• Title/Summary/Keyword: Cathode potential

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Effect of Potential Well Structure on Ion Current in SCBF Device (SCBF 장치에서 이온전류에 대한 포텐셜 우물 구조의 영향)

  • Ju, Heung-Jin;Park, Jeong-Ho;Ko, Kwang-Cheol
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.5
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    • pp.471-477
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    • 2007
  • SCBF(Spherically Convergent Beam Fusion) device has been studied as a neutron source. Neutron production rate is a most important factor for the application of SCBF device and is proportional to the square of the ion current[1]. It is regarded generally that some correlations between the potential well structure and the ion current exist. In this paper, the ion current and potential distribution were calculated in a variety of grid cathode geometries using FEM-FCT method. Single potential well structure was certified inside the grid cathode. The deeper the potential well became, the higher the ion current due to the high electric field near the grid cathode became.

Investigation of the mechanism of Ni-P alloy deposition using by in-situ surface pH measurement during electrodeposition (음극표면 pH 측정에 의한 Ni-P합금의 전착기구 고찰)

  • 이규환;장도연;김동수;이상열;권식철;강성군
    • Journal of the Korean institute of surface engineering
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    • v.35 no.2
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    • pp.93-100
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    • 2002
  • To better understand the codeposition mechanism of phosphorous, surface pH and potential of cathode were measured during electrodeposition of Ni-P alloys. The pH of cathode surface was measured using a flat-bottom glass pH electrode and a 500 mesh gold gauze as cathode. The cathode surface pH was increased with increasing the current density and always higher than the pH in the bulk solution. As a result of overplotting the surface pH and cathode potential on the Pourbaix diagram, it was found that cathode surface shift to the domain of predominant of $H_2$$PO3$-or $H_2$$PO_2$-. Additionally, new deposition mechanism was suggested that $H_2$ $PO_2$- and $H_2$$PO_3$- play important roles in the deposition reaction of Ni-P alloys.

Electrochemical stability of La0.6Sr0.4Co0.2Fe0.8O3-δ as a cathode for SOFC

  • Oh, Mi-Young;Jeong, Yong-Hoon;Oh, Se-Woong
    • Journal of the Korean institute of surface engineering
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    • v.49 no.6
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    • pp.498-506
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    • 2016
  • Electrochemical measurement using a LSCF6428 electrode was performed to estimate the oxygen potential gradient in the electrode layer and a long time stability test was performed by applied potential to learn the overpotential effect on the LSCF6428 electrode. By fitting the observed impedance spectra, it was obtained that the amount of faradic current decreased with distance from cathode/electrolyte interface. Oxygen potential gradient was estimated to occur within 1 um region from the cathode/electrolyte interface at an oxygen partial pressure of 10-1 bar. The segregation of cation rich phases in the LSCF6428 electrode suggests that kinetic decomposition took place. However, impedance response after applying the potential showed no changes in the electrode compared with before applying potential. The obtained results suggest that segregation of a secondary phase in a LSCF6428 cathode is not related to performance degradation for solid oxide fuel cells (SOFCs).

A study on the relationships between plasma parameters and magnetic field (플라즈마 파라메타와 자계의 상관관계에 관한 연구)

  • 김두환;장윤석;조정수;박정후
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.45 no.3
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    • pp.426-431
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    • 1996
  • It is well known that the understanding of the complex mechanism of magnetoplasma is closely related with understanding of the collective behavior of discharge plasma parameters such as the cathode-sheath potential, cathode-sheath thickness, electron temperature, electron density, and ambipolar diffusion. In this paper, some of the relationships between these plasma parameters and magnetic field is investigated experimentally with a Langmuir probe in the magnetoplasma generated by D.C diode system. It is found that when magnetic field is increased, cathode-sheath potential, cathode-sheath thickness, and ambipolar diffusion are decreased. In addition, peak ion density obtained as a parameter of ionic signal voltage by Faraday cup method is independent of magnetic field. (author). 9 refs., 11 figs.,1 tab.

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Improvement of Ethanol Production by Electrochemical Redox Combination of Zymomonas mobilis and Saccharomyces cerevisiae

  • Jeon, Bo-Young;Park, Doo-Hyun
    • Journal of Microbiology and Biotechnology
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    • v.20 no.1
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    • pp.94-100
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    • 2010
  • Zymomonas mobilis was immobilized in a modified graphite felt cathode with neutral red (NR-cathode) and Saccharomyces cerevisiae was cultivated on a platinum plate anode. An electrochemical redox reaction was induced by 3 volts of electric potential charged to the cathode and anode. The Z. mobilis produced 1.3-1.5 M of ethanol in the cathode compartment, whereas the S. cerevisiae produced 1.7-1.9 M in the anode compartment after 96 h. The ethanol produced by the Z. mobilis immobilized in the NR-cathode and S. cerevisiae cultivated on the platinum plate was 1.5-1.6 times higher than that produced under conventional conditions. The electrochemical oxidation potential inhibited Z. mobilis, but activated S. cerevisiae. The SDS-PAGE pattern of the total soluble proteins extracted from the Z. mobilis cultivated under the electrochemical oxidation conditions was gradually simplified in proportion to the potential intensity. Z. mobilis and S. cerevisiae were cultivated in the cathode and anode compartments, respectively, of an electrochemical redox combination system. The Z. mobilis culture cultivated in the cathode compartment for 24 h was continuously transferred to the S. cerevisiae culture in the anode compartment at a rate of 300 ml/day. Approx. 1.0-1.2 M of ethanol was produced by the Z. mobilis in the cathode compartment within 24 h, and an additional 0.8-0.9 M produced by the S. cerevisiae in the anode compartment within another 24 h. Thus, a total of 2.0-2.1 M of ethanol was produced by the electrochemical redox combination of Z. mobilis and S. cerevisiae within 48 h.

A Large Area Plasma Source Using Multi-cathode Electron Beam (다중 음극 전자빔을 이용한 대면적 플라즈마 소스)

  • Gang, Yang-Beom;Jeon, Hyeong-Tak;Kim, Tae-Yeong;Jeong, Gi-Hyeong;Go, Dong-Gyun;Jeong, Jae-Guk;No, Seung-Jeong
    • Korean Journal of Materials Research
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    • v.9 no.9
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    • pp.861-864
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    • 1999
  • A new plasma source using the multi-cathode electron beam has been designed and manufactured. A multi-cathode was adopted to produce bulk plasmas in a large volume. Multi-cathode electron beam plasma source(MCEBPS) was found to generate stable plasmas over the wafer diameter of 300 mm or above. W(tungsten) filament was used as a cathode. Over a 320 mm diameter, both the plasma potential $V_p$ and floating potential $V_f$ were uniformly maintained and the difference between $V_p and V_f$ was measured to be small. The plasma density was around $10^{10} cm^{-3}$ and its variation along the radial distance was small.

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Fabrication and Characterization of Cold Cathode Electron-gun of CRT using Mo-tip Field Emitter Array (몰리브덴 팁 전계 방출 소자를 이용한 CRT의 냉음극 전자총의 제조 및 특성 평가)

  • Ju, Byeong-Kwon;Kim, Hoon;Seo, Sang-Won;Park, Jong-Won;Lee, Yun-Hi;Kim, Nam-Su
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.50 no.8
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    • pp.409-413
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    • 2001
  • In the electron-gun of CRT, the Mo-tip FEA was employed as cold cathode in order to replace the conventional thermal cathode. The Mo-tip FEA was designed and fabricated according to CRT specification and mounted on the electron-gun. It was known that fabricated cold cathode electron-gun showed better performance in terms of maximum emission current and switch-on time when compared with the ones of thermal cathode electron-gun, but some geometrical structures in the inside of electron-gun must be changed to reduce the gate leakage current. Finally, the potential applicability was guaranteed by means of operating the 19 inch-sized LG-color CRT using the fabricated cold cathode electron-gun.

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Development of Advanced Polymeric Binders for High Voltage LiNi0.5Mn1.5O4 cathodes in Lithium-ion batteries (고전압 LiNi0.5Mn1.5O4 양극 고성능 바인더 개발 연구)

  • Dae Hui Yun;Sunghun Choi
    • Journal of Industrial Technology
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    • v.43 no.1
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    • pp.43-48
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    • 2023
  • Spinel LiNi0.5Mn1.5O4 (LNMO) has been considered as one of most promising cathode material, because of its low-cost and competitive energy density. However, 4.7V vs. Li/Li+ of high operating potential facilitates electrolyte degradation on cathode-electrolyte interface during charge-discharge process. In particular, commercial polyvinylidene fluoride (PVDF) is not sutaible for LNMO cathode binder because its weak van der waals force induces thick and non-uniform coverage on the cathode surface. In this review, we study high performance binders for LNMO cathode, which forms uniform coating layer to prevent direct contact between electrolyte and LNMO particle as well as modifying high quality cathode electrolyte interphase, improved cell performace.

Fundamental Studies of the Electrical Characteristics of the Glow Discharge for the Development of HPLC Detector (글로우방전을 이용한 액체크로마토그라피 검출기 개발을 위한 기초특성연구)

  • 이현주;김효진
    • YAKHAK HOEJI
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    • v.39 no.4
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    • pp.427-432
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    • 1995
  • The plasma oscillation has been observed in an argon pressure between a tungsten anode and cathode consisting of an aqueous conducting solution. The effects of experimental parameters on the electrical characteristics of the glow discharge have been studied. The experimental parameters include the anode-cathode distance, pressure, methanol flow rate, and cathode materials. The glow discharge with liquid cathode and solid anode showed the potential sensitive detector for HPLC

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Characteristics of Secondary Electron Emission for Electron Beam Extraction (전자빔 인출을 위한 2차전자방출 특성 연구)

  • Woo, Sung-Hun;Lee, Hong-Sik;Lee, Kwang-Sik
    • Proceedings of the KIEE Conference
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    • 2003.10a
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    • pp.204-206
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    • 2003
  • Electron beam generator of cold cathode type has been developed for industrial application, for example, waste water cleaning, flue gas cleaning, and pasteurization etc. The operational principle is based on the emission of secondary electrons from cold cathode when ions in the plasma hit the cathode, which are accelerated toward exit window by the gradient of an electric potential. The characteristics of secondary electron emission are studied by comparing total cathode current with ion current.

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