathodic protection has significant impact on pipeline integrity management. After risk analyses of a newly built gas distribution station constructed in an area with large dwelling density, risk score was high because of potential threat caused by galvanic corrosion. Except reinforced steel in concrete, there are four kinds of metal buried under earth: carbon steel, galvanized flat steel, zinc rod and graphite module. To protect buried pipeline from external corrosion, design and construction of regional cathodic protection was proposed. Current density was measured with potential using potential dynamic test and boundary element method (BEM) was used to calculate current requirement and optimize best anode placement during design. From our calculation on the potential, optimized conditions for this area were that an applied current was 3A and anode was placed at 40 meters deep from the soil surface. It results in potential range between $-1.128V_{CSE}$ and $-0.863V_{CSE}$, meeting the $-0.85V_{CSE}$ criterion and the $-1.2V_{CSE}$ criterion that no potential was more negative than $-1.2V_{CSE}$ to cause hydrogen evolution at defects in coating of the pipeline.

Relationship between the Cathodic Protection of Pipe Buried in Soil and Environmental Factors (토양 매설 배관의 음극방식과 환경인자 간의 상관관계)

  • Choi, S.H.;Won, S.Y.;Yoo, Y.R.;Kim, Y.S.
    • Corrosion Science and Technology
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    • v.21 no.5
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    • pp.372-380
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    • 2022
  • The external corrosion control of buried pipes can be achieved by a combination of coatings and cathodic protection to maximize effectiveness. One of the factors affecting cathodic protection is the environmental soil conditions. Because soil is a kind of electrolyte, the environmental conditions of soil may be changed by the atmospheric environment. Therefore, in this study, changes in environmental soil factors by atmospheric environmental factors were monitored. In cathodic protection, on-potential and off-potential were measured from December 2021 to July 2022. The effects of external environmental factors and soil environmental factors on cathodic protection were analyzed. Changes in outdoor temperature affected soil temperature, and soil conductivity had a proportional relationship with soil humidity, but outdoor humidity and precipitation did not significantly affect humidity and conductivity of the soil. In contrast, in cathodic protection, the on-potential was affected by temperature, humidity, the conductivity of the soil, and the anode used, but the off-potential was little affected by these factors.

A Study on the Characteristics of Cathodic Protection by Al-Alloy Sacrificial Anode in Marine Environment (해양환경중에서 A1-합금희생양극에 의한 음극방식특성)

  • 이연호
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.28 no.1
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    • pp.53-60
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    • 1992
  • In this study, cathodic protection experiment was carried out by Al-alloy sacrificial anode in marine environments which have specific resistance($\rho$) if 25~7000$\Omega$.cm and investigated protection potential, current density and loss rate of Al-alloy sacrificial anode. The main results resistance($\rho$) of 400$\Omega$.cm, the cathodic protection potential appears high about-720 mV(SCE). But below specific resistance($\rho$) of 300$\Omega$.cm, the cathodic protection potential appears low about-770 mV(SCE) and simultaneously, cathode is protected sufficiently. 2) The loss rate of Al-Alloy sacrificial anode became large with decreasing specific resistance and increasing the ratio(A sub(c)/A sub(a) of bared surface area of anode and cathode. 3) The loss rate of Al-alloy sacrificial anode(w) to the mean current density of anode(i) is as follows. w=ai+b (a, b : experimental constants)

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EFFECT OF POST-WELD HEAT TREATMENT OF MARINE STRUCTURE STEEL DURING CATHODIC PROTECTION

  • Kim, Seong-Jong;Masazumi Okido;Kim, Jin-Gyeong;Moon, Kyung-Man
    • Proceedings of the KWS Conference
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    • 2002.10a
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    • pp.273-275
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    • 2002
  • The effect of post-weld heat treatment (PWHT) of marine structures steel was investigated at electrochemical viewpoint. In addition, slow strain rate test (SSRT) was carried out to investigate both electrochemical and mechanical properties by PWHT effect during impressed current cathodic protection. The optimum cathodic protection potential by SSRT was -770 mV(SCE). At the applied cathodic protection potential of -770 mV -850 mV(SCE), the fracture morphology was dimple pattern with ductile fracture, while it was transgranular pattern (Q.C: quasi cleavage) under -875 mV(SCE).

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Engineering Technology Far-end Telecontrol Cathodic Protection on the Structure of Jetty Bridge Cap Beams

  • Liu, Yi-Hsiung;Lim, Pau-Yee;Shih, Chien-Chis
    • Corrosion Science and Technology
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    • v.2 no.1
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    • pp.47-52
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    • 2003
  • 23 cap beams on the 1 Km length jetty bridge in Shin-da power plant (Taipower co., Taiwan) utilize far-end telecontrol cathodic protection technology which is the first case ever used in Taiwan. The system comprises cathodic protection system and te1econtrol monitoring system. The control and monitoring such as protection current adjustment, protection potential and depolarization measurement of the 23 cap beams can be adjusted through system telecontrol operations. Thereby allows monitoring and control of the 23 anode zones in a convenient and cost effective way. This system is at present still in its best running condition since Sept. 1997 when it was completed. All the 23 cap beams can achieve the 100 mV depolarization potential criteria of protection. It meet the specifications of reinforced concrete cathodic protection standard and proved to be very excellent.

Distribution of Cathodic Protection Potential for Concrete Slab Specimens at Diverse Environmental Conditions

  • Jin, Chung-Kuk;Jeong, Jin-A
    • International Journal of Ocean System Engineering
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    • v.3 no.2
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    • pp.90-94
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    • 2013
  • This study represents the recent laboratory results from cathodic protection (CP) system with the use of sacrificial anodes at different environmental conditions (temperature of $10^{\circ}C$ and $40^{\circ}C$). Specimens were slab type with a dimension of $500mm{\times}50mm{\times}100mm$, and concrete cover thickness were 25mm. Zinc mesh and/or bulk type anodes were installed at the center of specimen to confirm the distance that CP system has influences on the specimen to distribute uniform CP current to rebar. Two different kinds of temperature condition were applied to verify the effect of temperature. Experiments were conducted for 60 days, and the distribution of potential and current that supplied from anode to rebar was measured. From the results, CP potential was varied with time, and temperature played an important role in CP potential variations. Current was also changed with time, and current distribution could be improved by installing additional bulk type anode.