• Transactions of the Korean hydrogen and new energy society
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• v.25 no.4
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• pp.364-377
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• 2014

The performances of a coupled reactor in which a steam reformer and a catalytic combustor were mounted simultaneously had been investigated and compared. The combustible offgas exhausted from the anode of SOFC and MCFC were utilized as heat sources for the endothermic steam methane reforming. The catalytic combustion was used in order to burn the combustible offgas. Thermal energy released by the catalytic combustion is directly transferred to the reformer surrounding the combustor. The various operational conditions such as fuel utilization rate, steam to carbon ratio, amount of catalysts, fuel cell loads were changed. And operating variables were comprehensively identified by sensitivity analysis. The fundamental results from this experimental study show the potential abilities of the coupled reactor. Therefore the results will be of help to design and manufacture the more better coupled reactor in the future.

• 한국연소학회:학술대회논문집
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• 2001.11a
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• pp.83-89
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• 2001

Most technologies of reduction process used in the heat treatment of existent metal products are related to metals applied to bolts and parts of automobiles, and nonmetal such as copper. Heating conditions and reduction gases produced in above processes depend on types of products to be treated thermally but heating systems employ electricity commonly and the reduction gases are separated into additional production equipment and a gas dryer and inefficiently provided into the system. Electrical heating system has the advantage of convenient temperature-control but is not economical because of disadvantages of high electricity-running cost and extra installation cost of a transformer. Accordingly, development of the system which has economical heating mode in which provision of reduction gas and heating conditions are unified is necessary for improvement of economy and efficiency in current reduction processes. This study aimed to develop a new advanced heat treatment furnace using catalytic combustion. thereby minimizing the cost during heating, supplying heat and reductive gas at the same time and controlling operating condition freely by changing electrical heating system to heating system by the gas combustion and regeneration of wasted heat.

• Journal of Environmental Science International
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• v.18 no.3
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• pp.283-288
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• 2009

This is a study on the volatile organic compounds(VOCs) concentrator with zeolite adsorptive honey rotor and catalytic combustion system for abating VOCs emitted from printing industry. VOCs emitted from the printing industry is mainly caused by organic solvent of printing ink. The content of organic solvents in printing ink varies from 40% to 75% and its content in the gravure ink is higher than that in any other ink. The average concentrations of each VOCs are 139 ppm for toluene, 152.1 ppm for MEK, 256.9 ppm for methanol and 42.9 ppm for isopropyl alcohol. We used zeolite honeycomb for absorbent of VOCs concentrator and palladium for catalyst combustion system. This system abated over 96% of emitted total VOCs, 98% of toluene, 100% of MEK, 92% of methanol and, 100% of isopropyl alcohol. It is concluded that the low-leveled high-volume VOCs emitted from printing process were removed almost by concentrator with zeolite adsorptive honey rotor and catalytic combustion system.

• Journal of the Korean Society of Combustion
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• v.2 no.1
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• pp.29-38
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• 1997

In this study, the experimental and numerical investigations of the ignition of methane-air mixtures by a electrically heated wire have been carried out. In order to define the initial condition and make the analysis simple, the following control unit was developed; which heats the wire to the setting temperature in a very short time, and maintains the wire temperature constant until ignition. Experiments with the feedback control have been performed using nickel and platinum wires in normal gravity and microgravity. From experimental results, ignition temperatures in normal gravity are higher than those in microgravity, however, the dependences of ignition temperature on equivalence ratio are not affected by natural convection. Numerical calculations, including catalytic reaction for platinum, have been performed to analyze the experimental results in microgravity. Numerical results show that reactants near platinum wire are consumed by catalytic reaction, therefore, the higher temperature is needed to ignite the mixture with platinum wire.

• Journal of Korean Society of Environmental Engineers
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• v.22 no.5
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• pp.819-825
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• 2000

The physico-chemical characteristics and the combustion activities of a waste automotive catalyst were carried out in this study. The physico-chemical characteristics of waste automotive catalyst was examined by EA(Elemental analysis), ICP-AES (Inductively coupled plasma-atomic emission spectrophotometer), and XRD(X-ray diffraction) analysis. Carbon deposit amount was higher in front brick than rear brick of catalyst, and increased with mileage. The content of Pt. Pd and Rh in waste automotive catalyst was different from the car manufacturing company. The combustion activities of waste automotive catalyst were investigated for acetaldehyde as a model VOC in a fixed bed reactor at atmospheric pressure. The catalytic activity of rear brick for acetaldehyde combustion was better than front brick of waste automotive catalyst. The catalytic activity of waste automotive catalyst for acetaldehyde combustion decreased with mileage. The linear relationship between catalytic activity and mileage was negative and has a very excellent correlation. Finally, the waste automotive catalyst has a good catalytic activity for acetaldehyde combustion. and can be used to control of small emission source.

• Journal of the Korea Organic Resources Recycling Association
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• v.14 no.1
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• pp.169-177
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• 2006

In this study, it was studied that the removal rate of VOC by the catalytic combustion. The combustion temperature was changed by the contact type of VOC(space velocity and catalyst depth) and the space velocity(SV) was defined by the rate of gas volume flow rate(Q, $m^3/hr$) over volume(V, $m^3$) of catalyst (SV=Q/V). The space velocity of catalytic combustor is maintained $10,000{\sim}50,000hr^{-1}$. it was studied that the conversion rate of VOC by the catalytic combustion. The combustion temperature was changed by the contact type of VOC and catalyst and the space velocity was defined by the rate of gas volume flow rate over volume of catalyst. The VOC which pass thru the heat exchanger was measured by the hydro ionic detector and measured the VOC removal rate by the activated catalyst in the reaction temperature range of 373K-423K. The removal rate was measured over 100 times. In the automobile painting booth The VOC concentration was 63.37ppm and the removal rate was 70 % at 373K and 78.92% at 423K. The removal rate was increased as increased the temperature.

• Journal of Environmental Science International
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• v.14 no.7
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• pp.669-674
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• 2005

Catalytic combustion of toluene was investigated on $CuOx/SnO_2-ZrO_2\;CuOx/SnO_2\;CuOx/ZrO_2$ catalysts prepared by impregnation. Characteristics of catalysts loaded on binary support and single support were observed by TPR, TPO, XRD, XPS techniques. The results on catalytic combustion showed that binary supports improve the activity of copper in the combustion of toluene. The reason for high catalytic activity on toluene combustion of $CuOx/SnO_2-ZrO_2$ catalyst was ascribed to oxidation$\cdot$reduction activity at low temperatures and stability of oxidation state after reduction.

• Journal of Korean Society for Atmospheric Environment
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• v.18 no.3
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• pp.205-212
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• 2002

The catalytic combustion of benzene, toluene and xylene over Pt-based catalyst was investigated in a fixed bed flow reactor system with atmospheric pressure to recycle the waste industrial catalyst for the processes of removing volatile organic compounds. According to the pretreatment condition, the properties of the waste Pt-based catalyst were characterized by XRD (X-ray diffraction) and BET (Brunauer-Emmett-Toller). In the carte of air pretreatment, 20$0^{\circ}C$ was found to be optimal, and increasing pretreatment temperature resulted in the reduction of the catalytic activity. When Pt-based catalyst pretreated at 20$0^{\circ}C$ by alto was retreated by hydrogen, the catalytic activity increased by increasing treatment temperature. In the case of HNO$_3$aqueous solution pretreatment, the catalytic activity decreased by increasing the concentration of HNO$_3$aqueous solution. The catalytic activity was seen to observe the following sequence : benzene > toluene > xylene.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2017.05a
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• pp.739-745
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• 2017

Research of ADN-based monopropellant thruster is progressed by developed countries in Europe to replace toxic hydrazine, and ADN-based monopropellant thruster system is the only system that was proved in space environment. In this research, ADN-based propellant and catalyst was fabricated to develop ADN-based monopropellant thruster, and catalytic combustion performance with fabricated propellant and catalyst were evaluated with DSC-TG analysis. Catalytic combustion of propellant and catalyst was determined with firing test using 5 N scale liquid monopropellant thruster.

• 한국연소학회:학술대회논문집
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• 1998.10a
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• pp.59-67
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• 1998

The aim of this study is to investigate advantages that the catalytically supported combustor can have. For this purpose, the catalytic combustor was prepared which consisted of the catalyst bed and the thermal combustor at the downstream of the catalyst bed. The catalyst bed consisted of two-stage. Pd catalyst was installed in the first stage of the catalyst bed, and Pt catalyst was placed in the second stage. Results showed that the catalytically supported combustion had some advantages. One was that auto-ignition occurred in the thermal combustor. This can give merit that an igniter is not necessary to start flame ignition. Other was that the catalytically supported combustion was stable for lean mixture. When combustion of lean mixture was not supported by surface reaction it became unstable so that big combustion noise was created. Therefore, it is desirable to support flame by catalytic surface reaction to obtain the stable combustion of lean mixture.