• Journal of Environmental Science International
• /
• v.22 no.8
• /
• pp.1019-1027
• /
• 2013

Sulfur hexa-fluoride has been used as a etching gas in semiconductor industry. From the globally environmental issues, it is urgent to control the emissions of this significant greenhouse gas. The main objective of this experimental investigation was to find the effective catalyst for $SF_6$ decomposition. The precursor catalyst of hexa-aluminate was prepared to investigate the catalytic activity and stability. The precursor catalyst of hexa-aluminate was modified with Ni to enhance the catalytic activities and stability. The catalytic activity for $SF_6$ decomposition increased by the addition of Ni and maximized at 6wt% addition of Ni. The addition of 6wt% Ni in precursor catalyst of hexa-aluminate improved the resistant to the HF and reduced the crystallization and phase transition of catalyst.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.21 no.6
• /
• pp.822-829
• /
• 1997

A catalytic burner was studied which can be used as a heater operated in medium temperature. Noble metal catalysts (Pd/NiO) were used, which were supported on alumina wash coated honeycomb. The maximum heat-resisting temperature of the catalyst is about 900.deg. C. Combustion efficiency of the catalytic burner reached more than 99.5 % at the excess air ratio above 1.25.NOx emissions were lower than 1.0 ppm at all operation conditions. The operation condition for a stable catalytic combustion was obtained. It was dependent on the catalyst thickness. The 30 mm thick catalyst showed the widest stable catalytic combustion region. Stable catalytic combustion region of 30 mm thick catalyst was the operation condition of excess air ratio 1.25 - 1.75 and heat flux 7 - 14 kcal/h center dot cm$^{2}$.

• Proceedings of the IEEK Conference
• /
• 2001.10a
• /
• pp.770-775
• /
• 2001

Effects of magnetic field and carrier gas velocity on the magnetic separation of FCC catalyst by a high gradient magnetic separator were studied. The activities of the equilibrium catalyst, the magnetic particles and the nonmagnetic particles were evaluated in a fixed bed microreactor The results showed that heavy metal contaminated catalyst can be selectively separated by means of high gradient magnetic separation at magnetic field 0.5T and carrier gas velocity 0.3m.s$^{-1}$ , and lightly metal contaminated catalyst retained high catalytic activity.

• 한국신재생에너지학회:학술대회논문집
• /
• 2007.11a
• /
• pp.63-66
• /
• 2007

Reformers which produce hydrogen from natural gas are essential for the operation of residential PEM fuel cells. For this purpose, steam-methane reforming reactions with Ni catalysts is primarily utilized. Commercial Ni catalysts are generally made to have porous pellet shapes in which Ni catalyst particles are uniformly dispersed over Alumina support structures. This study numerically investigates the reduction of catalyst effectiveness due to the mass transport resistances posed by porous structures of spherical catalyst pellets. The multi-component diffusion through porous media and the accurate kinetics of reforming reaction is fully considered in the numerical model. The preliminary results on the variation of the effectiveness factor according to different operation conditions are presented, which is planned to be used to develop correlations in future studies.

• 한국정보디스플레이학회:학술대회논문집
• /
• 2002.08a
• /
• pp.694-696
• /
• 2002

Growth behaviors of carbon nanotubes (CNTs) are studied in terms of catalyst by using scanning electron microscopy and transmission electron microscope (TEM). Catalyst films deposited on various substrates are agglomerated into nano-islands during the heat-up to the growth temperature. In particular, we focus on the direct investigation of the microstructures of the CNTs and the interface of CNTs-catalyst-substrate using cross-sectional TEM. We investigate relationship to the subsequent CNTs growth on each nucleation site. The growth of CNTs depends on the catalyst itself but not the silicide formation between the catalyst and the substrate.

• Journal of the Korean Applied Science and Technology
• /
• v.25 no.3
• /
• pp.275-281
• /
• 2008

The esterification of free fatty acid in Jatropha oil added by propylene glycol using p-TSA catalyst was done, and then the transesterification of Jatropha oil added by 1.0vol% GMS as an emulsifier using TMAH, and mixed catalyst(60wt%-TMAH+ 40wt%-KOH) respectively was followed at $60^{\circ}C$. The esterification conversion at the 1:8 molar ratio of free fatty acid to methanol using 8.0wt% p-TSA was 94.7% within 60min. The overall conversion at the 1:8 molar ratio of Jatropha oil to methanol and $60^{\circ}C$ using mixed catalyst was 95.4%. The kinematic viscosity of Biodiesel using TMAH and mixed catalyst in 24h met the ASTM D-6751 above $30^{\circ}C$, and showed a little more than its criterion.

• Transactions of the Korean Society of Automotive Engineers
• /
• v.8 no.1
• /
• pp.92-100
• /
• 2000

The model gas reaction tests were carried out to investigate the purification characteristics of methane on the exclusive catalyst for NGV. The experiment was conducted with the factors which affect the conversion efficiency of methane, such as Redox ratio, coexistence components of CO, MO, $H_2$O, precious metals and additives. The catalyst loaded with larger amount of pd and with additive La showed lower light-off temperature. In the presence of CO and NO, the conversion efficiency of methane was varied according to the kind of additive loaded. The conversion efficiency of methane was dropped for the catalyst loaded with La under lean air-fuel ratio, while it increased for the one loaded with Ti+Zr for the same condition. It was shown that the water vapor inhibited methane from oxidation by its poisoning on the surface of catalyst.

• Proceedings of the Korean Society of Propulsion Engineers Conference
• /
• 2007.04a
• /
• pp.163-167
• /
• 2007

Silver is widely used for catalytic decomposition of hydrogen peroxide, but start-up at room temperature is difficult and cannot withstand at high temperature. In this paper, to overcome these short-comings, a dual catalytic bed which consists of a vaporizer catalyst and a high temperature catalyst was studied. Platinum was selected as the vaporizer catalyst and perovskite type catalyst was selected for the high temperature catalyst. Preliminary test demonstrated start-up capability with non-preheating at room temperature and good thermal stability at high temperature.

• Elastomers and Composites
• /
• v.51 no.2
• /
• pp.99-105
• /
• 2016

Alkoxy modified silicone (PAMS) was synthesized from hydroxyl-terminated polydimethylsiloxane (OH-PDMS) and vinyltrimethoxysilane (VTMO) under alkali catalyst (NaOH and KOH) at room temperature ($25^{\circ}C$) via condensation polymerization. Then, the structural verification of the synthesized PAMS was confirmed using $^1H$-NMR and FT-IR spectroscopy. The reaction rate of PAMSs was studied in terms of the concentration variation of alkali catalyst. The reaction rate increased with the concentration of alkali catalyst, but no correlation between conversion and concentration of alkali catalyst was observed.

• Bulletin of the Korean Chemical Society
• /
• v.29 no.2
• /
• pp.328-334
• /
• 2008

The effects of catalyst preparation on the reaction route and the mechanism of biphenol (BP) hydrogenation, which consists of a long series-reaction, were studied. Pd/C catalysts were prepared by incipient wetness method and precipitation and deposition method. The reaction behaviors of the prepared catalysts and a commercial catalyst along with the final product distributions were very different. The choice of the catalyst preparation conditions during precipitation and deposition including the temperature, pH, precursor addition rate, and reducing agent also had significant effects. The reaction behaviors of the catalysts were interpreted in terms of catalyst particle size, metal distribution, and support acidities.