• Title/Summary/Keyword: Cathode reduction

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PM OLED Fabrication with New Method of Metal Cathode Deposition Using Shadow Mask

  • Lee, Ho-Chul;Kang, Seong-Jong;Yi, Jung-Yoon;Kim, Ho-Eoun;Kwon, Oh-June;Hwang, Jo-Il;Kim, Jeong-Moon;Roh, Byeong-Gyu;Kim, Woo-Young
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.987-989
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    • 2006
  • 1.52" $130(RGB){\times}130$ full color PM OLED device with $70\;{\mu}m{\times}210\;{\mu}m$ of sub-pixel pitch was fabricated using shadow mask method for metal cathode deposition. Instead of conventional patterning process to form cathode separator via photolithography, regularly patterned shadow mask was applied to deposit metal cathode in this OLED display. Metal cathode was patterned via 2-step evaporation using shadow mask with shape of rectangular stripe and its alignment margin is $2.5\;{\mu}m$. Technical advantages of this method include reduction of process time according to skipping over photolithographic process for cathode separator and minimizing pixel shrinkage caused by PR cathode separator as well as improving lifetime of OLED device.

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Effect of Current Collecting Layer on the Impedance of LSM and LSM-YSZ Cathode (LSM 및 LSM-YSZ 양극의 임피던스 특성에 미치는 집전층의 효과)

  • 문지웅;이홍림;김구대;김재동;이해원
    • Journal of the Korean Ceramic Society
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    • v.35 no.10
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    • pp.1070-1077
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    • 1998
  • Effect of current collecting layer on the cathode was characterized by AC impedance spectroscopy at 800$^{\circ}C$ under flowing air. LSM-YSZ composite cathode showed lower polarization resistance due to the in-crease of triple phase (LSM/YSZ/Pore) boundary length by incorporation of YSZ. Ohmic resistance {{{{ {R }_{1 } }} of LSM-YSZ was higher than that of pure LSM however because in-plane resistance of the cathode was fair-ly high due to its high specific resistivity. To reduce the in-plane resistance of LSM-YSZ cathode cathode side current collecting layer was required. Ohmic resistance {{{{ {R }_{1 } }} was reduced after forming LSM current col-lecting layer on the LSM-YSZ cathode. In case of pure LSM cathode the formation of Pt, or LSCO current collecting layer reduced polarization resistance {{{{ {R }_{p } }} but ohmic resistance {{{{ {R }_{1 } }} was relatively constant. After annealing of LSM cathode with Pt current collector at higher temperature polarization resistance {{{{ {R }_{p } }} was in-creased but ohmic resistance {{{{ {R }_{1 } }} was constant. These phenomena indicate that Pt or LSCo current col-lecting layers act as a catalytic layer for oxygen reduction of pure LSM cathode. LSCO current collector was effective in reducing the ohmic and polarization resistance of LSM-YSZ cathode.

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Electrochemical Performance of the Solid Oxide Fuel Cell with Different Thicknesses of BSCF-based Cathode (BSCF계 혼합전도성 공기극의 두께에 따른 고체산화물 연료전지의 전기화학적 특성)

  • Jeong, Jaewon;Yoo, Chung-Yul;Joo, Jong Hoon;Yu, Ji Haeng
    • Transactions of the Korean hydrogen and new energy society
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    • v.24 no.2
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    • pp.186-192
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    • 2013
  • In order to reduce the costs and to improve the durability of solid oxide fuel cell (SOFC), the operating temperature should be decreased while the power density is maintained as much as possible. However, lowering the operating temperature increases the cathode interfacial polarization resistances dramatically, limiting the performance of low-temperature SOFC at especially purely electronic conducting cathode. To improve cathode performance at low temperature, the number of reaction sites for the oxygen reduction should be increased by using a mixed ionic and electronic conducting (MIEC) material. In this study, anode-supported fuel cells with two different thicknesses of the MIEC cathode were fabricated and tested at various operating temperatures. The anode supported cell with $32.5{\mu}m$-thick BSCFZn-LSCF cathode layer showed much lower polarization resistance than that with $3.2{\mu}m$ thick cahtode and higher power density especially at low temperature. The effects of cathode layer thickness on the electrochemical performance are discussed with analysis of impedance spectra.

Synthesis and Electrochemical Evaluation of La1-xSrxCoO3 Cathode Material for Zinc Air Secondary Batteries Application (아연공기이차전지용 La1-xSrxCoO3 양극촉매의 제조 및 이를 적용한 양극의 전기화학적 특성연구)

  • Eom, Seung-Wook;Sun, Yang-Kook
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.5
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    • pp.447-452
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    • 2008
  • We synthesized nano-sized $La_{1-x}Sr_xCoO_3$ ($x=0.1{\sim}0.4$) cathode catalyst for the zinc air secondary batteries by citrate method, And we measured the cathode's electrochemical characteristics according to content of strontium compose the cathode catalyst. We controlled the pH of precursor solution by 10 in the process of manufacturing the precursor, We heat treated the prepared precursor at various calcination temperature ($500{\sim}900^{\circ}C$), and examined the optimum calcinations temperature by XRD analysis and electrochemical evaluation. We examined the ORR (oxygen reduction reaction) and OER (oxygen evolution reaction) performance of the prepared $La_{1-x}Sr_xCoO_3$ catalyst powder. When we consider ORR and OER performance simultaneously, $La_{0.7}Sr_{0.3}CoO_3$ catalyst has shown the best performance because of its lowest voltage deference between charge and discharge.

A Study on environmental-friendly Cleaning for Si-wafers (환경친화적인 실리콘 웨이퍼 세정 연구)

  • Yoon, Hyoseob;Ryoo, Kunkul
    • Clean Technology
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    • v.6 no.1
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    • pp.79-84
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    • 2000
  • In this study, to reduce the consumption of chemicals in cleaning processes, Si-wafers contaiminated with metallic impurities were cleaned with electrolyzed water(EW), which was generated by the electrolysis of a diluted electrolyte solution or ultra pure water(UPW). Electrolyzed water could be controlled for obtaining wide ranges of pH and ORP(oxidation-reduction potential). The pH and oxidation-reduction potential of anode water and cathode water were measured to be 4.7 and +1000mV, and 6.3 and -550mV, respectively. To analyze the amount of metallic impurities on Si-wafer surfaces, ICP-MS was introduced. Anode water was effective for Cu removal, while cathode water was more effective for Fe removal.

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Study on high performance cathode on YSZ electrolyte for intermediate-temperature solid oxide fuel cells(IT-SOFC) (중온형 고체산화물 연료전지를 위한 YSZ 전해질에서의 고성능 공기극 연구)

  • Lee, Chang-Bo;Bae, Joong-Myeon
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.11a
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    • pp.368-371
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    • 2006
  • [ $La_{0.8}Sr_{0.2}Co_{1-x}Mn_xO_3$ ] cathode as a high performance cathode on YSZ electrolyte was studied by analyzing impedance spectra. It was shown that cathode property of $La_{0.8}Sr_{0.2}Co_{1-x}Mn_xO_3$ is bet ter than that of$La_{0.8}Sr_{0.2}CoO_3$. At $700^{\circ}C$ in air environment, $La_{0.8}Sr_{0.2}Co_{0.4}Mn_{0.6}O_3$ cathode on CGO- layered YSZ electrolyte showed very low area specific resistance of $0.14{\Omega}cm^2$, which is low enough for intermediate-temperature sol id oxide fuel cells. This is because material properties of ionic conductivity and thermal expansion compatibility with electrolyte were optimized. Judging from activation energy and oxygen part i al pressure dependance of cathode property, it was noted that oxygen surface exchange kinetics is dominantly influential on cathode property in higher temperature region than $700^{\circ}C$ and oxygen self-diffusion in cathode material is more influential in lower temperature region.

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Study on metal-supported solid oxide fuel cells (신구조 금속지지체형 고체산화물 연료전지)

  • Lee, Chang-Bo;Bae, Joong-Myeon
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.129-132
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    • 2007
  • Advanced structure of metal-supported solid oxide fuel cells was devised to overcome sealing problem and mechanical instability in ceramic-supported solid oxide fuel cells. STS430 whose dimensions were 26mm diameter, 1mm thickness and 0.4mm channel width was used as metal support. Thin ceramic layer composed of anode(Ni/YSZ) and electrolyte(YSZ) was joined with STS430 metal support by using a cermet adhesive. $La_{0.8}Sr_{0.2}Co_{0.4}Mn_{0.6}O_{3}$ perovskite oxide was used as cathode material. It was noted that oxygen reduction reaction of cathode governed the overall cell performance from oxygen partial pressure dependance.

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Low Voltage-Driven CNT Cathode and It's Applications

  • Lee, Chun-Gyoo;Lee, Sang-Jo;Cho, Sung-Hee;Chi, Eung-Joon;Lee, Byung-Gon;Jeon, Sang-Ho;Ahn, Sang-Hyuck;Hong, Su-Bong;Choe, Deok-Hyeon
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.851-854
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    • 2004
  • By approaching the counter electrode to the CNT emitter, remarkable reduction of the cathode operating voltage has been accomplished in the under-gate CNT cathode structure. The peak emission current density of 2.5 ms/$cm^2$, which is sufficient for high brightness CNT field emission display, was obtained at the cathode-to-gate voltage of 57 V when the CNT-to-counter electrode gap was 2.2 ${\mu}m$. The gate current was less than 10 % of the anode current. The CNT cathode with low driving voltage can help the cost-effective field emission display implemented.

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Study of the Electrolytic Reduction of Uranium Oxide in LiCl-Li$_{2}$O Molten Salts with an Integrated Cathode Assembly

  • Park Sung-Bin;Seo Chung-seok;Kang Dae-Seung;Kwon Seon-Gil;Park Seong-Won
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.3 no.2
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    • pp.105-112
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    • 2005
  • The electrolytic reduction of uranium oxide in a LiCl-Li$_{2}$O molten salt system has been studied in a 10 g U$_{3}$O$_{8}$ /batch-scale experimental apparatus with an integrated cathode assembly at 650$^{\circ}C$. The integrated cathode assembly consists of an electric conductor, the uranium oxide to be reduced and the membrane for loading the uranium oxide. From the cyclic voltammograms for the LiCl-3 wt$\%$ Li$_{2}$O system and the U$_{3}$O$_{8}$-LiCl-3 wt$\%$ Li$_{2}$O system according to the materials of the membrane in the cathode assembly, the mechanisms of the predominant reduction reactions in the electrolytic reactor cell were to be understood; direct and indirect electrolytic reduction of uranium oxide. Direct and indirect electrolytic reductions have been performed with the integrated cathode assembly. Using the 325-mesh stainless steel screen the uranium oxide failed to be reduced to uranium metal by a direct and indirect electrolytic reduction because of a low current efficiency and with the porous magnesia membrane the uranium oxide was reduced successfully to uranium metal by an indirect electrolytic reduction because of a high current efficiency.

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A Study on the removal of Metallic Impurities on Si-wafer using Electrolyzed Water (전해수를 이용한 실리콘 웨이퍼 표면의 금속오염 제거)

  • Yoon, Hyo-Seob;Ryoo, Kun-Kul
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.04b
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    • pp.1-5
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    • 2000
  • As the semiconductor devices are miniaturized, the number of the unit cleaning processes increases. In order to processes by conventional RCA cleaning process, the consumption of volume of liquid chemical and DI water became huge. Therefore, the problem of environmental issues are evolved by the increased consumption of chemicals. To resolve this matter, an advanced cleaning process by Electrolyzed Water was studied in this work. The electrolyzed water was made by an electrolysis equipment which was composed of three chambers of anode, cathode, and middle chambers. In the case of electrolyzed water with electrolytes in the middle chamber, oxidatively acidic water of anode and reductively alkaline water of cathode were obtained. The oxidation/reduction potentials and pH of anode water and cathode water were measured to be +l000mV and 4.8, and -530mV and 6.3, respectively. The Si-wafers contaminated with metallic impurities were cleaning with the electrolyzed water. To analysis the amounts of metallic impurities on Si-water surfaces, ICP-MS(Inductively Coupled Plasma-Mass spectrometer) was introduced. From results of ICP-MS measurements, it was concluded that the ability of electrolyzed water was equivalent to that of the conventional RCA cleaning.

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