• Title/Summary/Keyword: Carrier Transport

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Transport Characteristics of Organic Anions through Poly (1-methyl-4vinylpyridium iodide-co-styrene) Membrane (Poly(1-methyl-4-vinylpyridium iodide-co-styrene)막을 통한 유기음이온의 투과특성)

  • 이광재;한정우박돈희조영일
    • KSBB Journal
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    • v.6 no.2
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    • pp.207-213
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    • 1991
  • In this study poly (1-methyl-4-vinylpyridinium iodide-co-styrene) membrane with pyridinium cation as a fixed carrier was synthesized and the transport characteristics of the membrane was examined over various factors. As the concentration of the fixed carrier in the membrane was increased, the water content was increased. Meanwhile, the counter current of the organic anion and the chloride ion, the following results were obtained. Initial flux of Cl-, organic anion and Na+ decreased with the increasing thickness of membrane, and as the concentration of the fixed carrier increases, the initial flux of Cl- and organic anion increase but the initial flux of Na+ decreased. The flux equation of the organic anion, CCl3COO- was obtained from saturation kinetics as follows;$V_{o}=\frac{(8.67{\times}10^{-5}){\cdot}[NaCl]}{9.63{\times}10^{-2}+[NaCl]} mol/cm^2h$

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Transport Properties of Conversion Materials for Digital Radiography

  • Kim, Jae-Hyung;Park, Chang-Hee;Nam, Sang-Hee
    • Transactions on Electrical and Electronic Materials
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    • v.8 no.6
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    • pp.250-254
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    • 2007
  • Applying the moving photo-carrier grating(MPG) technique and time-of-flight(TOF) measurements, we studied the transport properties of stabilized amorphous selenium typical of the material used in direct conversion X-ray imaging devices. For MPG measurement, we obtained electron and hole mobility and the recombination lifetime of $\alpha-Se$ films with arsenic(As) additions. We found an apparent increase in hole drift mobility and recombination lifetime, especially when 0.3 % As was added into $\alpha-Se$ film, whereas electron mobility decreased with the addition of As due to the defect density. For TOF measurement, a laser beam with pulse duration of 5 ns and wavelength of 350 nm was illuminated on the surface of $\alpha-Se$ with a thickness of 400 ${\mu}m$. The measured hole and electron transit times were about 8.73 ${\mu}s$ and 229.17 ${\mu}s$, respectively.

Design and Implementation for Construction Method of Management Network in MPLS-TP Network (MPLS-TP 망에서 관리 망 구축 방안에 대한 설계 및 구현)

  • Moon, Sungnam;Kang, Namhi
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.15 no.3
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    • pp.59-65
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    • 2015
  • To build a flexible network than traditional transport network, the carrier ethernet technology is emerging in network industry recently and MPLS-TP technologies are being applied as a major standard technology for the carrier ethernet. However, network management technologies required to handle equipment installed in MPLS-TP network are not clear. This paper propose an efficient method to build a management network automatically without any additional configuration when network equipments are installed in MPLS-TP network. The proposed scheme reduce cost required for both equipment installation and network maintenance by minimizing configuration procedures of connecting management system with network. We evaluated the effectiveness of the proposed scheme by applying the scheme to a real MPLS-TP equipment.

A Study on the Transport Mechanism of a SCH Quantum-Well Laser Diode and on the Modulation Characteristics (SCH 양자우물 레이저 다이오드의 수송기구와 변조응답 특성에 관한 연구)

  • Kim, Jong-Gi;Jeong, Jea-Yong;Suh, Chung-Ha
    • Journal of the Institute of Electronics Engineers of Korea TE
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    • v.37 no.1
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    • pp.27-34
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    • 2000
  • In this paper, carrier transport mechanism and modulation response for SCH(Separate Confinement Heterostructure) SQW(Single Quantum Well) laser diodes were studied. In order to explain carrier transport mechanism, both carrier density and current density were calculated. The recombination current density in the quantum well as a function of the SCH length was also calculated. For the modulation response, linearizing the rate equation, we calculated the bandwidth, relaxation oscillation frequency, damping factor, and the K-factor.

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The Mitochondrial Tricarboxylate Carrier of Silver Eel: Chemical Modification by Sulfhydryl Reagents

  • Capobianco, Loredana;Impagnatiello, Tecla;Ferramosca, Alessandra;Zara, Vincenzo
    • BMB Reports
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    • v.37 no.5
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    • pp.515-521
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    • 2004
  • The tricarboxylate (or citrate) carrier was purified from eel liver mitochondria and functionally reconstituted into liposomes. Incubation of the proteoliposomes with various sulfhydryl reagents led to inhibition of the reconstituted citrate transport activity. Preincubation of the proteoliposomes with reversible SH reagents, such as mercurials and methanethiosulfonates, protected the eel liver tricarboxylate carrier against inactivation by the irreversible reagent N-(1-pyrenyl)maleimide (PM). Citrate and L-malate, two substrates of the tricarboxylate carrier, protected the protein against inactivation by sulfhydryl reagents and decreased the fluorescent PM bound to the purified protein. These results suggest that the eel liver tricarboxylate carrier requires a single population of free cysteine(s) in order to manifest catalytic activity. The reactive cysteine(s) is most probably located at or near the substrate binding site of the carrier protein.

Gas Separation Membranes Containing $Re_6Se_8(MeCN)_6^{2+}$ Cluster-Supported Cobalt-Porphyrin Complexes

  • Park Su Mi;Won Jongok;Lee Myung-Jin;Kang Yong Soo;Kim Se-Hye;Kim Youngmee;Kim Sung-Jin
    • Macromolecular Research
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    • v.12 no.6
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    • pp.598-603
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    • 2004
  • Cellulose nitrate (CN) composite membranes, containing cobalt porphyrin (CoP) complexes self-assembled within nanometer-sized rhenium clusters (ReCoP), have been prepared and their oxygen and nitrogen gas perme­abilities were analyzed. The solubility of ReCoP and the characteristics of the corresponding composite membranes were analyzed using a Cahn microbalance, FT-IR spectroscopy, wide-angle X-ray scattering, and differential scanning calorimetry. The nitrogen permeability through the CN composite membranes decreased upon addition of ReCoP and CoP, which implies that the presence of these oxygen carrier complexes affects the structure of the polymer matrix. The oxygen permeability through the composite membranes containing small quantities of ReCoP decreased, but it increased upon increasing the concentration. The oxygen gas transport was affected by the matrix at low ReCoP concentrations, but higher concentrations of ReCoP increased the oxygen permeability as a result of its reversible and specific interactions with oxygen, effectively realizing ReCoP carrier-mediated oxygen transport.

The Ion Transport Phenomena through the Liquid Membrane with Macrocylic Compound (II). Transport of $H^+$Ion through Organic Liquid Membranes Containing Dibenzo-18-crown-6 and Dicyclohexyl-18-crown-6 as Carrier (마크로고리 화합물을 운반체로 하는 액체막을 통한 이온의 운반에 관한 연구 (제2보). 유기액체막 운반체를 통한 수소이온의 운반)

  • Yoon, Chang-Ju;Lee, Shim-Sung;Kim, Young-Hee;Kim, Si-Joong
    • Journal of the Korean Chemical Society
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    • v.28 no.3
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    • pp.170-175
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    • 1984
  • The transport rates of $H^+$ ion by DBC and DCC as carrier molecules through organic liquid membranes were determined at 25$^{\circ}$C. The transport rates depend highly on the dielectric constants of membrane solvents and these results were discussed in terms of Born's potential energy barrier methods. The sizes of anions also affect the transport rates and these results were well explained theoreticlly by extended Born's equation.

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Carrier Transport of Quantum Dot LED with Low-Work Function PEIE Polymer

  • Lee, Kyu Seung;Son, Dong Ick;Son, Suyeon;Shin, Dong Heon;Bae, Sukang;Choi, Won Kook
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.432.2-432.2
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    • 2014
  • Recently, colloidal core/shell type quantum dots lighting-emitting diodes (QDLEDs) have been extensively studied and developed for the future of optoelectronic applications. In the work, we fabricate an inverted CdSe/ZnS quantum dot (QD) based light-emitting diodes (QDLED)[1]. In order to reduce work function of indium tin oxide (ITO) electrode for inverted structure, a very thin (<10 nm) polyethylenimine ethoxylated (PEIE) is used as surface modifier[2] instead of conventional metal oxide electron injection layer. The PEIE layer substantially reduces the work function of ITO electrodes which is estimated to be 3.08 eV by ultraviolet photoemission spectroscopy (UPS). From transmission electron microscopy (TEM) study, CdSe/ZnS QDs are uniformly distributed and formed by a monolayer on PEIE layer. In this inverted QD LED, two kinds of hybrid organic materials, [poly (9,9-di-n-octyl-fluorene-alt-benzothiadiazolo)(F8BT) + poly(N,N'-bis (4-butylphenyl)-N,N'-bis(phenyl)benzidine (poly-TPD)] and [4,4'-N,N'-dicarbazole-biphenyl (CBP) + poly-TPD], were adopted as hole transport layer having high highest occupied molecular orbital (HOMO) level for improving hole transport ability. At a low-operating voltage of 8 V, the device emits orange and red spectral radiation with high brightness up to 2450 and 1420 cd/m2, and luminance efficacy of 1.4 cd/A and 0.89 cd/A, respectively, at 7 V applied bias. Also, the carrier transport mechanisms for the QD LEDs are described by using several models to fit the experimental I-V data.

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Highly Selective Transport of Ag+Ion through a Liquid Membrane Containing 2-Mercaptobenzothiazole as a Carrier

  • Akhond, Morteza;Tashkhourian, Javad
    • Bulletin of the Korean Chemical Society
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    • v.24 no.4
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    • pp.489-493
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    • 2003
  • 2-Mercaptobenzothiazole was used as a highly selective and efficient carrier for the uphill transport of silver ion through a chloroform bulk liquid membrane. In the presence of thiosulfate ion as a suitable metal ion acceptor in the receiving phase, the amount of silver transported across the liquid membrane after 180 min was 90 ± 3.0%. The selectivity and efficiency of silver ion transported from aqueous solutions containing equimolar mixtures of $Zn^{2+}, Cu^{2+}, Co^{2+}, Ni^{2+}, Cd^{2+}, Pb^{2+}, Bi^{3+}, Fe^{2+}, Fe^{3+}, Pd^{2+}, Mn^{2+}, Hg^{2+}, Sn^{2+}, Ca^{2+}, Mg^{2+}, K^+, Na^+ and Li^+$ were investigated.

Numerical Analysis of OLED Luminescence Efficiency by Hole Transport Layer Change (유기발광 소자의 수송층 두께 변화에 따른 수치적 해석)

  • Lee, Jung-Ho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.12
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    • pp.1341-1346
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    • 2004
  • The OLED research is gone for two directions. One is material development research, and another one is structural improvement part. All two are thing to heighten luminescence efficiency of OLED. n other to improve luminescence efficiency of OLED Electron - hole pairs must consist much more in the device Their profiles are sensitive to mobility velocity of electrons and holes. In this paper, we demonstrate the difference of velocity between hole and electron by experiments, and compare with a data of simulation and experiment changing hole carrier transport layer thickness, so we get the optimal we improve luminescence efficiency. We suggest improving the efficiency of OLEDS would be to balance the injection of electrons and holes into light emission layer of the device. And, we improve understanding of the various luminescence efficiency through experiments and numerical analysis of luminescence efficiency in variable hole carrier transport layer's thickness.