• Journal of the Korean Society of Combustion
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• v.2 no.1
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• pp.29-38
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• 1997

In this study, the experimental and numerical investigations of the ignition of methane-air mixtures by a electrically heated wire have been carried out. In order to define the initial condition and make the analysis simple, the following control unit was developed; which heats the wire to the setting temperature in a very short time, and maintains the wire temperature constant until ignition. Experiments with the feedback control have been performed using nickel and platinum wires in normal gravity and microgravity. From experimental results, ignition temperatures in normal gravity are higher than those in microgravity, however, the dependences of ignition temperature on equivalence ratio are not affected by natural convection. Numerical calculations, including catalytic reaction for platinum, have been performed to analyze the experimental results in microgravity. Numerical results show that reactants near platinum wire are consumed by catalytic reaction, therefore, the higher temperature is needed to ignite the mixture with platinum wire.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2009.11a
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• pp.74-77
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• 2009

Ignition performance tests were performed to develop a catalytic ignitor which used hydrogen peroxide and kerosene. Ignition characteristics were investigated by exit area of the catalytic bed, shape of kerosene injector and lead time of purge gas. The results showed that exit area of catalytic bed must be enough for non chocking condition and kerosene must be sprayed with swirl in the middle of catalytic bed. Also in case without preheating of catalytic bed, hydrogen peroxide must be leaded by 3sec, and purge gas must be supplied simultaneously or lately with kerosene.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.22 no.12
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• pp.1681-1690
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• 1998

The aim of this paper is to investigate combustion characteristics of lean premixed mixture stabilized by catalytic surface reaction. The catalytic combustor consisted of a catalyst bed and a thermal combustor. The catalyst bed was made of two stage, Pd catalyst in the first stage and Pt catalyst in the second stage. Auto ignition of lean mixture took place in the thermal combustor. Ignition temperature was about $810{\sim}820^{\circ}C$ at the fuel-air ratio of 1.5~3.0 % and the mixture velocity of 11~18m/sec. The position of flame front in the thermal combustor moved toward back as preheat temperature increased and fuel-air ratio decreased. The f1ame supported by surface reaction was stabilized without any flame stabilizers. NOx emissions from the catalytic combustor were below 2.0 ppm ($O_2$ 15 %) when gas temperature was limited below $1350^{\circ}C$. This result demonstrates that NOx emission from the catalytic combustor is much low comparing with conventional combustors.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2010.05a
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• pp.202-205
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• 2010

Auto ignition of hybrid rocket using $N_2O$ catalytic decomposition was studied in the present study. The hybrid rocket consists of catalytic igniter, solid fuel, combustor, and nozzle. The Ru/$Al_2O_3$ catalyst for $N_2O$ decomposition was synthesized by an impregnation method, and $N_2O$ conversion as reaction temperatures was measured. The temperature change of the catalytic ignitor was measured at the operating condition, and the possibility for the auto ignition of hybrid rocket was validated.

• Transactions of the Korean Society of Automotive Engineers
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• v.10 no.3
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• pp.61-69
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• 2002

To meet stringent LEV and ULEV emission standards, a considerable amount of development work was necessary to ensure suitable efficiency and durability of catalyst systems. The main challenge is to cut off the engine cold-start emissions. It is known that up to 80% of the total hydrocarbons(THC) are exhausted within the first five minutes in case of US FTP 75 cycle. Close-Coupled Catalyst(CCC) provides fast light-off temperature by utilizing the energy in the exhaust gas. However, if some malfunction occurred at engine operation and the catalyst temperature exceeds 1050$\^{C}$, the catalytic converter is deactivated and shows the poor conversion efficiency. This paper presents effEcts of engine operating conditions on catalytic converter temperature in a SI engine, which are the indications of catalytic deactivation. Exhaust gas temperature and catalyst temperature were measured as a function of air/fuel ratio, ignition timing and misfire rates. Additionally, light-off time was measured to investigate the effect of operating conditions. It was found that ignition retard and misfire can result in the deactivation of the catalytic converter, which eventually leads the drastic thermal aging of the converter. Significant reduction in light-off time can be achieved with proper control of ignition retard and misfire, which can reduce cold-start HC emissions as well.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2017.05a
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• pp.117-119
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• 2017

The multi-stage catalytic igniter for hybrid rocket auto ignition is described in this paper. After charging the catalyst and pre-heating the first stage, the $N_2O$ was supplied at the first stage with the low mass flow rate, and then the $N_2O$ with the high flow rate was supplied into the second stage. Even though the $N_2O$ flow rate was high, it was decomposed by supplying the high temperature gas which was evolved from the $N_2O$ decomposition in the first stage. This multi-stage ignitor resulted in the decrease of the ignition time in comparison with the previous ignitor, and confirmed the possibility of $N_2O$ decomposition with the high flow rate using the multi-stage catalytic-ignition system.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.28 no.6
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• pp.697-704
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• 2004

Bifurcation behavior of ignition and extinction of catalytic reaction is theoretically investigated in a stagnation-point flow. Considering that reaction takes place only on the catalytic surface, where conductive heat losses are allowed to occur, activation energy asymptotics with a overall one-step Arrhenius-type catalytic reaction is employed. For the cases with and without the limiting reactant consumption, the analysis provides explicit expressions, which indicate the possibility of multiple steady-state solution branches. The difference between the solutions with and without reactant consumption is in the existence of an upper solution branch, and the neglect of reactant consumption is inappropriate for determining extinction conditions. For larger values of reactant consumption, the solution response is all monotone, suggesting that multiple solutions are not possible. It is shown that bifurcation Damkohler numbers increase (decrease) with increasing of conductive heat loss (gain) on the catalytic surface, which means that smaller (larger) values of the strain rate allow the surface reaction to tolerate larger heat losses (gains). Lewis number of the limiting reactant can also significantly affect bifurcation behavior in a similar way to the effect of heat loss.

• Journal of Environmental Science International
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• v.13 no.7
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• pp.619-626
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• 2004

We have studied the catalytic combustion of soot particulates over perovskite-type oxides prepared by malic acid method, The catalysts were modified to enhance the activity by substitution of metal into A or B site of perovskite oxide. In addition, the reaction conditions such as temperature and $O_2$ concentration were investigated. The partial substitution of alkali metals into A site in the $LaMnO_3$ catalyst, enhanced the catalytic activity in the combustion of carbon particulate and the activity was shown in the order: Cs > K > Na. For the $La_{1-x}Cs_{x}MnO_{3}$ catalysts, the catalytic activity showed the maximum value with x=0.3 but no more increase on the catalytic activity was shown with x > 0.3. For the $La_{0.8}Cs_{0.2}MnO_{3}$ catalyst, the substitution of Fe or Ni increased the ignition temperature. The ignition temperature decreased with an increase of $O_2$ concentration, however, no more increase in the catalytic activity was shown with $O_2$ concentration > 0.2. The introduction of NO into reactants showed no effect on the catalytic activity.

• Journal of the Korean Society of Propulsion Engineers
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• v.15 no.6
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• pp.56-62
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• 2011

An experimental study on design of a catalytic ignitor was performed to use an ignition source for a small bi-propellant liquid rocket engine which use hydrogen peroxide and kerosene as propellants. In the catalytic ignitor, hot gas of hydrogen peroxide which was decomposed by a catalyst induced autoignition of kerosene. Mass flow rate and O/F ratio for the ignitor were calculated by CEA code. A combustion chamber which had a quartz window and thermocouples was manufactured to determine whether the ignition is successful. Ignition performance was investigated according to exit area of fixed rings and mixture ratio. Results showed that reliable ignition performance was achieved at non-choking exit area of fixed ring and O/F ratio of 6~8.

• Proceedings of the KSME Conference
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• 2000.11b
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• pp.335-340
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• 2000

Most vehicle's exhaust emissions come from the cold transient period of the FTP-75 test. In this study, UEGI technology was developed to help close-coupled catalytic converter (CCC) reach light-off temperature within a few seconds after cold-start. In the UEGI system, unburned exhaust mixture is ignited by four glow plugs installed upstream of the catalyst. Experimental results showed that the temperature of CCC rises faster with the UEGI technology, and the CCC reaches light-off temperature earlier. Under the conditions tested, the light-off time of the baseline case was 62 seconds and that of the UEGI case was 33 seconds.