• 환경위생공학
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• 제14권1호
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• pp.97-102
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• 1999

This study was carried out view that reuse of sludge of adsorbent for benzene in carbonized cast compare with activated carbon. Not only the carbonized cast is good than carbonized carbon in cation exchange capacity and 12 adsorption capacity, but also benzene adsorption capacity is no differences compare to activated carbon. As results, benzene adsorption capacity of carbonized cast and activated carbon are decreased as temperature increase($25~70^{\circ}C$).It is compatible in Lamgmuir model. Therefore, carbonized cast is applied general adsorbent. From experimental results and data regression, in model concerning effect of temperature, relative errors between the experimental data and those calculated by the model are within the range of 1.2~7.8%. In relative humidity effect (RH 0.25~0.50) of benzene adsorption, modified Freundlich model : $QB_{enzene}{;\}QB_{enzene},{\}_{RH=0}=1-kRH^{IN}$, relative errors between the experimental data and those calculated by the model are within are range of 0.5-5.1%. The constants k and l/n in equation were found to be 1.25, 1.89 in carbonized cast.

• 한국토양비료학회지
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• 제48권5호
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• pp.549-555
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• 2015

Objective of this study was to investigate the effect of carbonized biomass from crop residues on chemical properties of soil and soil carbon pools during soybean cultivation. The carbonized biomass was made by field scale mobile pyrolyzer. A pot experiment with soybean in sandy loam soil was conducted for 133 days in a greenhouse, by a completely randomized design with three replications. The treatments consisted of four levels including the control without input and three levels of carbonized biomass inputs of $9.75Mg\;ha^{-1}$, C-1 ; $19.5Mg\;ha^{-1}$, C-2 ; $39Mg\;ha^{-1}$, C-3. Soil samples were collected and analyzed pH, EC, TC, TN, inorganic-N, available phosphorus and exchangeable cations of the soils. Soil pH, Total-N and available phosphorus contents correspondingly increased with increasing the carbonized material input. The contents of soil carbon pools were $19.04Mg\;C\;ha^{-1}$ for C-1, $26.19Mg\;C\;ha^{-1}$ for C-2, $33.62Mg\;C\;ha^{-1}$ for C-3 and $12.01Mg\;C\;ha^{-1}$ for the control at the end of experiment, respectively. Increased contents of soil carbon pools relative to the control were estimated at $7.03Mg\;C\;ha^{-1}$ for C-1, $14.18Mg\;C\;ha^{-1}$ for C-2 and $21.62Mg\;C\;ha^{-1}$ for C-3 at the end of experiment, respectively, indicating that the soil carbon pools were increased with increasing the input rate of the carbonized biomass. Consequently, it seems that the carbonized biomass derived from the agricultural byproducts such as crop residues could increase the soil carbon pools and that the experimental results will be applied to the future study of soil carbon sequestration.

• 한국환경보건학회지
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• 제33권5호
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• pp.456-461
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• 2007

This study was carried out two point view that reuse of sludge and adsorption of benzene, toluene and o-xylene of VOCs in cast, carbonized cast and activated carbon. The cation exchange capacity of cast and carbonized cast were 59.2, 112 meq/100g, respectively. The specific surface were 560, $800m^2/g$, respectively. The average removal rates of benzene by 50g cast of 50% hydrous cast, anhydrous cast, carbonized cast, activated carbon were 15.0, 41.2, 88.2, 99.4% in 60min of retention time. The average removal efficiency of toluene by 50 g cast of 50% hydrous cast, anhydrous cast, carbonized cast, activated carbon were 12.5, 34.2, 88.2, 99.5% in 60 min of retention time. The average removal rates of o-xylene 50 g cast of 50% hydrous cast, anhydrous cast, carbonized cast, activated carbon were 8.8, 28.5, 84.8, 98.1% in 60min of retention time. The adsorption efficiency of test absorbent was in order of Activated Carbon > Carbonized Cast > Cast.

• Carbon letters
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• 제16권1호
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• pp.62-66
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• 2015

In this study, carbonized fibers were prepared by using acidically cross-linked LDPE fibers. The surface morphologies of the carbonized fibers were observed by SEM. The effects of cross-linking process temperatures were studied using thermal analyses such as DSC and TGA. The melting and heating enthalpy of the fibers decreased as the cross-linking temperature increased. The cross-linked fibers had a carbonization yield of over 50%. From SEM results the highest yield of carbonized LDPE-based fibers was obtained by cross-linking at a sulfate temperature ($170^{\circ}C$). As a result, carbonation yield of the carbonized fibers was found to depend on the functions of the cross-linking ratio of the LDPE precursors.

• 한국환경농학회지
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• 제35권3호
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• pp.159-165
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• 2016

과수원에서 발생하는 전정가지 부산물로부터 생산한 바이오매스 탄화물의 토양내 처리효과를 구명하기 위하여 배 전정가지를 활용하여 탄화물을 생산하고 이를 배 과원 토양에 투입하여 토양 화학성 변화와 토양 탄소 저장 잠재량을 비교 검토하였다. 배 전정가지 유래 탄화물은 방향족 화합물 형태를 유지하고 탄소함량도 62%로 매우 높았으며, 과원 토양의 유기물함량은 탄화물의 투입량이 많을수록 통계적으로 유의하게 증가하였다. 탄화물 투입 166일 후 토양 탄소저장 잠재량은 바이오매스 탄화물 시용 수준이 높을수록 증가하는 경향을 나타냈으며, 통계적으로 유의한 차이를 나타냈다. 대조구, C-1 그리고 C-2 처리구에서 각각 토양 탄소저장 잠재량은 40.1, 49.3 그리고 57.8 Mg/ha으로 나타났다. 토양 탄소저장 잠재량은 탄화물 투입량에 따라 고도로 높은 상관관계 (P < 0.001)를 나타내며 증가하였다. 기울기가 1.496인 1차 회귀방정식을 나타냈으며, 탄화물 투입량이 100 kg/ha 높아질수록 토양 탄소 저장 잠재량은 0.1496 Mg/ha 증가하였다. 이러한 결과를 미루어 볼 때 장기간 동안 지속적으로 바이오매스 탄화물을 시용한다면 토양 탄소의 중요한 공급원이 되며 결론적으로 농경지가 토양 탄소저장원으로서의 역할을 할 수 있을 것으로 판단된다.

• 한국토양비료학회지
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• 제47권6호
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• pp.486-490
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• 2014

This study was conducted to investigate the effect of carbonized biomass from crop residues on soil carbon storage during soybean cultivation. The carbonized biomass was made by field scale mobile pyrolyzer. The treatments consisted of control without input and three levels of carbonized biomass inputs as $59.5kg10a^{-1}$, C-1 ; $119kg10a^{-1}$, C-2 ; $238kg10a^{-1}$, C-3. Soil samples were collected during the 113 days of experimental periods, and analyzed soil pH and moisture contents. Soil carbon contents and soybean yield were measured at harvesting period. For the experimental results, soil pH ranged from 6.8 to 7.5, and then increased with increasing carbonized material input. Soil moisture contents were slightly higher by 0.1~1.5% than the control, but consistent pattern was not observed among the treatments. Soil carbon and organic carbon contents in the treatments increased at 24 and 15% relative to the control at 15 days after sowing, respectively. Loss rate of SOC (soil organic carbon) relative to its initial content was 7.2% in control followed by C-1, 6.8%> C-2, 3.5%>C-3, 1.1% during the experimental periods. The SOC change rate decreased with increasing carbonized biomass rate. It was appeared that soybean yields were $476.9kg10a^{-1}$ in the control, and ranged from 453.6 to $527.3kg10a^{-1}$ in the treatments. However, significant difference was not found among the treatments. It might be considered that the experimental results will be applied to soil carbon sequestration for future study.

• Carbon letters
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• 제3권3호
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• pp.127-132
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• 2002

Unidirectional polymer composites were prepared using high-strength carbon fibers as reinforcement and phenolic resin as matrix precursor with keeping fiber volume fraction at 30, 40, 50 and 60% respectively. These composites were carbonized at $1000^{\circ}C$ and graphitised at $2600^{\circ}C$ in the inert atmosphere. The carbonized and graphitised composites were characterized for mechanical properties as well as microstructure. Microscopic studies were carried out of the polished surface of carbonized and graphitised composites after etching by chromic acid, to understand the effect of fiber volume fraction on oxidation at fiber-matrix interface. It is found that the flexural strength in polymer composites increases with fiber volume fraction and so does for the carbonised composites. However, the trend was found to be reversed in graphitised composites. In all the carbonized composites anisotropic region has been observed at fiber-matrix interface which transforms into columnar type microstructure upon graphitisation. The extension of strong and weak columnar type microstructure is function of fiber volume fraction. SEM microscopy of the etched surface of the sample reveal that composites containing 40% fiber volume has minimum oxidation at the interface, revealing a strong interfacial bonding.

• 한국토양비료학회지
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• 제49권1호
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• pp.1-6
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• 2016

Carbonized biomass could be used as a mechanism for long-term storage of C in soils. However, experimental results are variable. Objective of this study was carried out to evaluate the effect of carbonized biomass made from soybean residue on soil organic carbon and seed yield during soybean cultivation. The carbonized biomass was made by field scale mobile pyrolyzer. Pyrolyzer was performed in a reactor operated at $400{\sim}500^{\circ}C$ for 2 hours using soybean residue. The treatments consisted of four levels as the control without input and three levels of carbonized biomass inputs as $357kg\;ha^{-1}$, C-1 ; $714kg\;ha^{-1}$, C-2 ; $1,428kg\;ha^{-1}$, C-3. It was appeared that seed yield of soybean was $2,847kg\;ha^{-1}$ for control, $2,897kg\;ha^{-1}$ for C-1, $2,946kg\;ha^{-1}$ for C-2 and $3,211kg\;ha^{-1}$ for C-3 at the end of experiment. It was shown that the contents of SOC were $5.21g\;kg^{-1}$ for C-1, $5.93g\;kg^{-1}$ for C-2, $7.00g\;kg^{-1}$ for C-3 and $4.73g\;kg^{-1}$ for the control at the end of experiment. Accumulated SOC contents linearly significantly (P < 0.001) increased with increasing the carbonized biomass input. The slopes (0.00162) of the regression equations suggest that SOC contents from the soil increase by $0.162g\;kg^{-1}$ with every $100kg\;ha^{-1}$ increase of carbonized biomass rate. Consequently the carbonized biomass for byproducts such as soybean residue could increase SOC. It might be considered that the experimental results will be applied to soil carbon sequestration for future study. More long-term studies are needed to prove how long does SOC stay in agricultural soils.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2001년도 추계학술발표대회 논문집
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• pp.133-136
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• 2001

The effect of pre-carbonization condition on the mechanical properties of nonwoven needle-punched carbon/phenolic composite was studied. The nonwoven Oxi-PAN felt was pre-carbonized at different temperature. The pre-carbonized Oxi-PAN felt was needle-punched and then carbonized. Needle-punched nonwoven carbon preforms were formed into composites with phenol resin. The tensile and flexural strengths showed maximum value with pre-carbonization temperature of $500^{\circ}C$. Compared with the non-pre-carbonized composite, the mechanical properties were slightly improved.

• 한국환경농학회지
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• 제36권2호
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• pp.73-79
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• 2017

본 연구는 농가에서 버려지는 부산물을 탄화물로 변환한 후 토양에 적용하여 토양의 화학적 특성 변화와 온실가스 발생량을 비교하였다 탄화물로의 활용은 세 가지의 장점이 있었다. 첫 번째 버려지는 자원은 활용하여 재이용한 측면, 두 번째 농경지의 토양탄소 함량을 증진 시킬 수 있는 측면, 세 번째 농경지에서 발생하는 아산화질소를 줄일 수 있는 측면에서 유용할 것으로 판단된다. 하지만 $N_2O$ 감축기작에 대한 정확한 파악을 위해 질소순환과 연계된 추가적인 연구가 필요하다.