• Korean Journal of Materials Research
• /
• v.28 no.4
• /
• pp.208-213
• /
• 2018

Epitaxial ($11{\bar{2}}0$) a-plane GaN films were grown on a ($1{\bar{1}}02$) R-plane sapphire substrate with photoresist (PR) masks using metal organic chemical vapor deposition (MOCVD). The PR mask with striped patterns was prepared using an ex-situ lithography process, whereas carbonization and heat treatment of the PR mask were carried out using an in-situ MOCVD. The heat treatment of the PR mask was continuously conducted in ambient $H_2/NH_3$ mixture gas at $1140^{\circ}C$ after carbonization by the pyrolysis in ambient $H_2$ at $1100^{\circ}C$. As the time of the heat treatment progressed, the striped patterns of the carbonized PR mask shrank. The heat treatment of the carbonized PR mask facilitated epitaxial lateral overgrowth (ELO) of a-plane GaN films without carbon contamination on the R-plane sapphire substrate. Thhe surface morphology of a-plane GaN films was investigated by scanning electron microscopy and atomic force microscopy. The structural characteristics of a-plane GaN films on an R-plane sapphire substrate were evaluated by ${\omega}-2{\theta}$ high-resolution X-ray diffraction. The a-plane GaN films were characterized by X-ray photoelectron spectroscopy (XPS) to determine carbon contamination from carbonized PR masks in the GaN film bulk. After $Ar^+$ ion etching, XPS spectra indicated that carbon contamination exists only in the surface region. Finally, the heat treatment of carbonized PR masks was used to grow high-quality a-plane GaN films without carbon contamination. This approach showed the promising potential of the ELO process by using a PR mask.

• Journal of the Korean Crystal Growth and Crystal Technology
• /
• v.29 no.2
• /
• pp.45-49
• /
• 2019

Relatively fine silicon carbide (SiC) crystalline aggregates have been synthesized with the carbonized rice husks, paper sludge, coffee grounds as the carbon sources and the silica powder. The main reaction source to obtain silicon carbide (SiC) aggregates from the mixture of carbon sources and silica was inferred as the gaseous silicon monoxide (SiO) phase, being created from this mixture through the carbothermal reduction reaction. The silicon carbide (SiC) crystalline aggregates, fabricated from the carbonized rice husks and paper sludge, coffee grounds and silica ($SiO_2$) powder, were investigated by XRD patterns, FE-SEM and FE-TEM images. In these specimens, obtained from the carbonized rice husks, paper sludge and silica, XRD patterns showed rather high strong peak of (111) plane near $35^{\circ}$. The FE-TEM images and patterns of specimens, synthesized from carbonized rice husks, paper sludge, coffee grounds and silica under Ar atmosphere, showed relatively fine particles under $1{\mu}m$ and crystalline peak (110) of silicon carbide (SiC) diffraction pattern.

• Journal of the Korean Crystal Growth and Crystal Technology
• /
• v.26 no.5
• /
• pp.188-192
• /
• 2016

In this work, the SiC powders were synthesized through the carbonized matter from the mixture of silica powder and rice husks. The SiC powders, obtained from the carbothermal reduction reaction of silica and carbonized rice husks, were investigated by XRD patterns, XPS, FE-SEM and FE-TEM. In the XRD patterns, the specimens showed clearly very high strong peak of (111) plane near $35^{\circ}$ as well as weak (220) and (311) peak respectively at approximately $60^{\circ}$ and $72^{\circ}$. Under Ar atmosphere, the power synthesized from the mixture (in case of mixing ratio, 6 : 4) of carbonized rice husks and silica showed mainly cubic SiC crystalline phase showing relatively lower ratio of hexagonal phase without residual carbon in XRD pattern. In the TEM analysis, the specimen, synthesized from carbonized rice husks and silica with mixing ratio of 6 : 4 under Ar atmosphere, showed relatively fine particles under $5{\mu}m$ and a crystalline SiC phase of (100) diffraction pattern.

• Fire Science and Engineering
• /
• v.33 no.6
• /
• pp.120-125
• /
• 2019

A real-scale combustion test was conducted on a vinyl flooring in a divided space, with 50 mL of an inflammable liquid sprayed on it. The combustion behavior of the vinyl flooring was studied in real time, and the carbonization patterns of the surface and cross-sections of the carbonized vinyl floor were analyzed. When the flame ignited by gasoline reached its peak, a continuously flaming region, intermittent flaming region, plume region, etc., were formed. The combustion of 50 mL gasoline on vinyl flooring took 26 s, and a halo pattern was observed. This test involved spraying kerosene evenly on the vinyl flooring and attempting to ignite the flooring using a gas torch, which failed. After the combustion of the vinyl flooring was complete, its carbonized range was measured to be 600 mm in length and 380 mm in width, and the carbonized area was 1000 ㎟. Heat transformed the coated layer of surface of the carbonized vinyl flooring into a carbonized layer, which became harder. The analysis of cross-section of the boundary surface of the carbonized vinyl flooring using a stereoscopic microscope showed that the vinyl flooring was bubbling, and that the white boundary layer at the bottom of the coated layer had disappeared.

• Fire Science and Engineering
• /
• v.16 no.1
• /
• pp.39-44
• /
• 2002

In this paper, we analysed the flame patterns and the electrical characteristics of the electric outlet which was fired at standby mode. The carbonized patterns indicated that the flame had spread about 50 cm to 70 cm. After the combustibles on wall started to burn, the temperature went up to about $300^{\circ}c$ in 150 sec. The flame formed ceiling jet and spread quickly. The tracking was generated at the shortest distance between two electrodes and the resistance was about 100$\Omega$ to 300$\Omega$ As the result of analysis using metallurgical microscope, the normal part of a blade holder showed amorphous structure, but the melted part of a blade holder damaged by tracking showed dendrite structure and void evenly. When the blade holder of damaged outlet was analyzed by SEM and EDX, we found that the structure and components of the normal part were different from those of melted part.

• Korean Journal of Soil Science and Fertilizer
• /
• v.47 no.5
• /
• pp.381-389
• /
• 2014

$NH_4$-N contents in the soil treated were relatively high in the initial stages, but rapidly decreased at 124 days after treatment. $NO_3$-N contents were shown to be opposite patterns of $NH_4$-N contents. $CO_2$ emissions in the non-treatment and Carbonized rice hull treatment with application of NPK fertilizers decreased by 43.7 and 21.9% relative to the non-application of NPK fertilizer plot except 5.4% increasement in the pig manure compost treatment. $N_2O$ emissions of the non-application, the Expander rice hull application, and bio-char treatment increased by 90, 25, and 21.4%, respectively, but decreased by 54.2% in the pig manure compost treatment applied with NPK fertilizers compared with the NPK fertilizer non-application plot.

• Fire Science and Engineering
• /
• v.23 no.6
• /
• pp.98-110
• /
• 2009

The burned patterns of fire are changed very diversely according to the direction of wind, conditions of combustibles, shape of buildings and so on in the fire scenes. And careful attentions are required on the determining of ignition point and fire causes. In this study, we examined that the burned pattern of fuel controlled fires and ventilation controled fires that impose a heavy burden on fire investigators, carbonized marks of floor, formed by flammable liquids, and combustion marks of falling firing materials through the fire cases. We suggest a proper fire investigation method.

• Fire Science and Engineering
• /
• v.24 no.5
• /
• pp.136-141
• /
• 2010

The purpose of this study is to examine the structure and heat generation mechanism of low voltage switches used to turn on or off the power supply to an indoor lighting system and investigate how the fixtures and movable contacts of the switches are damaged depending on the types of energy sources in order to secure the judgment base for expected PL disputes. Based on the Korean Standard (KS) testing method for incombustibility, this study applied a general flame to the switch. In addition, current was supplied to the switch using the PCITS (Primary Current Injection Test System). The ambient temperature and humidity were maintained at $22{\pm}2^{\circ}C$ and 40~60% respectively while performing the test. It is thought that the switch generated heat due to a defective connection of the wire and clip, insulation deterioration and defective contact of the movable contact, etc. The surface of the switch damaged by the general flame was uniformly carbonized. When the flame source was removed, the fire on the switch was extinguished naturally. From the result obtained by disassembling the switch carbonized by the general flame, it could be seen that fixtures and movable contacts remained in comparatively good shape but the enclosure, clip support, movable contact, indicating lamp, etc. showed carbonization and discoloration. In the case of the switch damaged by overcurrent, the clip connecting the wires, clip support, etc. showed almost no trace of damage, but the fixtures, movable contact, indicating lamp, etc. were severely carbonized. That is, the sections with high contact resistance were intensively damaged and showed a damage pattern indicating that carbonization progressed from the inside to the outside. Therefore, it is possible to judge the initial energy source by analyzing the characteristics of the carbonization pattern and the metal fixtures of damaged switches.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
• /
• v.23 no.2
• /
• pp.161-167
• /
• 2009

Organic insulating materials which are utilized as insulating materials for the low voltage show unique carbonization characteristics when they are carbonized by a leakage current. Therefore the use of the carbonization characteristics makes it possible to examine the electrical fire which is caused by a leakage current flowing on the surface of the organic insulating material. In order to understand such carbonization characteristics, in this paper, experiments have been done to carbonize typical organic insulating materials such as phenol resin, PVC, and acrylic resin, and the carbonization patterns and the IR absorption spectrum of specimens have been analyzed. According to the analysis of the carbonization patterns, the phenol resin shows the so-called 'spider-leg' carbonization pattern due to a thermosetting property. In contrast to the phenol resin, the thermoplastic property makes it difficult to observe a clear carbonization pattern to verify carbonizing causes on the surfaces of PVC and acrylic resins. In this case, the IR absorption spectrum can be analyzed to examine the specimen carbonized by a leakage current. The analysis result shows that absorption peaks appear at the wave numbers of $3,400[cm^{-1}]$ and $1,618[cm^{-1}]$, which can be an important factor to verify the carbonizing causes.

• Proceedings of the KIEE Conference
• /
• 2006.05a
• /
• pp.57-59
• /
• 2006

In this study, we experimented a deterioration characteristics by series arcing with 600V polyvinyl chloride insulation wire and analyzed the glowing/growing process of copper oxide, waveforms of contact voltage, current, power dissipation and carbonized patterns of insulation. We know that how glowing contacts and surface arcing can decompose PVC insulation and that it is possible for the subsequent series arc to ignite, and burn insulation. We expect that these results are useful for advancing the state-of-the-art in fire protection by Providing a better understanding of how electrical fires can initiate.